Supramolecular Materials: Self-Organized Nanostructures   总被引：1，自引：0，他引：1  

SI Stupp  V LeBonheur  K Walker  LS Li  KE Huggins  M Keser  A Amstutz 《Science (New York, N.Y.)》1997,276(5311):384-389

Miniaturized triblock copolymers have been found to self-assemble into nanostructures that are highly regular in size and shape. Mushroom-shaped supramolecular structures of about 200 kilodaltons form by crystallization of the chemically identical blocks and self-organize into films containing 100 or more layers stacked in a polar arrangement. The polar supramolecular material exhibits spontaneous second-harmonic generation from infrared to green photons and has an adhesive tape-like character with nonadhesive-hydrophobic and hydrophilic-sticky opposite surfaces. The films also have reasonable shear strength and adhere tenaciously to glass surfaces on one side only. The regular and finite size of the supramolecular units is believed to be mediated by repulsive forces among some of the segments in the triblock molecules. A large diversity of multifunctional materials could be formed from regular supramolecular units weighing hundreds of kilodaltons.  相似文献   

Inhibitory effects of citrus essential oils and their components on the formation of N-nitrosodimethylamine   总被引：1，自引：0，他引：1  

Sawamura M  Sun SH  Ozaki K  Ishikawa J  Ukeda H 《Journal of agricultural and food chemistry》1999,47(12):4868-4872

Twenty-eight kinds of citrus essential oils and their components were studied for inhibitory effects on the formation of N-nitrosodimethylamine (NDMA). The reaction mixture consisted of dimethylamine and sodium nitrite adjusted at pH 3.6, in addition to essential oils and an emulsifying agent. The quantification was determined by high-performance liquid chromatography monitored at 220 nm. All of the essential oils inhibited the formation of NDMA in the range of 20-85%. The oils of ujukitsu (Citrus ujukitsu Hort. ex Shirai), yuzu (C. junos Tanaka), mochiyu (C. inflata Hort. ex Tanaka), and ponkan (C. reticulata Blanco cv. F-2426) inhibited the formation of NDMA much more effectively than other citrus oils. The inhibitory proportions of components of citrus essential oils such as myrcene, alpha-terpinene, and terpinolene were as high as 80%.  相似文献   

Evaluation of tumescent local anesthesia in cats undergoing unilateral mastectomy     

Clarissa MR. Moreira  Renato LS. Oliveira  Gilberto A. Costa  Katia B. Corgozinho  Stelio PL. Luna  Heloisa JM. Souza 《Veterinary anaesthesia and analgesia》2021,48(1):134-141

ObjectiveTo evaluate the analgesic efficacy and safety of tumescent local anesthesia (TLA) in cats undergoing unilateral mastectomy.Study designProspective clinical trial.AnimalsA total of 12 ovariohysterectomized female cats.MethodsAll animals were premedicated with pethidine (4 mg kg^–1) intramuscularly (IM), followed by induction of anesthesia with propofol (5 mg kg^–1) intravenously and maintenance with isoflurane in oxygen. A refrigerated TLA solution (15 mL kg^–1, 8 °C) was injected using a Klein cannula. The solution was composed of 0.5 mL of epinephrine (1 mg mL^–1) and 40 mL of 2% lidocaine added to 210 mL lactated Ringer’s solution (final lidocaine concentration 0.32%). Heart and respiratory rates, systolic arterial blood pressure, temperature and oxygen saturation were measured during anesthesia. Blood samples were collected from the jugular vein for measurement of plasma lidocaine concentration using high performance liquid chromatography. Postoperative pain scores were evaluated hourly for 6 hours. Analgesic rescue was performed with tramadol (2 mg kg^–1) IM and meloxicam (0.15 mg kg^–1) subcutaneously.ResultsPlasma lidocaine concentration peaked at 90 minutes after injection of TLA, but no concentration considered toxic for the species was measured. The median postoperative analgesia time was 6 hours after injection of TLA.ConclusionsThis study found that TLA prevented sympathetic response to noxious stimuli during anesthesia and provided satisfactory postoperative analgesia in cats submitted to total unilateral mastectomy, with no apparent signs of toxicity.Clinical relevanceTLA can prevent sympathetic stimulation resulting from noxious stimuli during anesthesia, promoting good intraoperative conditions, proving to be a viable addition to analgesia in cats submitted to a total unilateral mastectomy.  相似文献   

Ant nestmate and non-nestmate discrimination by a chemosensory sensillum   总被引：2，自引：0，他引：2  

Ozaki M  Wada-Katsumata A  Fujikawa K  Iwasaki M  Yokohari F  Satoji Y  Nisimura T  Yamaoka R 《Science (New York, N.Y.)》2005,309(5732):311-314

In animal societies, chemical communication plays an important role in conflict and cooperation. For ants, cuticular hydrocarbon (CHC) blends produced by non-nestmates elicit overt aggression. We describe a sensory sensillum on the antennae of the carpenter ant Camponotus japonicus that functions in nestmate discrimination. This sensillum is multiporous and responds only to non-nestmate CHC blends. This suggests a role for a peripheral recognition mechanism in detecting colony-specific chemical signals.  相似文献   

Anoxification recovery using underwater LED irradiation and influence of its optical spectrum on water quality improvement     

Honglikith  Daoluang  Harada  Masayoshi  Hiramatsu  Kazuaki  Tabata  Toshinori  Ozaki  Akinori 《Paddy and Water Environment》2022,20(1):153-175

Paddy and Water Environment - This study focuses on a method for improving water quality via anoxification recovery using underwater LED treatment in an organically polluted reservoir. The main aim...  相似文献