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1.
Lattice mismatch stresses, which severely restrict heteroepitaxial growth, are greatly minimized when thin alumina films are grown by means of van der Waals forces on inert mica substrates. A 10-nanometer-thick epitaxial film exhibits crystallographic sixfold symmetry, a lattice constant close to that of the basal plane [0001] of alpha-alumina (sapphire), and an aluminum: oxygen atomic ratio of 1:1.51 +/- 0.02 (measured by x-ray photoelectron spectroscopy), again the same as for bulk sapphire. The film is free of steps and grain boundaries over large areas and appears to be an ideal model system for studying adhesion, tribology, and other surface phenomena at atomic scales.  相似文献   
2.
Diffuse reflectance Fourier transform mid infrared (FTMIR) and near-infrared spectroscopy (FTNIR) were compared to scanning monochromator-grating-based near-infrared spectroscopy (SMNIR), for their ability to quantify fatty acids (FA) in forages. A total of 182 samples from thirteen different forage cultivars and three different harvest times were analyzed. Three calibration analyses were conducted for lauric (C12:0), myristic (C14:0), palmitic (C16:0), stearic (C18:0), palmitoleic (C16:1), oleic (C18:1), linoleic (C18:2), and alpha-linolenic (C18:3) acids. When all samples were used in a one-out partial least squares (PLS) calibration, the average R (2) were FTNIR (0.95) > SMNIR (0.94) > FTMIR (0.91). Constituents C18:2 and C16:0 had among the highest R (2) regardless of the spectroscopic method used. The FTNIR did better for C12:0, C14:0, and C18:3. The SMNIR did better for C16:0, C16:1, C18:0, C18:1, and C18:2. A second set of calibrations developed with half of the samples as the calibration set and the rest as the validation set showed that all the methods produce acceptable calibrations, with calibration R (2) above 0.9 for most constituents. However, the SMNIR had a better average calibration relative error than the FTNIR, which was slightly better than the FTMIR. A third set of calibration equations developed using 100 random PLS runs with the 182 samples split randomly also shows that the three spectral methods are satisfactory for predicting FA. It is not clear whether any of the spectral methods is distinctly better than another. Calibration R (2) and validation R (2) were higher for most FA with the SMNIR than the FTMIR and FTNIR.  相似文献   
3.
The goal of this research was to determine the potential for use of site-specific management of corn hybrids and plant densities in dryland landscapes of the Great Plains by determining (1) within-field yield variation, (2) yield response of different hybrids and plant densities to variability, and (3) landscape attributes associated with yield variation. This work was conducted on three adjacent fields in eastern Colorado during the 1997, -98, and -99 seasons. Treatments consisted of a combination of two hybrids (early and late maturity) and four plant densities (24,692, 37,037, 49,382 and 61,727 plants ha-1) seeded in replicated long strips. At maturity, yield was measured with a yield-mapping combine. Nine landscape attributes including elevation, slope, soil brightness (SB) (red, green, and blue bands of image), ECa (shallow and deep readings), pH, and soil organic matter (SOM) were also assessed. An analysis of treatment yields and landscape data, to assess for spatial dependency, along with semi variance analysis, and block kriging were used to produce kriged layers (10 m grids). Linear correlation and multiple linear regression analysis were used to determine associations between kriged average yields and landscape attributes. Yield monitor data revealed considerable variability in the three fields, with average yields ranging from 5.43 to 6.39 Mg ha-1 and CVs ranging from 20% to 29%. Hybrids responded similarly to field variation while plant densities responded differentially. Economically optimum plant densities changed by around 5000 plants ha-1 between high and low-yielding field areas, producing a potential savings in seed costs of $6.25 ha-1. Variability in yield across the three landscapes was highly associated with landscape attributes, especially elevation and SB, with various combinations of landscape attributes accounting for 47%, 95%, and 76% of the spatial variability in grain yields for the 1997, -98, and -99 sites, respectively. Our results suggest site-specific management of plant densities may be feasible.  相似文献   
4.
Triticale’s forage-yield response to fertilizer nitrogen (N) is impressive on soils testing low in available N. Our objectives were to (1) quantify the forage-yield response of dryland winter triticale to applied N and residual nitrate N and (2) fit the yield data to a regression equation based on both applied N and residual soil nitrates and use the fitted equation to calculate economic optimum N rates for this crop (EONR). Winter triticale was direct seeded no-till into wheat or millet stubble for four site years at the United States Department of Agriculture, Agricultural Research Service (USDA-ARS) Central Great Plains Research Station. In each experiment (1995, 2007, 2009 and 2010) just prior to planting, the soil was sampled for nitrate-N. Replicated field plots were top-dressed with 0, 22, 34, 67, 90, 101 or 135 kg of N fertilizer per ha as urea-N. Yield and total biomass N was then measured in each plot in late spring each year. A relative yield N response equation, fitted to all four years of data, was able to explain 93% of the variability in yield. That equation provided reasonable EONR estimates that matched 87% of the EONRs calculated for individual years.  相似文献   
5.
The method of fertilizer nitrogen (N) application can affect N uptake in tall fescue and therefore its yield and quality. Subsurface-banding (knife) of fertilizer maximizes fescue N uptake in the poorly-drained clay-pan soils of southeastern Kansas. This study was conducted to determine if knifed N results in greater N uptake than the conventional top-dress application method in a deep, well-drained soil of east-central Kansas. The experiment, conducted in a Smolan silty clay loam soil, was a split-plot with fertilizer nitrogen rates 0, 140 and 280 kg N ha?1 applied as urea-ammonium nitrate (UAN, 28% N), knifed or top-dressed. Soil inorganic N [ammonium (NH4)- and nitrate (NO3–N)] and N in roots and plant tops were measured at various times during the growing season. At final harvest, most of the knifed N (99.7%) was accounted for in plant tissue (roots and tops) and soil, with more than half of the knifed N remaining as soil inorganic N. With the top-dressed method, 27% was unaccounted for and presumed lost in gaseous form. Knifing fertilizer N in fescue fields of east-central Kansas will maximize the availability of N, reduce potential N losses, and increase forage quality.  相似文献   
6.
One of the problems to affect Portland cement matrices is low resistance to aggressive agents, due principally to the presence of a high content of portlandite in the hydrated cements. Pozzolanic materials have, for decades, played an important role in improving the durability of cement-based materials. This work studies the behaviour of cement mortar matrices blended with 10% calcined paper sludge (source for metakaolin, MK) and exposed to different environmental conditions (marine and tableland environments). The results obtained using X-ray diffraction and scanning electron microscopy/energy-dispersive X-ray analyser techniques show that the ions present speed of different penetration as well as various phases and/compounds in the matrices following exposure over 1 year.  相似文献   
7.
Critical precipitation period for dryland maize production   总被引:1,自引:0,他引:1  
Grain yields for dryland maize (Zea mays L.) production in the semi-arid Great Plains of the United States can be unpredictable because of the erratic nature of growing season precipitation. Because of the high input costs for maize production, farmers need to have a tool that will help them assess the risk associated with dryland maize production. The objectives of this work were to determine the critical period for precipitation during the maize growing season and to develop a relationship between critical period precipitation and maize yield to use as a tool to quantify expected yield variability associated with dryland maize production in this region. Maize yield data were collected at Akron, CO from two dryland cropping systems experiments (1984–2009) in which maize was grown in a 3-year winter wheat (Triticum aestivum L.)–maize–fallow rotation. Yields were correlated with weekly precipitation amounts from planting to harvest in search of the period of time in which yield was most influenced by precipitation. Soil water contents at planting were measured either by gravimetric sampling or by neutron attenuation. Yields were found to be most closely correlated with precipitation occurring during the 6-week period between 16 July and 26 August. The data separated into two linear relationships defined by whether the sum of available soil water at planting and May precipitation was less than or greater than 250 mm. These two linear relationships between precipitation during this critical period and yield were used with long-term precipitation records to determine the probability of obtaining a maize yield of at least 2500 kg ha−1 (generally considered to be a break-even yield) at three locations across the central Great Plains precipitation gradient. This analysis quantified the production risk associated with the highly variable corn yields that result from erratic summer precipitation in this region.  相似文献   
8.
Because its relevance for the sustenance and livelihood of human systems, the assessment of the impacts that future climatic conditions may have on agricultural productivity becomes a key piece of information for agricultural scientists and policy makers.  相似文献   
9.
Salmonids of the genus Oncorhynchus, distributed throughout the Pacific Rim, can be infected by the gill lice species Salmincola californiensis (Dana, 1852), which makes them one of the most broadly distributed gill lice species. Despite their broad distribution and valuable obligate salmonid hosts, relatively little is known about S. californiensis. We evaluated effects of temperature on timing of S. californiensis hatching and survival of copepodids, and provide information on brood size and variability. Our results suggest that temperature was a primary driver of timing of S. californiensis hatching and post‐hatching survival. Prior to this study, the free‐swimming stage of S. californiensis was reported to survive approximately 2 days without a suitable host. We observed active copepodids 13 days after hatch with some individuals from most (>90%) viable egg sacs at all temperature treatments surviving ≥5 days. Our findings indicate that warmer temperatures could increase development rates of gill lice at certain life stages, potentially increasing fecundity. This information coupled with predictions that warmer water temperatures could intensify crowding of coldwater fishes, stress, and parasite transmission suggests that climate change could exacerbate negative effects of S. californiensis on ecologically and economically important salmonids.  相似文献   
10.
Farmers in the central Great Plains want to diversify crop rotations from the traditional monoculture system of winter wheat-fallow. Corn (Zea mays L.) could work well as a rotation crop, but inputs are expensive and farmers would like to know the chances of producing a certain yield before investing in seed, fertilizer, herbicides, etc. Information on the yield response of corn to available soil water at planting could help guide the crop choice decision regarding corn. This study was conducted to determine if a predictive relationship exists between dryland corn yield and available soil water at planting time and, if such a relationship exists, to use it to assess the risk in obtaining profitable yields. Yield and soil water data from 10 years of a dryland crop rotation study at Akron, CO were analyzed by linear regression to determine predictive relationships. The yield-soil water content production function was highly variable, with values ranging from 0.0 to 67.3 kg ha−1 per mm of available soil water in the 0 to 1.8 m soil profile at planting. The differences in yield response to soil water were related to the amount and timing of precipitation that fell during the corn growing season. Because dryland corn yield is highly dependent on precipitation during reproductive and grain-filling stages, soil water content at corn planting cannot be used alone to reliably determine whether corn should be planted in a flexible rotational system. The predictive relationships developed in this study indicate that under typical amounts of available soil water at corn planting, profitable corn production under dryland conditions is a risky and speculative activity in the central Great Plains of the United States.  相似文献   
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