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基于XPS的苹果表皮残留农药界面层的氩刻分析 总被引：1，自引：1，他引：0
针对果皮表面残留农药进行微观深度探测及分析。结果表明,苹果表皮氧乐果及敌敌畏随施药浓度及施药时间的残留沿纵向深度变化呈现非线性规律性,主要残留部位为果实表皮的角质层区距表面8μm,氧乐果残留分布的规律性强于敌敌畏。 相似文献
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X－ray photoelectron spectroscopy(XPS) was applied to examine the N structures of soil humic substances and some of their analogues.It was found that for soil humic substances XPS method gave similar results as those obtained by ^15N CPMAS NMR (cross-polarization magic-angle spinning nuclear magnetic resonance) method.70%-86% of total N in soil humic substances was in the form of amide,and 6%-13% was presented as ammes,with the remaining part as heterocyclic N.There was no difference in the distribution of the forms of N between the humic substances from soils formed over hundreds or thousands of years and the newly formed ones.For fulvic acid from weathered coal and benzoquinone-(NH4)2SO4 polymer the XPS results deviated significantly from the ^15N CPMAS NMR data. 相似文献
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用复合镀法制得Ｎｉ－Ｗ－ＷＣ－ＷＯ３复合电极，在０．５ｍｏｌ／ＬＨ２ＳＯ４中的氢超电势比软钢降低２８０ｍＶ，ｉ０提高三个数量级，电极表面粗糙度为Ｎｉ电极的三倍。在３００ｍＡ／ｃｍ＾２的大电流密度下，进行的长期恒电流电解试验表明电极性能稳定。ＸＰＳ分析证明电极表面主要成分为Ｎｉ，Ｗ，ＷＣ，ＷＯ３等。 相似文献
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A type of TiO 2 /bamboo charcoal composite made by a dip-dry method was loaded onto wood veneer with a vacuumpressure method in order to prepare modified poplar veneer.The pore structure parameters and surface morphology of the TiO 2 /bamboo charcoal composite were determined and analyzed by means of a porosimetry analyzer and SEM.The results show that the surface morphology of the composite does not change after being loaded with nano TiO 2.However,its specific surface area (359.814 m 2 ·g-1),pore volume (0.317 cm 3 ·g-1) and average pore diameter (3.526 nm) increased;particularly the cumulative volume of pores was increased by 65.83%.In addition,the distribution range of the pores was wider than that of the bamboo charcoal.Combining the SEM of unmodified and modified poplar veneer,the results of X-ray photoelectron spectroscopy revealed that actually some TiO 2 compounds,i.e.,4.08%,are imbedded in the modified poplar veneer. 相似文献
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We explored the discoloration of rattan cane using X-ray photoelectron spectroscopy(XPS) and Fourier transform infrared spectroscopy(FTIR). XPS analysis showed that after the cane was stained by Lasiodiplodia theobromae, carbon and oxygen elements and the ratio of oxygen to carbon decreased. Considering atomic binding,C_1 and C_4 contents increased, while C_2 and C_3 contents decreased, and the ratio of O_2 to O_1 decreased sharply. The relative contents of lignin, cellulose and polysaccharides increased and new substances with low O_2/O_1 ratio occurred. FTIR analysis showed that the absorption peaks of O–H at 3346 cm-1, aliphatic C–H at 2921, 2853 and1464 cm-1, and C=O at 1723 cm-1, were characteristic peaks of fungal melanin intensified, indicating that cane discoloration was primarily caused by fungal melanin. The absorption peaks characterizing cellulose and lignin like polysaccharides at 800 cm-1, C–H at 1374 cm-1, C–O at1058 and 1038 cm-1, phenolic hydroxyl at 1245 cm-1,aromatic ether bonds at 1270 cm-1, carbon skeleton at1608 cm-1 and benzene ring at 1500 cm-1 were enhanced since the fungus mainly consumed the extractives in cane cell lumens and the main composition content increased relatively. Regardless of the discoloration caused by natural fungi or inoculated fungi, the discoloring feature and composition changes were identical except that the fungusinoculated cane had more melanin. 相似文献
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利用生物矿化原理制备木材—SiO2复合材料,采用溶胶—凝胶法制备硅溶液,用不同质量分数的硅溶液对喜树进行浇灌和滴注试验。经过1个月的试验得到样品,利用光电子能谱仪(XPS)分析素材和SiO2复合材样品中硅、碳的质量比,证实喜树成功吸收硅元素,并且存活,植株根茎附近生长较好,枝叶较多,顶部附近枝叶较少。比较浇灌、滴注2种方法:①浇灌过程相对简单,树木对硅的吸收相对较少;使用质量分数越高的药品对树木进行浇灌,树木对硅的吸收越好。②滴注过程相对复杂,树木对硅的吸收相对较多;使用质量分数越高的药品进行滴注,树木对硅的吸收越好;但吸收不均匀,呈滴注孔口附近往树梢方向减少趋势。前期研究结果表明,对树木进行浇灌和滴注,药品硅的质量分数过高树木会死亡,过低则达不到要求,因此,最佳质量分数配制还有待于进一步研究确定。总的来说,利用生物矿化原理模拟木材—SiO复合材是可行的。 相似文献
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The preparation technology and thermal treatment PT thin film used in infrareddetector and photo-electron devices are studied. The er thin film prepared by multi-ion-beam reac-tive co-sputtering apparams are analysised by x-ray , XPS and EPMA. The impurity of PbO,Pb2Ti2O6 in PT thin film is eleminated and PbTiO3 (001)preferred orientation is improved. The rea-sonable teperature of substrates is given in this paper. 相似文献
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X射线光电子能谱(XPS)在木质材料研究领域中的应用 总被引：1，自引：0，他引：1
近年来,X射线电子能谱(XPS)不断出现在木材表面及界面研究中,成为木材研究领域中重要的分析手段。为深化对XPS在木质材料研究领域应用的认识,扩展其在该领域的应用空间,对XPS在木质材料研究领域的成果结合实例进行阐述,说明XPS在木质材料研究领域尤其是表面及界面的研究中的应用现状。XPS的利用将提高木材及木质结构单元的质量及使用寿命,提高对短缺的木材资源的利用效率。 相似文献