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81.
Resistance to the bacteria-derived insecticides spinosad (Conserve), abamectin (Vertimec), Bacillus thuringiensis var kurstaki (Btk) (Dipel), B thuringiensis var aizawai (Bta) (Xentari), B thuringiensis crystal endotoxins Cry1Ac and Cry1Ca, and to the synthetic insecticide fipronil was estimated in a freshly-collected field population (CH1 strain) of Plutella xylostella (L) from the Cameron Highlands, Malaysia. Laboratory bioassays at G1 indicated significant levels of resistance to spinosad, abamectin, Cry1Ac, Btk, Cry1Ca, fipronil and Bta when compared with a laboratory insecticide-susceptible population. Logit regression analysis of F1 reciprocal crosses indicated that resistance to spinosad in the CH1 population was inherited as a co-dominant trait. At the highest dose of spinosad tested, resistance was close to completely recessive, while at the lowest dose it was incompletely dominant. A direct test of monogenic inheritance based on a back-cross of F1 progeny with CH1 suggested that resistance to spinosad was controlled by a single locus.  相似文献   
82.
在红火蚁严重发生地区进行的药效试验表明,0.5%硫氟磺酰胺饵剂投放后15d药效开始发挥,25d后处理蚁巢全部死亡,药后70d调查结果显示,其对红火蚁的校正防治效果高达94.1%;0.001%氟虫腈饵剂撒施后15d开始发挥药效,30d后蚁巢中无工蚁活动,药后70d调查显示其对红火蚁的防治效果为90.9%;0.5%苯氧威饵剂撒施后40d,在蚁巢中仍能监测到工蚁的活动,70d后调查结果表明其对红火蚁的防治效果为84.9%。统计分析结果说明,0.5%硫氟磺酰胺饵剂和0.001%氟虫腈饵剂对红火蚁的防治效果好于0.5%苯氧威饵剂。由于0.001%氟虫腈饵剂和0.5%苯氧威饵剂是实验室临时配制,虽然其对红火蚁的诱食性较差,但仍能表现较好的防治效果。0.5%硫氟磺酰胺饵剂和0.001%氟虫腈饵剂可以用于红火蚁的防治,0.5%苯氧威饵剂配方需要进一步改进。  相似文献   
83.
BACKGROUND: Fipronil, a phenylpyrazole insecticide, and its oxidative sulfone metabolite are two potential pollutants from treated rice and cotton production. A consequence of these pollutants occurring in surface runoff is degradation of downstream aquatic ecosystems. Utilization of primary intercept drainage ditches as management practices to reduce fipronil concentrations and loads has not been examined. This study used ditch mesocosms planted with monospecific stands of common emergent wetland vegetation to determine if certain plant species were more proficient in fipronil mitigation. RESULTS: Three replicates of four plant species were compared against a non-vegetated control to determine differences in water column outflow concentrations (microg L(-1)) and loads (microg). There were no significant differences between vegetated and control treatments in outflow concentrations (F = 0.35, P = 0.836) and loads (F = 0.35, P = 0.836). The range of fipronil reduction was 28-45% for both concentration and load. Unlike fipronil, fipronil sulfone concentrations and load increased by 96-328%. CONCLUSION: The increase in fipronil sulfone was hypothesized as a direct consequence of oxidation of fipronil within each mesocosm. The type of ditch vegetation had no effect on fipronil reduction. Future research needs to examine initial concentrations and hydraulic retention times to examine potential changes in reduction capacities.  相似文献   
84.
氟虫腈在三种土壤中的降解特性研究   总被引:5,自引:0,他引:5  
实验室条件下,研究了氟虫腈在东北黑土、江西红壤和太湖水稻土中的降解特性。结果表明,氟虫腈在土壤中降解较慢,其在好气条件下的东北黑土、江西红壤和太湖水稻土中的降解半衰期分别为165、267和42 d,在渍水条件下的3种土壤中的降解半衰期分别为31、173和32 d。氟虫腈在pH 偏中性的太湖水稻土中降解最快;微生物对氟虫腈在土壤中的降解起主要作用;渍水条件有利于氟虫腈的降解,推测降解氟虫腈的微生物主要是厌氧菌属。  相似文献   
85.
以氯虫苯甲酰胺和氟虫腈的结构为基础,通过活性亚结构拼接的方法,设计合成了24个新型含吡唑杂环邻氨基苯甲酰胺类化合物,其结构经1H NM R、IR及APCI-M S表征。初步生物活性测试结果表明:化合物5-溴-N-[4-氯-2-甲基-6-(甲氨基甲酰基)苯基]-1-1-[2,6-二氯-4-(三氟甲基)苯基]-4-三氟甲基亚磺酰基-1H-吡唑-3-甲酰胺(5k)和5-溴-N-[4-溴-2-甲基-6-(甲氨基甲酰基)苯基]-1-[2,6-二氯-4-(三氟甲基)苯基]-4-三氟甲基亚磺酰基-1H-吡唑-3-甲酰胺(5l)在500 mg/L下对朱砂叶螨Tetranychus cinnabarinus的致死率为100%,但在100 mg/L下其致死率则分别降至30%和50%。所得结果可为邻氨基苯甲酰胺类化合物构效关系研究提供参考。  相似文献   
86.
87.
利用荧光标记法及分子模拟法,研究了氟虫腈与昆虫γ-氨基丁酸(aminobutyric acid,GABA)受体的相互作用。荧光标记试验结果显示,氟虫腈与家蝇脑内GABA受体有较强的相互作用,其最大结合量[RT]值和亲和常数Kd值分别为(21.3±2.5) pmol/mg protein和(109±9) nmol/L。分子模拟结果显示:氟虫腈与果蝇RDL受体间形成3条氢键;两者之间的CDOCKER的相互作用能为-137.93 kJ/mol。试验和理论两方面均证实,氟虫腈对昆虫GABA受体的强亲和性是导致氟虫腈对昆虫产生高毒性的重要原因。  相似文献   
88.
BACKROUND: Fipronil is an insecticidal pyrazole that is commonly used as an insecticide in field crops, urban pesticide and veterinary medicine, but there are no reports of its evaluation against stored‐product insects. Three series of laboratory bioassays were conducted to assess fipronil as a potential grain protectant against adults of Sitophilus oryzae (L.), Tribolium confusum Jacquelin du Val, Rhyzopertha dominica (F.) and Prostephanus truncatus (Horn). Factors such as dose (0.01, 0.1, 1 and 10 mg fipronil kg?1 grain), exposure interval (24 h, 48 h, 7 days and 14 days), temperature (20, 25 and 30 °C), relative humidity (RH; 55 and 65%) and commodity (wheat, maize, barley and paddy rice) were evaluated with regard to their impact on the insecticidal activity of fipronil. Progeny production was assessed after 64 days of exposure. RESULTS: At doses of < 1 mg fipronil kg?1 grain, efficacy of fipronil was enhanced by an increase in temperature from 20 to 25 °C against S. oryzae or R. dominica for exposures of > 48 h and against T. confusum or P. truncatus for exposures of > 24 h. A further increase in temperature from 25 to 30 °C, although it enhanced efficacy at doses of < 1 mg fipronil kg?1 grain against S. oryzae at all exposure intervals and against T. confusum after 7 days of exposure, it was negatively associated with efficacy against R. dominica or P. truncatus for exposures of > 24 h. By contrast, increase in RH did not have a significant impact on efficacy of fipronil. Although the performance of fipronil among the tested commodities was species dependent, this substance appeared to be less effective in paddy rice than in barley, maize and wheat. Regardless of the treated commodity, progeny production of all the tested species was almost suppressed with doses higher than 0.1 mg fipronil kg?1 grain. CONCLUSIONS: Fipronil appeared to be a very effective alternative to the existing substances in stored‐grain protection at doses equal to or higher than 1 mg fipronil kg?1 grain, and thus these doses require further evaluation in terms of safety for the consumer and residues on stored products. Copyright © 2010 Society of Chemical Industry  相似文献   
89.
研究了阿维菌素、氟虫腈两种药剂对小菜蛾\[Plutella xylostella (Linnaeus)\]3龄幼虫的毒力及对 其取食的影响。Potter喷雾法处理后,两种农药处理中的试虫校正死亡率均随着时间的推移而逐渐升高 ,但叶片保护率却有降低趋势,且在阿维菌素低浓度处理中更明显。浸叶法处理后,试虫校正死亡率与叶 片保护率均随时间的推移而升高,在阿维菌素的72 h处理中,除了10.00 mg/L、0.31 mg/L两个浓度处理 中试虫校正死亡率与叶片保护率相近外,其余均为叶片保护率显著高于校正死亡率。而氟虫腈的处理中 ,则除了12.50 mg/L浓度处理中的叶片保护率与试虫校正死亡率相近外,其余均为试虫校正死亡率与叶 片保护率相近。最后讨论了叶片保护率在农药毒力评价中的意义。  相似文献   
90.
为评价新型有机硅表面活性剂对水生生物的影响,采用"半静态法"分别研究了乙氧基改性三硅氧烷(捷润,JIERUN)和硅氧烷化合物(好湿,High-Speed)与3种农药对斑马鱼的急性毒性与联合毒性。结果表明:"捷润"和"好湿"对斑马鱼的LC50值(96 h)分别为有效成分5.90和17.4 mg/L,分别属于中毒和低毒。"捷润"与氟虫腈、茚虫威和乙酰甲胺磷混用后对斑马鱼的共毒系数分别为139.52、107.24和165.65,其联合毒性效果分别为增毒、相加和增毒;"好湿"与氟虫腈、茚虫威和乙酰甲胺磷混用后对斑马鱼的共毒系数分别为111.36、48.26和80.08,其联合毒性效果分别为相加、拮抗和相加。  相似文献   
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