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十氯酮污染土壤上根茎作物收割部分的污染状况   总被引:3,自引:0,他引:3  
A bacterial strain, Arthrobacter oxydans (B4), capable of degrading benzo[a]pyrene (BaP) in water body, was isolated from a polycyclic aromatic hydrocarbons-contaminated site. Effects of different factors, such as reaction time, pH value, temperature and organic nutrients, on BaP biodegradation by the strain B4 were studied. After 5 d treatment, the concentration of BaP in mineral salts medium was reduced to 0.318 mg L-1 , compared to the initial concentration of 1.000 mg L-1 . There was a process of acid formation during the degradation with pH falling from initial 7.01 to 4.61 at 5 d, so keeping the water body under slightly alkaline condition was propitious to BaP degradation. Strain B4 efficiently degraded BaP at 20 to 37 ℃ with addition of organic nutrients. The biodegradation and transformation of BaP mainly occurred on cell surfaces, and extracellular secretions played an important role in these processes. Fourier transform infrared spectroscopy and gas chromatograph-mass spectrometer analyses of metabolites showed that ring cleavage occurred in the BaP degradation process and the resulting metabolically utilizable substrates were generated as sole carbon sources for B4 growth. Furthermore, mineralization extent of metabolites was verified by determining the total organic carbon and inorganic carbon in the degradation system.  相似文献   
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The structural voids in vertisols contain easily available water for plants and their volume can be calculated from the shrinkage curve. Access by plants to that water depends also on the geometric arrangement of the pores so that the water can flow through them. We have devised a method for studying the structural porosity by casting the pores in resin. The intraprism pore space of wet soil clods is impregnated with a UV fluorescent polyester resin under vacuum. When this has set we use the swelling properties of the clay to separate the clay matrix from the resin. A cast so obtained is the real three-dimensional solid reproduction of the structural porosity. This representation of the pore system is easier to study than results from computerized reconstitution of the three-dimensional space from two-dimensional images of soil in thin sections. Channels, packing pores and planar voids can be observed directly in three dimensions as the method saves the integrity and continuity of pores as small as 10 μm in diameter. The geometry of the cast shapes agrees with the interpretation of shrinkage and moisture characteristic curves. The method offers direct qualitative observation of pore organization and volume measurements of the intraprism structural porosity in vertisols.  相似文献   
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