Studies on Selective Uptake Behavior of Hg(II) and Pb(II) by Functionalized Poly(Ethylene Terephthalate) Fiber with 4-Vinyl Pyridine/2-Hydroxyethylmethacrylate     

Zülfikar Temoçin  Mustafa Yiğitoğlu 《Water, air, and soil pollution》2010,210(1-4):463-472

The adsorption behavior of 4-vinyl pyridine and 2-hydroxyethylmethacrylate grafted poly(ethylene terephthalate) fiber toward the Hg(II) and Pb(II) ions in aqueous solutions was studied by a batch equilibration technique. The influence of the treatment time was considered as well as the pH of the solution, the initial metal ions concentration, the graft yield, and the temperature. Such parameters as the adsorption kinetics, the adsorption isotherm, and the desorption time were further studied. Maximum adsorption occurred at pH 3 and pH 6 for Hg(II) and Pb(II), respectively. The adsorption kinetics followed the mechanism of the pseudo-second-order equation for heavy metal ions. The adsorption data is a good fit with Freundlich isotherm. Desorption studies indicated that the maximum percent recovery of Hg(II) and Pb(II) was 93.4% and 76.3%, respectively with 1 M HNO₃.  相似文献   

Some descriptive characteristics of a new goat breed called Honamli in Turkey     

?zkan Elmaz  Mustafa Saatc?  Birol Da?  Ahmet Hamdi Akta?  Ayhan Ata  Mehmet ?ükrü Gülay  Nuri Mamak  Bekir G?k 《Tropical animal health and production》2012,44(8):1913-1920

This study has been carried out in the Western Mediterranean Region of Turkey on seven different Honamli goat flocks. The aim of this study was to determine the growth characters, survival rate (till weaning, 105th day), some reproductive characteristics and marketable milk yield. The data were collected from 516 does and 210 kids (125 buckling and 85 doelings). The results indicate that the numbers of multiple birth and litter size were 32.8 % and 1.35 respectively. Survival rates of kids at the 30th, 90th, and 105th days were 98.5, 97.2, and 97.2?%, respectively. The average birth weight for the buckling and doelings was 4.1 and 3.7?kg, respectively. The average weaning weights for buckling and doelings were 26.9 and 23.4?kg, respectively. The effects of dams?? age, on sex and birth type on the growth of Honamli kids were statistically significant (p?<?0.05, p?<?0.01, and p?<?0.001). While the diameters of erythrocytes of Honamli goats are smaller, the density of hemoglobin in the erythrocytes is more than Asian, Indian, and American caprine breeds. The average lactation length and marketable milk yield was assessed to be at 210.3?days and was 89?L, respectively. The growth characteristics of Honamli kids at weaning age were assessed to be higher than most of the other goat breeds in Turkey. The results further indicated that there is a significant variation in the production traits among the different Honamli goat flocks. Production traits of Honamli goats at different breeding conditions should further be investigated to come to a definite conclusion.  相似文献   

Field trial on comparative efficacy of four fasciolicides against natural liver fluke infection in cattle     

Elitok B  Elitok OM  Kabu M 《Veterinary parasitology》2006,135(3-4):279-285

A controlled trial was conducted to evaluate the current efficacy of albendazole (ABZ), rafoxanide (RFX), triclabendazole (TRC) or clorsulon (CLS) against Fasciola hepatica in naturally infected cattle. This trial was conducted in Turkey during the spring, the time of year when liver fluke infection is endemic. Fifty crossbred cattle were selected for inclusion in the trial based on finding eggs of F. hepatica in the feces. The cattle were weighed and randomly allotted into five groups of 10 cattle and treatments were as follows: Group 1 served as non-treated control (CONT), Group 2 was treated orally with ABZ at 12 mg/kg, Group 3 was treated orally with RFX at 10 mg/kg, Group 4 received TRC orally at 12 mg/kg and Group 5 received CLS administered subcutaneously (s.c.) at 2 mg/kg. On day 0 (inclusion day), individual fecal samples were collected on days 0 (inclusion day), 7, 14, 28 and 56, after treatment. The drug efficacy was assessed as a percentage of the egg or fluke reduction and body weight gain relative to the untreated control. The results in the study showed a mean reduction of egg counts by 66.7%, 68.2%, 78% and 84.2% in Groups 2-5, respectively. In conclusion, our results indicate that CLS is a highly effective compound for the treatment of F. hepatica in cattle under these field conditions.  相似文献   

Factors influencing acrylamide content and color in rye crisp bread     

Mustafa A  Andersson R  Rosén J  Kamal-Eldin A  Aman P 《Journal of agricultural and food chemistry》2005,53(15):5985-5989

An industrial baking procedure for yeast-leavened whole-grain rye crisp bread was adapted to local laboratory conditions to study the effect of time and temperature of baking and the addition of fructose, asparagine, and oat-bran concentrate on the acrylamide content and color of the bread. Baking time and temperature affected acrylamide content that increased from 10 to 30 mug/kg of bread at the combination of a long time and high temperature, with a significant interaction between the two factors (p < 0.008). Added asparagine had a significant effect (p < 0.001) on the formation of acrylamide, but fructose did not. There was a correlation between acrylamide content and color of the milled bread in the time-temperature experiment, but this correlation was not observed in the experiment with added precursors. Added oat-bran concentrate with high content of mixed-linkage beta-glucan did not influence the acrylamide content in the breads.  相似文献   

Novel total antioxidant capacity index for dietary polyphenols and vitamins C and E, using their cupric ion reducing capability in the presence of neocuproine: CUPRAC method   总被引：1，自引：0，他引：1  

Apak R  Güçlü K  Ozyürek M  Karademir SE 《Journal of agricultural and food chemistry》2004,52(26):7970-7981

The chemical diversity of antioxidants makes it difficult to separate and quantify antioxidants from the vegetable matrix. Therefore, it is desirable to establish a method that can measure the total antioxidant activity level directly from vegetable extracts. The current literature clearly states that there is no "total antioxidant" as a nutritional index available for food labeling because of the lack of standard quantitation methods. Thus, this work reports the development of a simple, widely applicable antioxidant capacity index for dietary polyphenols and vitamins C and E, utilizing the copper(II)-neocuproine [Cu(II)-Nc] reagent as the chromogenic oxidizing agent. Because the copper(II) (or cupric) ion reducing ability of polyphenols is measured, the method is named by our research group "cupric reducing antioxidant capacity" abbreviated as the CUPRAC method. This method should be advantageous over the ferric reducing antioxidant power (FRAP) method because the redox chemistry of copper(II)-as opposed to that of ferric ion-involves faster kinetics. The method comprises mixing of the antioxidant solution (directly or after acid hydrolysis) with a copper(II) chloride solution, a neocuproine alcoholic solution, and an ammonium acetate aqueous buffer at pH 7 and subsequent measurement of the developed absorbance at 450 nm after 30 min. Because the color development is fast for compounds such as ascorbic acid, gallic acid, and quercetin but slow for naringin and naringenin, the latter compounds were assayed after incubation at 50 degrees C on a water bath for 20 min [after Cu(II)-Nc reagent addition] so as to force the oxidation reaction to reach completion. The flavonoid glycosides were hydrolyzed to their corresponding aglycons by refluxing in 1.2 M HCl-containing 50% MeOH so as to exert maximal reducing power toward Cu(II)-Nc. Certain compounds also needed incubation after acid hydrolysis to fully exhibit their reducing capability. The CUPRAC antioxidant capacities of synthetic mixtures of antioxidants were experimentally measured as Trolox equivalents and compared to those theoretically found by making use of the principle of additivity of absorbances assuming no chemical interaction between the mixture constituents. Because ascorbic acid is not resistant to elevated temperature incubation, it should be assayed initially by measuring the absorbance (at 450 nm) difference of original and ascorbate oxidase-added mixture solutions at the end of 1 min of Cu(II)-Nc reagent addition. Thus, the total CUPRAC antioxidant capacity of a mixture containing various antioxidants should be that finally measured after a suitable combination of hydrolysis and incubation procedures, added to the initially measured capacity due to ascorbate. The antioxidant polyphenolic compounds tested demonstrate that the highest capacities in the CUPRAC method were observed for epicatechin gallate, epigallocatechin gallate, quercetin, fisetin, epigallocatechin, catechin, and caffeic acid in this order, in accordance with theoretical expectations, because the number and position of the hydroxyl groups as well as the degree of conjugation of the whole molecule are important. The antioxidant potency of flavonoids is nearly proportional to the total number of -OH groups and is positively affected by the presence of an o-dihydroxy moiety in the B-ring. beta-Carotene, which did not react with the CUPRAC reagent in alcoholic aqueous medium, could be assayed in dichloromethane solvent. Linear calibration curves for ascorbic acid and flavonoids were redrawn in synthetic solutions containing a mixture of antioxidants, and also in real matrices such as grape and orange juices, green tea, and blackberry tea, showing an initial nonzero absorbance with the CUPRAC reagent. The parallellism of the linear calibration curves of pure compounds in a given complex matrix effectively demonstrated that there were no interferent chemical interactions among the solution constituents and that the antioxidant capacities of the tested antioxidants were additive. The CUPRAC reagent is reasonably selective, stable, easily accessible, and sensitive toward thiol-type oxidants, unlike the FRAP method. The reaction is carried out at nearly physiological pH as opposed to the unrealistic acidic pH of FRAP.  相似文献   

Effects of deficit irrigation on the yield and yield components of drip irrigated cotton in a mediterranean environment   总被引：1，自引：0，他引：1  

Mustafa Ünlü  R?za KanberD. Levent Koç  Servet TekinBurçak Kapur 《Agricultural Water Management》2011,98(4):597-605

A field study on cotton (Gossypium hirsutum L., cv.) was carried out from 2005 to 2008 in the Çukurova Region, Eastern Mediterranean, Turkey. Treatments were designated as I₁₀₀ full irrigation; DI₇₀, DI₅₀ and DI₀₀ which received 70, 50, and 0% of the irrigation water amount applied in the I₁₀₀ treatment. The irrigation water amount to be applied to the plots was calculated using cumulative pan evaporation that occurred during the irrigation intervals. The effect of water deficit or water stress on crop yield and some plant growth parameters such as yield response, water use efficiencies, dry matter yield (DM), leaf area index (LAI) as well as on lint quality components was evaluated. The average seasonal evapotranspiration ranged from 287 ± 15 (DI₀₀) to 584 ± 80 mm (I₁₀₀). Deficit irrigation significantly affected crop yield and all yield components considered in this study. The average seed cotton yield varied from 1369 ± 197 (DI₀₀) to 3397 ± 508 kg ha⁻¹ (I₁₀₀). The average water use efficiency (WUE_ET) ranged from 6.0 ± 1.6 (I₁₀₀) to 4.8 ± 0.9 kg ha⁻¹ mm⁻¹ (DI₀₀), while average irrigation water use efficiency (WUE_I) was between 9.4 ± 3.0 (I₁₀₀) and 14.4 ± 4.8 kg ha⁻¹ mm⁻¹ (DI₅₀). Deficit irrigation increased the harvest index (HI) values from 0.26 ± 0.054 (I₁₀₀) to 0.32 ± 0.052 kg kg⁻¹ (DI₅₀). Yield response factor (Ky) was determined to be 0.98 based on four-year average. Leaf area index (LAI) and dry matter yields (DM) increased with increasing water use. This study demonstrated that the full irrigated treatment (I₁₀₀) should be used for semiarid conditions with no water shortage. However, DI₇₀ treatment needs to be considered as a viable alternative for the development of reduced irrigation strategies in semiarid regions where irrigation water supplies are limited.  相似文献   

Ovarian response and embryo yield of Angora and Kilis goats given the day 0 protocol for superovulation in the non-breeding season     

Taşdemir U  Ağaoğlu AR  Kaymaz M  Karakaş K 《Tropical animal health and production》2011,43(5):1035-1038

The aim of this study was to compare ovarian response and embryo yield of Day 0 protocol in Angora goats (AG) and indigenous Kilis goats (KG) in the non-breeding season. A total of 16 Angora goats (AG group) and 11 Kilis goats (KG group) were used in this study. In the synchronization process, after controlled internal drug release withdrawal, when estrus signs were observed, natural mating was performed. Ovarian response was determined by synchronized laparotomy 6 days after natural mating, and number of corpora lutea (CL) was recorded. Embryos were collected and morphologically evaluated by stereomicroscope. Synchronization rates did not differ between AG (88%, 14/16) and KG group (91%, 10/11). In AG and KG groups, the proportion of CL on the right (44% and 53%, respectively) and left (56% and 47%, respectively) ovaries were similar. The CL number per animal did not differ significantly between the two breeds and was determined as 4.4 ± 0.90 in AG group and 6.4 ± 1.44 in KG group. Transferable embryo yields were significantly higher in AG group (31/42, 74%) compared to KG group (16/46, 35%) in the non-breeding season (P < 0.01). In conclusion, it is suggested that the day 0 protocol can be used for goat superovulation in the non-breeding season; however, transferable embryo yields are affected by the breed.  相似文献   

Variations in heavy metal concentrations among trophic levels of the food webs in two agroecosystems     

Mustafa Soliman  Mohamed El-Shazly  Emtithal Abd-El-Samie  Hamed Fayed 《African Zoology》2019,54(1):21-30

Excessive accumulation of trace metal in soil represents a growing environmental problem posing severe risks to biota, humans and ecosystems. Concentrations of Cd, Pb, Cu and Zn were determined in soil, as well as in representatives of some trophic levels in the terrestrial food webs in two Egyptian agroecosystems; El-Manzala (a rural area located in the northeast of the River Nile Delta) and El-Tebbin (an industrial area located in South Cairo). Representatives of trophic levels included arthropods, amphibians, reptiles, birds and small mammals. Metal concentrations were determined in the leaves of wild plants, bodies of arthropods and livers of vertebrates. Levels of metals in the soil, plants and most animal species were higher in El-Tebbin than El-Manzala. Minimal concentrations of metals were detected more often in plants and in the cattle egret, whereas maximum values were common in the soil, amphibians and a mantid. Accumulation of metals was more frequent in arthropods and other taxa at lower trophic levels of food webs, suggesting that the transfer of metals along the vertebrate food web may be of relatively minor importance. However, of all the metals examined, only Pb was bioaccumulated to any appreciable extent in some of the higher trophic levels. A significant increase in liver mass and relative liver mass of the Norway rat from the polluted site was observed.  相似文献   

Deltamethrin raises potassium activity in the microenvironment of the central nervous system of the cockroach: An assessment of the potential role of the blood-brain barrier in insecticide action     

Christopher H. Hendy  Mustafa B. A. Djamgoz 《Pest management science》1988,24(4):289-298

The effect of deltamethrin (10μm) on extracellular K ⁺ activity in the micro-environment of the central nervous system of the cockroach has been studied. At normal room temperature, deltamethrin induced a rise in the K ⁺ concentration of about 3 mM, representing some 75% increase from normal Deltamethrin also caused a transient surge in the frequency of spontaneous activity, which preceded the K ⁺ effect. At a lowered temperature, the final value of the deltamthrin-induced rise in extracellular K ⁺ concentration was very similar to normal. However, when the structural component of the blood-brain barrier was disrupted, the effect of deltamethrin was much reduced. Possible consequences of the deltamethrin-induced rise in extracellular K ⁺ concentration and the potential role of the blood-brain barrier in insecticide action are discussed.  相似文献   

Effectiveness of different avian influenza (H5) vaccination regimens in layer chickens on the humoral immune response and interferon-alpha signalling immune marker     

Mustafa Hamad  Omar Amen  Mohamed Mahmoud  Ola Hassanin  Mostafa Saif-Edin 《Veterinary research communications》2018,42(2):145-152

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