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81.
Parrish DD Holloway JS Trainer M Murphy PC Fehsenfeld FC Forbes GL 《Science (New York, N.Y.)》1993,259(5100):1436-1439
Measurement of the levels of ozone and carbon monoxide (a tracer of anthropogenic pollution) at three surface sites on the Atlantic coast of Canada allow the estimation of the amount of ozone photochemically produced from anthropogenic precursors over North America and transported to the lower troposphere over the temperate North Atlantic Ocean. This amount is greater than that injected from the stratosphere, the primary natural source of ozone. This conclusion supports the contention that ozone derived from anthropogenic pollution has a hemisphere-wide effect at northern temperate latitudes. 相似文献
82.
A device for sampling the interstitial waters of deep-sea sediments in situ has been developed and tested. The sampler collects a series of samples over a depth of 1.5 meters in the sediment and thus makes possible the accurate delineation of chemical gradients existing in the pore waters. Samples collected in the North Atlantic indicate that significant gradients of K(+) and Ca(2+) exist in the sediments sampled. Interstitial solutions sampled between Ireland and Cape Cod, Massachusetts, are characterized by the depletion of K(+) and the enrichment of Ca(2+). 相似文献
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84.
Discrepancies in the growth curves for the sodium requirement of the cricket indicate that hormology may play an important role in the response to essential nutrients as well as to toxic compounds. Differentiation between stimulation of growth by a nonnutritive action and support of growth by an essential nutrient is difficult. 相似文献
85.
Many protein enzymes use general acid-base catalysis as a way to increase reaction rates. The amino acid histidine is optimized for this function because it has a pK(a) (where K(a) is the acid dissociation constant) near physiological pH. The RNA enzyme (ribozyme) from hepatitis delta virus catalyzes self-cleavage of a phosphodiester bond. Reactivity-pH profiles in monovalent or divalent cations, as well as distance to the leaving-group oxygen, implicate cytosine 75 (C75) of the ribozyme as the general acid and ribozyme-bound hydrated metal hydroxide as the general base in the self-cleavage reaction. Moreover, C75 has a pK(a) perturbed to neutrality, making it "histidine-like." Anticooperative interaction is observed between protonated C75 and a metal ion, which serves to modulate the pK(a) of C75. General acid-base catalysis expands the catalytic repertoire of RNA and may provide improved rate acceleration. 相似文献
86.
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88.
Brüning JC Gautam D Burks DJ Gillette J Schubert M Orban PC Klein R Krone W Müller-Wieland D Kahn CR 《Science (New York, N.Y.)》2000,289(5487):2122-2125
Insulin receptors (IRs) and insulin signaling proteins are widely distributed throughout the central nervous system (CNS). To study the physiological role of insulin signaling in the brain, we created mice with a neuron-specific disruption of the IR gene (NIRKO mice). Inactivation of the IR had no impact on brain development or neuronal survival. However, female NIRKO mice showed increased food intake, and both male and female mice developed diet-sensitive obesity with increases in body fat and plasma leptin levels, mild insulin resistance, elevated plasma insulin levels, and hypertriglyceridemia. NIRKO mice also exhibited impaired spermatogenesis and ovarian follicle maturation because of hypothalamic dysregulation of luteinizing hormone. Thus, IR signaling in the CNS plays an important role in regulation of energy disposal, fuel metabolism, and reproduction. 相似文献
89.
Chemical analyses of morphologically preserved organic matter in a Carboniferous coal ball reveal that the material is coalified to a rank approximately equal to that of the surrounding coal. Hence, the plant tissues in the coal ball were chemically altered by coalification processes and were not preserved as peat. 相似文献
90.
Sereno PC Wilson JA Larsson HC Dutheil DB Sues HD 《Science (New York, N.Y.)》1995,267(5205):1752-1753