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1.
Penndorf I Biedermann D Maurer SV Henle T 《Journal of agricultural and food chemistry》2007,55(3):723-727
To obtain information about the extent of the early Maillard reaction between the N-termini of peptides and lactose, alpha-N-(2-furoylmethyl) amino acids (FMAAs) were quantified together with epsilon-N-(2-furoylmethyl)lysine (furosine) in acid hydrolyzates of hypoallergenic infant formulas, conventional infant formulas, and human milk samples using RP-HPLC with UV-detection. FMAAs are formed during acid hydrolysis of peptide-bound N-terminal Amadori products (APs), and furosine is formed from the Amadori products of peptide-bound lysine. Unambiguous identification was achieved by means of LC/MS and UV-spectroscopy using independently prepared reference material. The extent of acid-induced conversion of APs to FMAAs was studied by RP-HPLC with chemiluminescent nitrogen detection (CLND). Depending on the corresponding alpha-N-lactulosyl amino acid, between 6.0% and 18.1% of FMAAs were formed during hydrolysis for 23 h at 110 degrees C in 8 N HCl. From epsilon-N-lactulosyllysine, 50% furosine is formed under these conditions. Whereas furosine was detectable in all assayed samples, five different FMAAs, alpha-FM-Lys, alpha-FM-Ala, alpha-FM-Val, alpha-FM-Ile, and alpha-FM-Leu, were exclusively detected in acid hydrolyzates of hypoallergenic infant formulas in amounts ranging from 35 to 396 mumol/100 g protein. Taking the conversion factors into account, modification of N-terminal amino acids in peptides by reducing carbohydrates was between 0.3% and 8.4%. This has to be considered within the discussion concerning the nutritional quality of peptide-containing foods. 相似文献
2.
The ability of scanning tunneling microscopy to probe the pathways of thermally activated high-barrier surface processes is frequently limited by competing low-barrier processes that can confuse measurement of the true initial and final configuration. We introduce an approach to circumvent this difficulty by driving the surface process with nanosecond laser heating. The method is applied to determine the pathway of recombinative desorption in the H/Si(001) system. The observed configuration of dangling bonds after laser heating reveals that the desorbed hydrogen molecules are not formed on single dimers, but rather from neighboring silicon dimers via an interdimer reaction pathway. 相似文献
3.
Urban habitats, particularly wastelands and brownfields, maintain rich biodiversity and offer habitat for many species, even rare and endangered taxa. However, such habitats are also under socio-economic pressures due to redevelopment for housing and industrial uses. In order to maintain urban biodiversity, it is currently unknown how much open area must be preserved and whether conservation is possible without complete exclusion from economic development. In this study, we applied a simulation model based on species distribution models for plants, grasshoppers, and leafhoppers to investigate planning options for urban conservation with special focus on business areas. Altogether, we modelled the occurrence of 81 species of the urban species pool and analysed settings of different proportions of open sites, different habitat turnover times, and different lot sizes. Our simulations demonstrated that dynamic land use supports urban biodiversity in terms of species richness and rarity. Setting aside brownfields before redevelopment for a period of on average 15 years supported the highest conservation value. Consequently, we recommend integrating the concept of ‘temporary conservation’ into urban planning for industrial and business areas. This concept requires habitat to be destroyed by redeveloping brownfield sites to built-up sites, but simultaneously creating new open spaces due to abandonment of urban land uses at other locations. This maintains a spatio-temporal mosaic of different successional stages ranging from pioneer to pre-forest communities. 相似文献
4.
The ovulation status and the amount of ovulated follicles were determined in 3 experiments from 197 gilts which had been given differentiated treatment and which were subsequently slaughtered. Ovulation stimulation produced high synchronisation effects, as compared to untreated animals. Partial substitution proved possible of Gn-RH vet. "Berlin-Chemie" for 500 I.U. of HCG which were generally used to stimulate ovulation, since the amount of ovulated follicles 169 hours from the last application of Suisynchron premix was in all 3 cases above the specified value of 85.0 per cent even after injection of 300 I.U. HCG/300 micrograms Gn-RH. 相似文献
5.
Biedermann W Lücker E Hensel A 《Berliner und Münchener tier?rztliche Wochenschrift》2002,115(3-4):131-133
Determination of specified risk material (SRM) in processed meat products was performed by quantification of brain specific fatty acids using gas chromatography-mass spectrometry (GC-MS). Results from SMP (internal standardised meat products) based analyses showed that absolute concentrations of CNS are correlated (r2 = > 0.97) with the contents of the CNS typical fatty acids docosahexaenoic acid (C 22:6), nervonic acid (C 24:1), lignoceric acid (C 24) and cerebronic acid (C 24oh). GC-MS detection limits were measured at 0.01% CNS. The cut off value was calculated at 0.39% (w/w) CNS in SMP. In a controlled blindfold experiment we were able to identify correctly all positive and negative SMP samples, respectively. Our results indicate that GC-MS based SRM detection may serve as a reference method for immunochemical and immunohistochemical determination of SRM in processed meat products. 相似文献
6.
Potential of acrylamide formation,sugars, and free asparagine in potatoes: a comparison of cultivars and farming systems 总被引：7，自引：0，他引：7
Amrein TM Bachmann S Noti A Biedermann M Barbosa MF Biedermann-Brem S Grob K Keiser A Realini P Escher F Amadó R 《Journal of agricultural and food chemistry》2003,51(18):5556-5560
Glucose, fructose, sucrose, free asparagine, and free glutamine were analyzed in 74 potato samples from 17 potato cultivars grown in 2002 at various locations in Switzerland and different farming systems. The potential of these potatoes for acrylamide formation was measured with a standardized heat treatment. These potentials correlated well with the product of the concentrations of reducing sugars and asparagine. Glucose and fructose were found to determine acrylamide formation. The cultivars showed large differences in their potential of acrylamide formation which was primarily related to their sugar contents. Agricultural practice neither influenced sugars and free asparagine nor the potential of acrylamide formation. It is concluded that acrylamide contents in potato products can be substantially reduced primarily by selecting cultivars with low concentrations of reducing sugars. 相似文献
7.
Gugliuzzo Antonio Biedermann Peter H. W. Carrillo Daniel Castrillo Louela A. Egonyu James P. Gallego Diego Haddi Khalid Hulcr Jiri Jactel Hervé Kajimura Hisashi Kamata Naoto Meurisse Nicolas Li You Oliver Jason B. Ranger Christopher M. Rassati Davide Stelinski Lukasz L. Sutherland Roanne Tropea Garzia Giovanna Wright Mark G. Biondi Antonio 《Journal of pest science》2021,94(3):615-637
We provide an overview of both traditional and innovative control tools for management of three Xylosandrus ambrosia beetles (Coleoptera: Curculionidae: Scolytinae), invasive species with a history of damage in forests, nurseries, orchards and urban areas. Xylosandrus compactus, X. crassiusculus and X. germanus are native to Asia, and currently established in several countries around the globe. Adult females bore galleries into the plant xylem inoculating mutualistic ambrosia fungi that serve as food source for the developing progeny. Tunneling activity results in chewed wood extrusion from entry holes, sap outflow, foliage wilting followed by canopy dieback, and branch and trunk necrosis. Maintaining plant health by reducing physiological stress is the first recommendation for long-term control. Baited traps, ethanol-treated bolts, trap logs and trap trees of selected species can be used to monitor Xylosandrus species. Conventional pest control methods are mostly ineffective against Xylosandrus beetles because of the pests’ broad host range and rapid spread. Due to challenges with conventional control, more innovative control approaches are being tested, such as the optimization of the push–pull strategy based on specific attractant and repellent combinations, or the use of insecticide-treated netting. Biological control based on the release of entomopathogenic and mycoparasitic fungi, as well as the use of antagonistic bacteria, has yielded promising results. However, these technologies still require validation in real field conditions. Overall, we suggest that management efforts should primarily focus on reducing plant stress and potentially be combined with a multi-faceted approach for controlling Xylosandrus damage.
相似文献8.
In this paper, habitat models were used to predict potential habitat for endangered species, which is an important question in landscape and conservation planning. Based on logistic regression, we developed habitat distribution models for the burnet moth Zygaena carniolica and the nymphalid butterfly Coenonympha arcania in Northern Bavaria, Germany. The relation between adult occurrence and habitat parameters, including the influence of landscape context, was analyzed on 118 sites. Habitat connectivity analyses were carried out on the basis of (1) habitat suitability maps generated from these models and (2) dispersal data from mark recapture studies. Our results showed that (1) the presence of the burnet depended mainly on the presence of nectar plants and of nutrient-poor dry grasslands in direct vicinity, that of the nymphalid on larger areas of extensively used dry grasslands within 100 m vicinity in combination with small patches of higher shrubs and bushes. (2) Internal as well as external validation indicated the robustness and general applicability of the models. Transferability in time and space indicated their high potential relevance for applications in nature conservation, such as predicting possible effects of land use changes. (3) Habitat connectivity analyses revealed a high degree of habitat connectivity within the study area. Thus, we could show no effects of isolation or habitat size for both species. 相似文献
9.
Mira Kattwinkel Barbara Strauss Robert Biedermann Michael Kleyer 《Landscape Ecology》2009,24(7):929-941
The importance of the spatial as well as the temporal structure of habitat patches for urban biodiversity has been recognised,
but rarely quantified. In dynamic environments the rate of habitat destruction and recreation (i.e. the landscape turnover
rate), the minimum amount of potential habitat, its spatial configuration as well as the environmental conditions determining
habitat quality are crucial factors for species occurrence. We analysed species responses to environmental parameters and
to the spatio-temporal configuration of urban brownfield habitats in a multi-species approach (37 plant and 43 insect species).
Species presence/absence data and soil parameters, site age, vegetation structure and landscape context were recorded by random
stratified sampling at 133 study plots in industrial areas in the city of Bremen (Germany). Based on the field data, we predicted
species occurrences by species distribution models using a multi-model inference approach. Predicted species communities were
driven by successional age both at the scale of a single building lot and at the landscape scale. Minimum average succession
time of brownfield habitats required to support all and especially regionally rare species depended on the proportion of available
open space; the larger the potential habitat area the faster the acceptable turnover. Most plant, grasshopper, and leafhopper
species modelled could be maintained at an intermediate turnover rate (mean age of 10–15 years) and a proportion of open sites
of at least 40%. Our modelling approach provides the opportunity of inferring optimal spatio-temporal landscape configurations
for urban conservation management from patch scale species-environment relationships. The results indicate that urban planning
should incorporate land use dynamics into the management of urban biodiversity.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
10.
Fiorini D Fiselier K Biedermann M Ballini R Coni E Grob K 《Journal of agricultural and food chemistry》2008,56(23):11245-11250
The contamination of 11 commercial grape seed oils with paraffins of mineral oil origin was analyzed by online-coupled HPLC-HPLC-GC-FID and ranged from 43 to 247 mg kg(-1). The analysis of the marc and seeds indicated that the contamination is primarily from the peels. Since superficial extraction of the seeds with hexane removed most of the mineral paraffins, the contamination of the seeds is largely on the surface, perhaps transferred from the peels during storage of the marc. Mechanical purification of the seeds combined with washing with hexane reduced the contamination of the oil by a factor of about 10. The refining process removed 30% of the mineral paraffins, primarily the more volatile components. Oil obtained from the seeds of fresh grapes, including grapes not having undergone any phytochemical treatment, contained clearly less mineral paraffins (up to 14 mg kg(-1)), and the peels were less contaminated, suggesting an environmental background contamination. To this an additional contamination might be added by a treatment of the grapes used for wine making. 相似文献