Modeling the Effect of pH and Salinity on Biogeochemical Reactions and Metal Behavior in Sediment     

Yongseok Hong  Danny D. Reible 《Water, air, and soil pollution》2014,225(1):1-20

A mathematical model is developed to investigate the effect of pH and salinity fluctuation on biogeochemical reactions and metals' behavior in sediments. The model includes one-dimensional vertical advective and diffusive transport of species, serial reductions of electron acceptors, and precipitation/dissolution of species, acid–base chemistry, and metal sorption to sediments. The model was tested using data obtained from laboratory microcosm experiments which exposed metal (Cd, Zn) contaminated sediment to alternating fresh and salty overlying water. The model successfully reproduces the contrasting metal's release behavior and the vertical profiles of pH, Cl^?, SO₄ ^2?, Mn and Fe in porewater and the acid volatile sulfides (AVS) and simultaneously extracted metals (SEM) in sediments. The model showed that FeOOH_(s) was the dominant sorption phase controlling the solubility of the metals at the surficial sediments while AVS controlled the solubility of the metals in anoxic sediments. The model also showed that the release of the metals to overlying water was controlled by the oxidation of metal sulfides in a very thin layer of oxic sediments (2–3 mm). The proposed model can be useful in managing metal contaminated sediments where pH and salinity are fluctuating by assessing the underlying biogeochemical processes and metals' behavior.  相似文献   

"Green" composites from renewable resources: preparation of epoxidized soybean oil and flax fiber composites     

Liu Z  Erhan SZ  Akin DE  Barton FE 《Journal of agricultural and food chemistry》2006,54(6):2134-2137

In recent years there has been considerable interest in using natural plant fibers as reinforcements for plastics. The motivation includes cost, performance enhancement, weight reduction, and environment concerns. High performance flax fiber could potentially substitute for glass or carbon fibers as reinforcements for plastics. This study reports the "green" composites obtained from a mixture of epoxidized soybean oil and epoxy resin, 1,1,1-tris(p-hydroxyphenyl)ethane triglycidyl ether (THPE-GE), reinforced with flax fiber. The compression molding method is used for making the composites. Curing agents triethylenetetramine and diethylenetriamine provide better physical properties of the composites than Jeffamine agents D-230 and EDR-148. Both the flexural modulus and the tensile modulus of the composites increase as the amount of THPE-GE increases. The flexural modulus increased at a fiber content of <10 wt %, but there is a decrease beyond 10 wt %. The tensile modulus increases with fiber content until a maximum at 13.5 wt %, and then it decreases. The flax fiber length affected the mechanical properties of the composites: the longer the fiber length, the better are the mechanical properties observed.  相似文献   

Effect of added caffeic acid and tyrosol on the fatty acid and volatile profiles of camellia oil following heating   总被引：3，自引：0，他引：3  

Haiyan Z  Bedgood DR  Bishop AG  Prenzler PD  Robards K 《Journal of agricultural and food chemistry》2006,54(25):9551-9558

Camellia oil is widely used in some parts of the world partly because of its high oxidative stability. The effect of heating a refined camellia oil for 1 h at 120 degrees C or 2 h at 170 degrees C with exogenous antioxidant, namely, caffeic acid and tyrosol, was studied. Parameters used to assess the effect of heating were peroxide and K values, volatile formation, and fatty acid profile. Of these, volatile formation was the most sensitive index of change as seen in the number of volatiles and the total area count of volatiles in gas chromatograms. Hexanal was generally the dominant volatile in treated and untreated samples with a concentration of 2.13 and 5.34 mg kg(-1) in untreated oils heated at 120 and 170 degrees C, respectively. The hexanal content was significantly reduced in heated oils to which tyrosol and/or caffeic acid had been added. Using volatile formation as an index of oxidation, tyrosol was the more effective antioxidant of these compounds. This is contradictory to generally accepted antioxidant structure-activity relationships. Changes in fatty acid profiles after heating for up to 24 h at 180 degrees C were not significant.  相似文献   

Frictional afterslip following the 2005 Nias-Simeulue earthquake, Sumatra   总被引：1，自引：0，他引：1  

Hsu YJ  Simons M  Avouac JP  Galetzka J  Sieh K  Chlieh M  Natawidjaja D  Prawirodirdjo L  Bock Y 《Science (New York, N.Y.)》2006,312(5782):1921-1926

Continuously recording Global Positioning System stations near the 28 March 2005 rupture of the Sunda megathrust [moment magnitude (Mw) 8.7] show that the earthquake triggered aseismic frictional afterslip on the subduction megathrust, with a major fraction of this slip in the up-dip direction from the main rupture. Eleven months after the main shock, afterslip continues at rates several times the average interseismic rate, resulting in deformation equivalent to at least a M(w) 8.2 earthquake. In general, along-strike variations in frictional behavior appear to persist over multiple earthquake cycles. Aftershocks cluster along the boundary between the region of coseismic slip and the up-dip creeping zone. We observe that the cumulative number of aftershocks increases linearly with postseismic displacements; this finding suggests that the temporal evolution of aftershocks is governed by afterslip.  相似文献   

Assessing the benefits of the marine protected area of Punta Coles,southern Peru (south-east Pacific) on productivity of conspicuous benthic species using pre-image population analysis     

Alex Tejada  Danny Baldarrago  Ruslan Pastor  Marco Ortiz 《水产资源保护:海洋与淡水生态系统》2023,33(1):29-43

1. The coastal marine protected ecosystem at Punta Coles (as a part of the Reserva Nacional de Islas, Islotes y Puntas Guaneras) is located in a highly exploited area in southern Peru and contains several commercial, bioengineering and other benthic species.
2. Pre-image population analysis was used to estimate the transient values of intrinsic growth rate (r) based on biomass and density time series as a proxy of productivity to assess the effectiveness of protection.
3. The outcomes obtained showed that the gastropods Concholepas concholepas, Fissurella latimartiginata and the tunicate Purya chilensis showed a reduction of productivity during recent years, whilst the sea urchin Loxechinus albus, the barnacle Balanus laevis and the bivalve Semimytilus algosus showed an opposite pattern. Several species exhibited a chaotic dynamic, coinciding with the highest productivity values. In 2016 and 2017, several species exhibited a reduction of their abundance which could be delayed responses explained by changes in oceanographic conditions (reduction of coastal upwelling), La Niña event and illegal harvest.
4. The above notwithstanding, the results suggest that effective protection of benthic species in the protected ecosystem of Punta Coles have been partially accomplished. Therefore, this work could be considered a baseline study, permitting the subsequent monitoring of productivity of the main species inhabiting the coastal area of Punta Coles.
5. Pre-image population analysis could be used as a complimentary analytical tool since it enables the evaluation of transient population parameters (e.g. productivity) thus aiding population management, conservation and monitoring decisions.

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