Fall and Spring Phosphorus Fertilization of Potato Using a Dicarboxylic Acid Polymer (AVAIL®)     

Jeffrey C. Stark  Bryan G. Hopkins 《Journal of plant nutrition》2015,38(10):1595-1610

A dicarboxylic acid polymer (AVAIL) modifies the soil immediately around fertilizer—potentially improving crop phosphorus (P) uptake efficiency and yield. Study objectives were to evaluate potato (Solanum tuberosum L.) response to seasonal applications of liquid and dry AVAIL blended P fertilizer on calcareous soils with low to moderate soil test P. Field experiments conducted 2005–2008 included comparisons of monoammonium phosphate (MAP; 11-52-0) broadcast and/or ammonium polyphosphate (APP; 10-34-0) liquid band applications with or without AVAIL in various fall or spring applications. AVAIL increased US No. 1 yields for selected P rate/source/timing combinations in each of the four years; increased United States No. 1 yields overall in 2006 and 2008; and increased total yield and yield of large (>284g) tubers in 2006. The greatest responses to AVAIL occurred on soils with high lime concentrations. No seasonal advantage was observed in any case.  相似文献   

Flavonol glycosides and novel iridoid glycoside from the leaves of Morinda citrifolia   总被引：5，自引：0，他引：5  

Sang S  Cheng X  Zhu N  Stark RE  Badmaev V  Ghai G  Rosen RT  Ho CT 《Journal of agricultural and food chemistry》2001,49(9):4478-4481

One new iridoid glycoside and five known flavonol glycosides have been isolated from the leaves of Morinda citrifolia. The new iridoid exists as an epimeric mixture in solution. Complete assignments of the proton and carbon chemical shifts for the individual epimers were accomplished on the basis of high-resolution 1D and 2D NMR data. Their antioxidative activities were measured. All of these compounds showed DPPH free radical scavenging activity at the concentration of 30 microM.  相似文献   

Sensory-guided decomposition of roasted cocoa nibs (Theobroma cacao) and structure determination of taste-active polyphenols     

Stark T  Bareuther S  Hofmann T 《Journal of agricultural and food chemistry》2005,53(13):5407-5418

Sequential application of solvent extraction, gel permeation chromatography, and RP-HPLC in combination with taste dilution analyses, followed by LC-MS and 1D/2D-NMR experiments and thiolytic degradation, revealed that, besides theobromine and caffeine, the flavan-3-ols epicatechin, catechin, procyanidin B-2, procyanidin B-5, procyanidin C-1, [epicatechin-(4beta-->8)](3)-epicatechin, and [epicatechin-(4beta-->8)](4)-epicatechin were among the key compounds contributing to the bitter taste as well as the astringent mouthfeel imparted upon consumption of roasted cocoa. In addition, a series of quercetin, naringenin, luteolin, and apigenin glycopyranosides as well as a family of not previously identified amino acid amides, namely, (+)-N-[4'-hydroxy-(E)-cinnamoyl]-L-aspartic acid, (+)-N-[3',4'-dihydroxy-(E)-cinnamoyl]-L-aspartic acid, (-)-N-[3',4'-dihydroxy-(E)-cinnamoyl]-L-glutamic acid, (-)-N-[4'-hydroxy-(E)-cinnamoyl]-L-glutamic acid, (-)-N-[4'-hydroxy-(E)-cinnamoyl]-3-hydroxy-L-tyrosine, (+)-N-[4'-hydroxy-3'-methoxy-(E)-cinnamoyl]-L-aspartic acid, and (+)-N-(E)-cinnamoyl-L-aspartic acid, have been identified as key astringent compounds of roasted cocoa. Furthermore, (-)-N-[3',4'-dihydroxy-(E)-cinnamoyl]-3-hydroxy-l-tyrosine (clovamide), (-)-N-[4'-hydroxy-(E)-cinnamoyl]-L-tyrosine (deoxyclovamide), and (-)-N-[3',4'-dihydroxy-(E)-cinnamoyl]-L-tyrosine, reported previously as antioxidants, have been found as contributors of cocoa's astringent taste. By means of the half-tongue test, the taste thresholds of flavan-3-ols and glycosides have been determined.  相似文献   

Grapefruit and oroblanco enhance hepatic detoxification enzymes in rats: possible role in protection against chemical carcinogenesis     

Hahn-Obercyger M  Stark AH  Madar Z 《Journal of agricultural and food chemistry》2005,53(5):1828-1832

Citrus fruits are considered to be functional foods that promote good health. This study was carried out to assess the effect of oroblanco and grapefruit consumption on hepatic detoxification enzymes. Male Sprague-Dawley rats were provided with either regular drinking water (control) or experimental treatments of oroblanco juice, grapefruit juice, or a sugar mix for 6 weeks. After 1 week of treatment, half the animals in each group were injected with the procarcinogen 1,2-dimethylhydrazine. Grapefruit juice significantly increased activity and expression of the hepatic phase I enzyme, cytochrome P450 CYP1A1, with a marked trend toward enhanced NAD(P)H:quinone reductase (QR) activity. Oroblanco juice significantly increased glutathione S-transferase phase II enzyme activity along with CYP1A1 expression and a notable trend toward increased activity of both CYP1A1 and QR. These results suggest that these citrus fruits are bifunctional inducers, modulating both phase I and phase II drug-metabolizing enzymes to enhance hepatic detoxification.  相似文献   

Restoring the capacity of spent mushroom compost to treat coal mine drainage by reducing the inflow rate: A microcosm experiment     

Lloyd R. Stark  William R. Wenerick  Frederick M. Williams  S. Edward Stevens Jr.  Paul J. Wuest 《Water, air, and soil pollution》1994,75(3-4):405-420

Four volumes of spent mushroom compost were exposed to synthetic coal mine drainage (pH 3.5, 48 mg L^?1 Fe, 22 mg L^?1 Mn) under oxidizing conditions (Eh 300 to 400 mV) at a relatively high rate of flow. After 15 days, the compost lost its ability to elevate pH, to lower the redox potential, to lower outlet iron concentrations, and to lower manganese concentrations, with larger volumes retaining more Fe and H⁺, but less Mn. Estimated retention maxima per liter of spent mushroom compost were 281 μeq H⁺, 5.56 g Fe, and 0.15 g Mn. These values are similar to those reported elsewhere for peat. The ‘saturated’ compost was then mixed and exposed to mine water in order to eliminate ‘dead zones’ in the compost. Subsequently, the compost was re-exposed to synthetic mine water (pH 4.0, 60 mg L^?1 Fe, O mg L^?1 Mn) under a much lower flow rate and less oxidizing regime for a period of 114 days. Under the low flow regime, iron was first exported from the compost as reducing conditions were established, and then retained on a stable basis. In addition, Eh was lowered and pH was elevated by the compost. On a net basis, the capacity of the compost to retain iron was increased and apparently stable under the decreased flow conditions.  相似文献   

Comparison of three serologic techniques for detection of antibody to Mycoplasma pulmonis     

E V Vincent  D M Stark  N Samberg  D F McBride 《The Cornell veterinarian》1984,74(1):21-29

A comparison of three micro-assay detection systems for naturally occurring and experimentally induced rat antibody to Mycoplasma pulmonis was performed. The micro-enzyme linked immunoabsorbent assay was found superior to counter immunoelectrophoresis or complement fixation techniques when comparing sensitivity, duration of antibody response, or technical requirements. The primary immune response was routinely detected at 3 weeks after antigen exposure when using the enzyme linked or complement fixation assays.  相似文献   

Ventricular septal defect repair in a small dog using cross-circulation     

GB HUNT  MRB PEARSON †  CR BELLENGER †  R. MALIK † 《Australian veterinary journal》1995,72(10):379-382

SUMMARY A haemodynamically significant ventricular septal defect was diagnosed in a 3-month-old male Cavalier King Charles Spaniel. A median sternotomy was performed and the 6.5 kg dog placed on cardiopulmonary bypass using pump-assisted cross-circulation. A 10 mm diameter peri-membranous ventricular septal defect was closed using a continuous suture of 4–0 polypropylene, via a 2.5 cm incision in the right ventricular outflow tract. The duration of cardiopulmonary bypass was 90 minutes. Complications in the immediate postoperative period were mild and easily managed.  相似文献   

Cross-reactive antigens of bovine streptococci     

D M Stark 《The Cornell veterinarian》1971,61(4):617-624

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Transmissible gastroenteritis virus in neonatal pigs: intestinal transfer of colostral immunoglobulins containing specific antibodies     

S S Stone  S L Stark  M Phillips 《American journal of veterinary research》1974,35(3):339-345

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Application of a molecular sensory science approach to alkalized cocoa (Theobroma cacao): structure determination and sensory activity of nonenzymatically C-glycosylated flavan-3-ols     

Stark T  Hofmann T 《Journal of agricultural and food chemistry》2006,54(25):9510-9521

Application of comparative taste dilution analyses on nonalkalized and alkalized cocoa powder revealed the detection of a velvety, smoothly astringent tasting fraction, which was predominantly present in the alkalized sample. LC-MS/MS analysis, 1D- and 2D-NMR, and CD spectroscopy as well as model alkalization reactions led to the unequivocal identification of the velvety, smoothly astringent molecules as a series of catechin- and epicatechin-C-glycopyranosides. Besides the previously reported (-)-epicatechin-8-C-beta-D-galactopyranoside, additional flavan-3-ol-C-glycosides, namely, (-)-epicatechin-8-C-beta-D-glucopyranoside, (-)-catechin-8-C-beta-D-glucopyranoside, (-)-catechin-6-C-beta-D-glucopyranoside, (-)-epicatechin-6-C-beta-D-glucopyranoside, (-)-catechin-8-C-beta-D-galactopyranoside, (-)-catechin-6-C-beta-D-galactopyranoside, (-)-catechin-6-C,8-C-beta-D-diglucopyranoside, (-)-epicatechin-6-C,8-C-beta-D-digalactopyranoside, (-)-catechin-6-C,8-C-beta-D-digalactopyranoside, and epicatechin-6-C,8-C-beta-D-diglucopyranoside, were identified for the first time in cocoa. Most surprisingly, these phenol glycoconjugates were demonstrated by model experiments to be formed via a novel nonenzymatic C-glycosylation of flavan-3-ols. Using the recently developed half-tongue test, human recognition thresholds for the astringent and mouth-drying oral sensation were determined to be between 1.1 and 99.5 micro mol/L (water) depending on the sugar and the intramolecular binding position as well as the aglycone.  相似文献