超声波降解苹果汁中展青霉素动力学研究   总被引：2，自引：0，他引：2  

高振鹏  刘瑞  张德举  袁亚宏  岳田利 《农业机械学报》2015,46(11):230-235

为了掌握超声波降解苹果汁中展青霉素的动力学特性,在前期超声波降解苹果汁中展青霉素的研究基础上,利用拟一级反应动力学方程对超声波影响因素中超声波功率、频率及温度降解苹果汁中展青霉素的试验数据进行拟合,确定相关参数,进一步建立各影响因素降解速率常数与相关影响因子之间的关系方程。结果表明:超声波功率对苹果汁中展青霉素的降解符合拟一级反应方程,超声波功率为490 W时,降解率最大;功率降解速率常数kP与超声波功率的方程为kP=6×10-5P-0.011 7。超声波频率对展青霉素的降解符合拟一级反应方程,超声波频率为45 k Hz时,降解率最大;频率降解速率常数kf与超声波频率f的关系方程为kf=-8×10-4f2+0.111 9f-2.512 6。温度对苹果汁中展青霉素的降解符合拟一级反应方程,温度为30℃时,降解率最大;温度降解速率常数kT与温度T的关系方程为kT=-1×10-4T2+0.006 1T-0.076 9。  相似文献   

酞酸酯类增塑剂对土壤─作物系统的影响   总被引：47，自引：1，他引：47  

安琼  靳伟  李勇  徐瑞薇 《土壤学报》1999,36(1):118-126

本研究揭示了酞酸酯类增塑剂邻苯二甲酸二丁酯（ＤＢＰ）和邻苯二甲酸二异辛酯（ＤＥＨＰ）在土壤中的持留动态,降解动力学特征及其对作物生长的影响。结果表明：试验温度越低,ＤＢＰ,ＤＥＨＰ的持留性越强;ＤＥＨＰ在土壤中的持留性受温度的影响程度比ＤＢＰ更为突出。随土壤水份含量增加,代停工物持留性降低,二者在土壤中的降解可用一级反应动力学方程Ｃ＝Ｃ０ｅ＾－ｋｔ进行描述（Ｃ０初始浓度,Ｋ速度常数,ｔ时间）。ＤＥ  相似文献   

Degradability of atrazine, cyanazine, and dicamba in methanogenic enrichment culture microcosms using sediment from the Pearl River of Southern China     

Chen Lin  Ji-Guang Gu  Chuanling Qiao  Shunshan Duan  Ji-Dong Gu 《Biology and Fertility of Soils》2006,42(5):395-401

Degradation of three herbicides, atrazine, cyanazine and dicamba, was assessed in laboratory microcosms incubated under simulated methanogenic conditions using sediment from Pearl River of Southern China as an inoculum. Atrazine was much more resistant to degradation than cyanazine and dicamba over 300 days of incubation. Biodegradation of cyanazine and dicamba was further substantiated by establishment of enrichment transfer cultures in which the degradation of the respective herbicide was accelerated by the active microorganisms. Degradation of cyanazine initially involved the removal of chlorine and the two side chains, while that of dicamba was O-demethylation reaction forming 3,6-dichlorosalicyclic acid. Results suggest that biodegradation of xenobiotics can be established through enrichment culture transfer technique, and further mechanism of degradation and microorganisms involved can be elucidated.  相似文献   

除草剂草甘膦的性质及环境行为综述   总被引：31，自引：0，他引：31  

卢信  赵炳梓  张佳宝  邓建才  李立平  信秀丽 《土壤通报》2005,36(5):785-790

草甘膦是一种广谱、非选择性芽后除草剂,它被越来越广泛地应用于农业。本文总结了草甘膦的一些基本性质及其在环境中的行为和降解机理,概述了国内外的研究现状,及影响其在土壤环境去向的一些因素,如土壤性质、磷酸盐、重金属和DOC的存在等,为进一步研究提供一些建设性的参考。  相似文献   

城市土壤的压实退化及其环境效应   总被引：17，自引：2，他引：17  

杨金玲  汪景宽  张甘霖 《土壤通报》2004,35(6):688-694

城市土壤普遍存在严重的压实退化现象。由于压实的影响,土壤物理性质发生了显著的改变:结构破坏、容重和硬度增大、孔隙度和渗透性降低。这些重要的变化对土壤生物活动、土壤物理-化学平衡和氧化还原状况、土壤的过滤和缓冲性能都产生影响。由此对环境产生严重的负面效应:地下水的自然回灌减少,地表径流量增加,降雨的径流洪峰加快、加大,地表水体的污染负荷增加。土壤温度、微生物活动、养分转化都不同于自然土壤,植物的生长也受到严重的影响。  相似文献   

Arthrobacter sp. AG1菌株降解土壤中阿特拉津研究     

代先祝  蒋建东  李荣  李顺鹏 《土壤》2008,40(5):754-759

在阿特拉津浓度为50mg/kg干土的黄棕壤、潮土和红壤接种1.5×106CFU/g干土的降解菌Arthrobacter sp. AG1,10天后土壤中的阿特拉津分别降解至1.5、6.6和10mg/kg干土。阿特拉津的降解速率受到土壤性质的影响,但AG1仍能在不满足其生长繁殖要求的pH值的土壤中有效降解酸性土壤中阿特拉津;土壤中水分含量对降解效果影响较大,>20%时降解效果较好;土壤低含水量和低pH值会导致AG1降解阿特拉津的活力下降。不同的接种量对降解效果有一定影响,但105～107CFU/g干土接种量的AG1都能有效发挥降解作用。AG1降解完土壤中的阿特拉津后,在土壤含水量分别为5%和15%的情况下能长期保持降解活性,对60天后第2次施入黄棕壤和潮土中的50mg/kg阿特拉津4天时降解效率在65%以上。  相似文献   

黑土环境中乙草胺的微生物降解特征研究     

冯慧敏  何红波  武叶叶  张旭东  张明 《土壤通报》2008,39(2):379-383

通过室内恒温(25℃)避光培养试验,研究了黑土环境中乙草胺的微生物降解特征。在适宜水分条件下,将土壤样品分别进行常规、灭菌、选择性抑菌剂加入等处理后培养并测定土壤乙草胺含量和土壤微生物量。结果显示:在灭菌土壤中乙草胺的残留量较未灭菌土壤显著增加,未灭菌土壤中乙草胺残留数量与微生物量变化密切相关,表明微生物活性是影响乙草胺降解的主要因素。适当的水分有益于土壤中微生物生长,从而促进了土壤中乙草胺的降解。加入青链霉素后乙草胺残留量远大于放线菌酮和常规培养,表明细菌比真菌具有更强的降解乙草胺的能力。随着乙草胺的施药量增加,初期微生物量显著降低,是导致乙草胺总降解率下降的主要原因。  相似文献   

乐斯本乳油在小麦和土壤中的残留试验   总被引：6，自引：0，他引：6  

戴荣彩  陈莉  陈家梅  夏福利  余苹中 《华北农学报》2006,21(1):133-135

2000~2001年分别在北京市郊区和武汉市郊区进行了48%乐斯本乳油在小麦和土壤中残留消解规律和最终残留量的研究。结果表明,其有效成分毒死蜱在小麦上的半衰期为2.5~4.2 d,土壤上的半衰期为3.7~9.5 d;在用量375~750 g/hm2、施用1~2次的情况下,小麦麦粉中残留量为未检出(<0.011)~0.038 mg/kg,麦秸中残留量为未检出(<0.045)~0.960 mg/kg,土壤中残留量则均未检出(<0.006 mg/kg)。  相似文献   

Future of land use in Australia: An economic perspective     

C. Mues  D. Peterson  T. Walshaw  P. Morris 《Land Degradation \u0026amp; Development》1994,5(2):127-141

It is proposed that the standard economist's model of optimum land use is extended to include the interaction with land cover and land condition. Such a model allows consideration of the influence of market factors and government policies and programmes on land use patterns and management practices, and the feedback effect on land cover and land condition. Recent developments in the approach to modelling land condition, which include the joint consideration of economic factors and physical processes, are discussed. Factors affecting the pattern of agricultural land use in Australia are then reviewed. The importance of considering economic and physical interactions when assessing land use patterns is increasingly being recognized in research and policy development. If research is to meet the needs of land managers in the future then economists and physical scientists will need to integrate their data modelling capabilities in order to address natural resource management issues.  相似文献   

Trends in natural resource use and prospects for sustainable resource management in Kenya's Arid and Semiarid Lands     

M. B. K. Darkoh 《Land Degradation \u0026amp; Development》1990,2(3):177-190

This paper describes the environmental problems facing the development of Kenya's Arid and Semiarid lands (ASAL) today. The problems arise because of a rapidly declining resource base in the ASAL as a result of overexploitation and misuse, following basic land use conflicts. The extent of the overutilization or resource damage is not well known and varies a great deal from one agroecological zone to another and from resource to resource in the ASAL; those most affected include: soil, water, range, forest, livestock and wildlife. As a result of increased population growth in the ASAL, these resources are under stress. This paper argues that many of the environmental problems in the ASAL cannot be solved if the development programme does not address the needs of the people who live in the ASAL. There is a need to shift the objective of ASAL development from a preoccupation with economic growth and the idea that the ASAL should make a contribution to GNP through interregional trade and export to sustainable development that enables the communities in the ASAL to support themselves at as good a standard of living as possible. The last part of this paper outlines a strategy to promote such sustainable development.  相似文献