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41.
Acid deposition is considered to be a major environmental problem in China, but information about effects on soils and waters is scarce. To contribute to increased knowledge about the problem a small catchment (about 7 ha) in the outskirts of Guiyang, the provincial capital of Guizhou in south-western China, was instrumented for collection of precipitation, throughfall, soil water and stream water. In addition soil samples have been collected and analyzed for key properties. Median pH in the precipitation is 4.40 (quartiles: 4.19 and 4.77) and the median sulfate concentration 228 µeq/L (quartiles: 147 and 334 µeq/L). The dry deposition of both SO2 and alkaline dust is considerable. The sum of wet deposition of sulfate and dry deposition of SO2 has been estimated to about 8.5 gSm-2yr-1. The total S-deposition may be somewhat higher due to dry deposition of sulfate and occult deposition. In soil water, SO4 2- is the major anion, generally ranging from 300 to 2500 µeq/L in the different plots. Calcium is an important cation, but there is also a considerable contribution of aluminum from the soil. In some of the plots the concentrations of inorganic monomeric aluminum (Ali) are typically between 200 and 400 µm. Potential harmful levels of aluminum and/or high Ali/(Ca2+ + Mg2+) molar ratios occur in the catchment, but damages to vegetation have not yet been reported. In most cases exchangeable aluminum accounts for between 75 and 95% of the total effective cation exchange capacity (CECE) in the mineral soils. The aluminum chemistry cannot easily be explained by conventional models as the Gaines-Thomas ion-exchange equation or equilibrium with an Al(OH)3 mineral phase. The stream water is generally less acidic and has considerably lower concentrations of aluminum than the soil water, even though quite acid events have been observed (pH < 4.4). The median pH values are 4.9 and 5.0 in the two first order streams and 6.3 in the dam at the lower boarder of the catchment.  相似文献   
42.
自70年代起,我国南方地区开始出现大面积缺钾现象,其中以果园土壤尤为严重;80年代中期以来,我国北方地区缺钾问题亦有逐年发展的趋势.近年来,无论在南方还是北方,果园土壤由于水果产量和品质对钾的特别需要而表现出普遍缺钾的现象,事实上,施用钾肥已成为果园增产增收的一个重要措施.  相似文献   
43.
Cadmium (Cd) sorption isotherms were estimated by two different analytical approaches to assess the influence of initial Cd concentrations of soil matrix on the sorption of added Cd. For the laboratory experiments a heterogeneous set of samples was collected to include a wide range of different initial Cd concentrations. Comparison of both analytical methods (conventional analysis, radioanalysis) resulted in a strong conformity of Cd contents in solution at equilibrium. The calculated Cd concentrations in the soil solid phase differ according to the analytical approach for considering the initial contents. The determination of the initial contents by the proposed radioanalytical method with 109Cd resulted in long linear Freundlich‐isotherms, even in the low concentration range. Thus, radioanalysis seems to be the most suitable method to recognise the initial contents of Cd in soil. EDTA extractable Cd represent the initial concentrations, which are averaged over solid and liquid phase. However, depending on the sorption characteristics of the soil these rates vary. In the investigated set of soil samples 52.3 to 99.3% of Cd must be added to the solid phase.  相似文献   
44.
During the last three decades, large amounts of soil organic matter (SOM) and associated nutrients have been accumulated in arable soils of Western Germany (former FRG) due to deepening of the plough layers (from < 25 to > 35 cm) and to fertilizer application rates which have exceeded the amounts of nutrients removed in harvested crops. Organic carbon and total nitrogen balances (1970—1998) on 120 plots from 16 farms in southern Lower Saxony yielded a cumulative increase of up to 16 t C ha−1 and 1 t N ha−1 in loess soils used for cash crop production and up to 26 t C ha−1 and 2.4 t N ha−1 in sandy soils under livestock production. The buffering capacity for reactive compounds, particularly of C, N, S and P and of other (organic or inorganic) pollutants will reach its limits in the near future, after organic matter ”︁equilibria” have been re‐established. An immediate adaptation of the current fertilizer application rates to the nutrient export by field crops is therefore urgently needed.  相似文献   
45.
Yield and water productivity of potatoes grown in 4.32 m2 lysimeters were measured in coarse sand, loamy sand, and sandy loam and imposed to full (FI), deficit (DI), and partial root-zone drying (PRD) irrigation strategies. PRD and DI as water-saving irrigation treatments received 65% of FI after tuber bulking and lasted for 6 weeks until final harvest. Analysis across the soil textures showed that fresh yields were not significant between the irrigation treatments. However, the same analysis across the irrigation treatments revealed that the effect of soil texture was significant on the fresh yield and loamy sand produced significantly higher fresh yield than the other two soils, probably because of higher leaf area index, higher photosynthesis rates, and “stay-green” effect late in the growing season. More analysis showed that there was a significant interaction between the irrigation treatments and soil textures that the highest fresh yield was obtained under FI in loamy sand. Furthermore, analysis across the soil textures showed that water productivities, WP (kg ha−1 fresh tuber yield mm−1 ET) were not significantly different between the irrigation treatments. However, across the irrigation treatments, the soil textures were significantly different. This showed that the interaction between irrigation treatments and soil textures was significant that the highest significant WP was obtained under DI in sandy loam. While PRD and DI treatments increased WP by, respectively, 11 and 5% in coarse sand and 28 and 36% in sandy loam relative to FI, they decreased WP in loamy sand by 15 and 13%. The reduced WP in loamy sand was due to nearly 28% fresh tuber yield loss in PRD and DI relative to FI even though ET was reduced by 9 and 11% in these irrigation treatments. This study showed that different soils will affect water-saving irrigation strategies that are worth knowing for suitable agricultural water management. So, under non-limited water resources conditions, loamy sand produces the highest yield under full irrigation but water-saving irrigations (PRD and DI) are not recommended due to considerable loss (28%) in yield. However, under restricted water resources, it is recommended to apply water-saving irrigations in sandy loam and coarse sand to achieve the highest water productivity.  相似文献   
46.
47.
Generation of organic waste is increasing worldwide and strategies for its environmentally sound use must be developed and optimized. Regulations in European countries and the USA differ largely with respect to requirements of organic waste quality and the quantities of pollutants which can be added to the soil. Research has shown beneficial effects regarding the improvement of soil fertility. Enrichment of total metals in soil was attributed to long‐term sludge application but the effect on bioavailability of metals must be further clarified. A number of organic pollutants, such as hydrophobic persistent organic contaminants and surfactants, are known to accumulate in organic wastes. However, the former interact strongly with organic matter in the sludge‐soil‐plant system and systemic plant uptake is generally assumed to be minimal. Surfactants may cause adverse environmental impacts when they enter sewage systems in high loads and accumulate in sludge. Surfactants and some of their metabolites are not readily biodegraded in non‐aerated environments. Due to their toxicity and estrogenic activity, of nonylphenol for example, more research is needed to optimize analytical techniques and to trace their behavior in soil. Some options to cope with the risks of huge amounts of organic waste and also some benefits are presented: (1) further limitation of standards for pollutants and reduced application rates; (2) improved treatment of sewage sludge to reduce the total and bioavailable portions of both heavy metals and organic pollutants; (3) adaptation of waste application rates to soil properties such as sorption capacity for pollutants; (4) harmonization of analytical protocols for organic contaminants, i.e. surfactants and metabolites, enabling a more thorough monitoring of the wastes which are to be applied onto soils.  相似文献   
48.
Phaeozems of northeastern Germany and their position in holocene landscape development A typical soil association of NE-German young moraine area (Uckermark-region) including Phaeozems and colluvial deposits (Cumulic Anthrosols) was described macromorphologically using a trench profile and investigated by chemical standard analyses, humic compound analysis, pollen analysis and 14C-radiocarbon dating. Results are discussed in view of pedogenesis of Phaeozems. Conclusions were made concerning the holocene premedieval landscape development. A key position for reconstructing palaeoecological environmental conditions is held by “Black colluvium”. The “Black colluvium” is the relocated humous horizon of former Chernozems influenced by syn- and postsedimentary processes. The specific character of holocene landscape development and pedogenesis of the Uckermark-region is connected with the special natural conditions and history of land-use.  相似文献   
49.
Thermal and oxidation resistant coating is necessary for carbon fiber (CF) in CF reinforced concrete (CFRC) composite application in order to fulfil a high level of safety standard in case of fire. Pre-ceramic coatings such as Polysilazane, Polysiloxane, and Methyl silicone resin have been deposited on CF filament yarn by means of wet chemical continuous dip coating method. The surface analyses e.g. scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and infrared spectroscopy (IR) results showed the changes of surface morphology by the coatings. Thermo gravimetric analysis (TGA) revealed that the high temperature (up to 800 °C) oxidation stability of CF was significantly improved with coatings. Thermo-mechanical properties also significantly enhanced up to 600 °C. CF yarn retains its original strength and elasticity modulus/stiffness at 700 °C due to thermal and oxidation resistant coatings.  相似文献   
50.
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