High water content silk protein-based hydrogels with tunable elasticity fabricated via a Ru(II) mediated photochemical cross-linking method     

Di Zhang  Han Peng  Baochang Sun  Shanshan Lyu 《Fibers and Polymers》2017,18(10):1831-1840

Silk is very promising in the field of biomaterials as a natural biomacromolecule. Silk protein can be made into various forms of materials, including hydrogels. However, silk protein-based hydrogels have not attracted much attention due to its weak mechanical properties. Here, we report high water content silk protein-based hydrogels with tunable elasticity which were fabricated through Ru(II) mediated photochemically cross-linking tyrosine residues in regenerated silk protein. The regenerated silk protein was characterized by Fourier transform infrared spectroscopy (FTIR). The gelation kinetics of the silk protein was studied by rheology measurements. The compressive mechanical properties of the silk protein-based hydrogels was investigated using compressive tests and dynamic mechanical analysis (DMA). Compressive modulus of the hydrogels reached 349±64 MPa at 15 % strain. The fabricated silk protein-based hydrogels were also characterized by Scanning electron microscopy (SEM), revealing an interconnected porous network structure, typical of hydrogels, with an average pore size of approximately 130 μm. Finally, biocompatibility of the silk protein-based hydrogels was demonstrated through cell culture studies using a human fibroblast cell line, HFL1. The reported silk protein-based hydrogels represent a promising candidate for biomaterial applications.  相似文献   

Characterization,Pathogenicity and Chemical Control of <Emphasis Type="Italic">Streptomyces acidiscabies</Emphasis> Associated to Potato Common Scab     

María Elena Santos-Cervantes  Ruben Felix-Gastelum  Gabriel Herrera-Rodríguez  Mariela Guadalupe Espinoza-Mancillas  Arlene Guadalupe Mora-Romero  Norma Elena Leyva-López 《American Journal of Potato Research》2017,94(1):14-25

The pathogenicity of 10 bacterial isolates was investigated on potato, radish, carrot and beet, including sensitivity and pathogen control efficacy. The isolates were identified by morphological, biochemical and molecular methods. All isolates were pathogenic on radish, carrot, and beet, and were highly virulent on potato. Although the isolates were obtained from different locations in the El Fuerte Valley (Sinaloa, Mexico), they were similar in their morphological, physiological and biochemical characteristics. Sequences of the 16S rRNA gene obtained by PCR were identical for all isolates. These results indicate that the bacterial isolates from potato scabby tissue belong to S. acidiscabies. Furthermore, the effectiveness of fluazinam, both in vitro and under greenhouse and field conditions, represents a possibleoption for chemical control of potato common scab disease. While our results suggest that spraying at seeding is effective in controlling common scab, future studies to combine this treatment with seed dressing before planting will be conducted to determine if there is an increase in disease control.  相似文献   

How Long can Rogued Potato Plants Left in the Field Be a Source of <Emphasis Type="Italic">Potato Virus Y</Emphasis> for Aphids?     

Sébastien Boquel  Jianhua Zhang  Xianzhou Nie 《American Journal of Potato Research》2017,94(1):81-87

Removal of diseased plants (roguing) is commonly practiced in seed potato production. Diseased plants left to desiccate in fields could possibly serve as sources of Potato virus Y (PVY). PVY acquisition by three aphid species (Myzus persicae, Rhopalosiphum padi, Aphis fabae) was evaluated with leaflets from rogued plants for seven days. Results showed greater PVY acquisition rates in non-colonizing aphids species compared to colonizing ones. The proportion of aphids leaving leaflets increased with time (i.e. days after plants were uprooted) and some aphids were carrying PVY in their stylets on each of the seven days of the experiment, suggesting that aphids were able to probe and acquire PVY even when plants wilted. These results confirmed that diseased plants left in fields can serve as a source of PVY for aphids even after they wilted and emphasises that proper actions must be taken to efficiently remove diseased plants from fields.  相似文献   

Effectiveness of Combined Use of Mineral Oil and Insecticide Spray in Reducing <Emphasis Type="Italic">Potato Virus Y</Emphasis> (PVY) Spread under Field Conditions in New Brunswick,Canada     

Tyler D. B. MacKenzie  Jacques Lavoie  Xianzhou Nie  Mathuresh Singh 《American Journal of Potato Research》2017,94(1):70-80

In the 2014 and 2015 crop seasons, the efficacies of different types, rates and combinations of mineral oil and insecticide foliar sprays for reducing Potato virus Y (PVY) spread were tested in controlled field trials in New Brunswick (NB), Canada. Experimental plots were planted with certified PVY-free Goldrush, supplemented with known virus-infected seed to raise PVY inoculum to 2.3% and 3% at the beginning of the 2014 and 2015 seasons, respectively. Treatments consisted of mineral oil-only sprays at different application rates, insecticide-only sprays of differing numbers, and several combined mineral oil and insecticide spray regimes, all compared to a no-spray control treatment. PVY spread to 18% (2014) and 22% (2015) of initially virus-free plants in no-spray control plots, with significant reductions observed in PVY spread in several treatments. Greatest PVY reductions, as low as 4% (2014) and 12% (2015), were in combined mineral oil and insecticide spray treatments, followed by oil-only sprays; while insecticide-only sprays did not significantly reduce PVY spread. As well as measuring PVY spread to marked test plants and randomly collected post-harvest tuber sample from the plots, exhibited similar treatment pattern for PVY incidence. Multiple logistic regression modeling confirmed the relative efficacy of combined oil and insecticide sprays for reducing PVY spread, while accounting for variable inoculum and aphid factors. Modeling also highlighted the importance of planting low-PVY seed initially, and of early application of foliar sprays. Local best management practice recommendations for reduction of in-field PVY spread were discussed.  相似文献   

Nano-calcium carbonate reinforced polypropylene and propylene-ethylene copolymer nanocomposites: Tensile vs. impact behavior     

Mangala Joshi  Satyajit Brahma  Anasuya Roy  S. Wazed Ali 《Fibers and Polymers》2017,18(11):2161-2169

Improvement of both the tensile and impact strength of the same polymeric material has always been a great challenge for the plastic industry. The study focuses on the effect of incorporation of calcium carbonate nanoparticles (0.3 wt% to 15 wt%) into three polypropylene (PP) based matrices viz. PP homopolymer, propylene-ethylene (PP-PE) copolymer and the blend of PP:PP-PE (30:70) to improve their impact behavior without hampering the tensile strength much. A loss in both the tensile and impact properties was observed in PP based nanocomposite. However, PP-PE based nanocomposites showed a significant improvement in impact strength (47 %) at 10 wt% loading with a loss of tensile strength by 22 %. To minimize this loss a blend of PP:PP-PE (30:70) was explored as a matrix. At 10 wt% loading, this matrix showed an improvement of 30 % in impact strength whereas the tensile loss was minimized to 10 %. Further, silane coupling agent which promoted good interfacial adhesion was used for best compositions. The variation of crystalline morphology of the nanocomposites with various formulations was analyzed using differential scanning calorimetry and X-ray diffraction.  相似文献   

Degradation and kinetic modeling of polyvinyl alcohol in aqueous solutions by a H<Subscript>2</Subscript>O<Subscript>2</Subscript>/Mn(II) system     

Yangfan Su  Mengjuan Li  Qiang Gao  Xiaoqiang Li  Anqi Ju  Yang Lu  Mingqiao Ge 《Fibers and Polymers》2017,18(12):2269-2277

This paper is about the degradation of polyvinyl alcohol (PVA) in aqueous solutions using a H2O2/Mn(II) system. Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC) were applied to analyze the degradation products of PVA, and the results revealed that the backbone chain of PVA could be effectively broken and oxidized. Several unsaturated degradation products, including carboxylic acids, ketones, aldehydes, olefins, and alkynes were also detected and identified by gas chromatography-mass spectrometry (GC-MS), which indicated that higher treatment temperatures would considerably promote the generation of lower molecular weight degradation products. According to the work presented in this paper, the degradation efficiency of PVA increased from 55 % at 60 oC to 99 % at 90 oC after treatment when the initial PVA concentration was 5 %, at pH=3 with a H2O2 and Mn(II) dose of 100 ml/l and 0.6 mol/l, respectively. In addition, kinetic modeling indicated that the experimental results were best fitted by the Page-modified model with an activation energy of 48.78 kJ/mol.  相似文献   

Dyeing performance of the azo dyes containing trifluoromethyl group for polyester fabrics and its single crystal structure     

Hongwei Shen  Liu Hu  Kongliang Xie  Aiqin Gao 《Fibers and Polymers》2017,18(12):2322-2327

The structures of disperse dyes and their intermolecular interactions have important impacts on dyeing and printing performances for polyester fabrics. The fluorine dyes show some unique molecular stability and photochemical properties. The dyeing property of the azo dye containing trifluoromethyl group for polyester fabrics, 4'-(N-acetoxyethyl-Nethyl)- amino-2-bromine-4-nitro-6-trifluoromethylazo- benzene (D1), was investigated and compared with the similar structure disperse dye. The results show that the high color yield and good exhaustion of the dyed PET fabrics could be obtained. The polyester fabrics dyed with D1 had excellent light fastness. Its single crystal was prepared and the supramolecular interactions were solved by X-ray diffraction. Dye D1 formed triclinic crystals in a trimeric packing mode. The C-F bond distances of CF3 are 1.2730 Å, 1.2240 Å and 1.2900 Å, respectively. The two benzene rings linked azo unit (-N=N-) are obviously twist. The dihedral angle of the two benzene rings is 50.23 o. There are six weak hydrogen bonds around trifluoromethyl group in the intramolecule and intermolecule. The excellent light stability of the dye should be attributed to its unique supramolecular structure.  相似文献   

Structural and optical properties of cellulose nanocrystals isolated from the fruit shell of <Emphasis Type="Italic">Camellia oleifera</Emphasis> Abel     

Jin Yao  Haibo Huang  Long Mao  Zhihan Li  Heping Zhu  Yuejun Liu 《Fibers and Polymers》2017,18(11):2118-2124

Cellulose nanocrystals (CNC) with high aspect ratio of 80 have been readily prepared from the inexpensive fruit shell of Camellia oleifera Abel (SCOA) for the first time. In this study, SOCA was consecutively subjected to alkali extraction, hydrogen peroxide bleaching and acid hydrolysis to remove non-cellulosic components and release CNC. The derived CNC possesses a needle-shaped structure that in average diameter and length of 6±2 nm and 500±100 nm, respectively. The crystallinity index of CNC increased to 72 % and the initial decomposition temperature raised to 230 oC. The obtained CNC was formed to nanopaper by vacuum filtration showing high visible light transmittance over 90 %. Thus SOCA derived CNC is of great practical potential to apply in the field of biomedicine, energy, packing, etc. Overall, this study is anticipated to offer new possibility for the CNC production from the inexpensive but abundant agricultural wastes.  相似文献   

Water and dye-free coloration of wool     

Guangming Cai  Zhenglin Xu  Bin Tang  Xungai Wang 《Fibers and Polymers》2017,18(1):102-109

A water and dye-free heat treatment method was used to color wool fibers. The heat effect changed wool fibers to different colors from white in a nitrogen atmosphere. The influences of heating temperature and time on the colors of wool were investigated and the mechanical property of colored wool fibers was evaluated. The color strength of wool fibers increased as heat treatment temperature and time increased. The tensile strength retention rate of wool fiber was relatively high (≥90 %) when the heat temperature was below 200 °C. The surface morphologies of wool fibers scarcely changed during the heat treatment. The carbon content of fibers was found to reduce by heat treatment, indicating oxidization of components in the wool fibers in the process of coloration. Heat treatment may provide a water and dye-free approach to color wool and other textile fibers, albeit within a limited color range.  相似文献   

Optimization of curing process for polymer-matrix composites based on orthogonal experimental method     

Tengfei Chang  Lihua Zhan  Wei Tan  Shujian Li 《Fibers and Polymers》2017,18(1):148-154

In this paper, the orthogonal experimental method was carried out to optimize the curing process of aeronautical composite X850/T800 in autoclave process. Four important curing parameters including curing pressure, heating rate, curing temperature and heat preservation time were taken into account, and sixteen samples were fabricated to study the effects of the four parameters mentioned above on the curing quality by interlaminar properties test and microstructure analysis. The interlaminar properties and the interfacial bonding quality of these samples were studied by the short-beam three points bending test and scanning electron microscopy, respectively. Results revealed that the optimal curing process of X850/T800 composite laminate should be as follows: curing pressure of 0.6 MPa, heating rate of 1.5 °C/min, curing temperature of 160 °C, and heat preservation time of 120 min.  相似文献