排序方式： 共有45条查询结果，搜索用时 109 毫秒
1.
从二硫代磷酸二乙酯钠盐或O,O-二乙基硫代磷酰氯出发 ,经酯化、去烷基化反应得到相应的硫代或二硫代铵盐 ,分别与 2 -氯 - 5 -氯甲基吡啶反应得产物 2 a～ 2 c。从 O-乙基硫代磷酰二氯或苯基硫代膦酰二氯出发 ,先与取代苯酚或甲胺反应 ,然后与 2 -氯 - 5 -羟甲基吡啶反应得到产物 2 d～ 2 k和 2 m～ 2 u。O-乙基 - S-丙基二硫代磷酰氯、O-乙基硫代磷酰二氯和苯基硫代膦酰二氯与 2 -氯 - 5 -羟甲基吡啶反应分别得产物 2 l、2 v和 2 w。所合成的 2 3个新化合物对9种植物病菌的离体及活体杀菌活性测试表明 ,其中一些化合物对水稻稻瘟病和水稻纹枯病有一定活性 ,个别化合物活性很好 ,但对其它病菌的活性均较低 相似文献
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以对硝基苯胺和合成得到的2-溴-4-硝基苯胺为原料, 采用Gomberg-Bachmann芳基偶联反应,合成了两种电致磷光材料的关键中间体2-(4-硝基苯基)吡啶和2-(2-溴-4-硝基苯基)吡啶,并通过1HNMR确证了产物结构.研究结果表明,该合成方法简单、可行,芳基偶联产物2-(4-硝基苯基)吡啶和2-(2-溴-4-硝基苯基)吡啶的产率分别达到了22.5%和5.9%,其中前者超过文献报道水平,后者未见文献报道. 相似文献
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Novel 2-amino-4-(4-methoxyphenyl)-6-(piperidin-1-yl)pyridine-3,5-dicarbonitrile is synthesized using malononitrile, 4-methoxybenzaldehyde and piperidine as starting material in methanol by one-spot. The yield is 40% with three-component reaction at room temperature. The structure is confirmed by 1H NMR, MS and X-ray single crystal diffraction. 相似文献
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Bruce L. Finkelstein Melissa A. Martz Christopher J. Strock 《Pest management science》1997,50(4):319-323
A model has been developed which has led to the design and synthesis of novel 6-methanesulfonyloxypyridine-2-carboxamides with insecticidal activity, low mammalian toxicity and safety to aquatic organisms. The amides formed from amines with α branching (e.g. isopropyl and sec-butyl) demonstrated the highest level of activity. Rice nursery box field test results on laboratory raised insects gave insufficient control of the entire Japanese hopper spectrum to warrant further development of these compounds. © 1997 SCI 相似文献
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生化抑制剂组合与施肥模式对黄泥田稻季氨挥发的影响 总被引：4，自引：2，他引：2
为探讨生化抑制剂组合与施肥模式对黄泥田稻季氨挥发的影响,采用二因素随机区组设计,研究生化抑制剂组合[N-丁基硫代磷酰三胺(NBPT)、N-丙基硫代磷酰三胺(NPPT)和2-氯-6-(三氯甲基)吡啶(CP)]与施肥模式(一次性和分次施肥)互作对黄泥田稻季氨(NH3)挥发动态变化的影响。结果表明:黄泥田稻季NH3挥发损失主要集中于施肥后1周,峰值发生在第1~3 d。生化抑制剂组合与施肥模式对黄泥田稻季NH3挥发损失量的效应显著。尿素分次施用处理稻季NH3挥发净损失率较一次性施用处理显著降低24.6%。不同施肥模式下,硝化抑制剂CP处理显著提高田面水NH+4-N峰值和NH3挥发速率峰值,增加稻田NH3挥发损失量;脲酶抑制剂NBPT/NPPT或配施CP处理明显延缓尿素水解,降低NH3挥发速率峰值,减少稻田NH3挥发损失量。新型脲酶抑制剂NPPT单独施用及与CP配施的稻田NH3挥发动态变化与NBPT相似。相关性分析表明,稻田NH3挥发速率与田面水NH+4-N浓度和pH值呈显著正相关,而与气温、土温和土壤相对湿度无显著相关性。总之,生化抑制剂组合与适宜的运筹相结合更能有效减少黄泥田稻季NH3挥发损失。 相似文献
6.
[目的]探讨季铵盐化合物溴代十六烷基吡啶（CPB）对夏季月季鲜切花瓶插期间保鲜状况的影响。[方法]分别检测蒸馏水（对照）、30g/L蔗糖＋0.25g/L柠檬酸＋0.3g/L8-HQS（处理Ⅰ）、30g/L蔗糖＋0.25g/L柠檬酸＋0.3g/L8-HQS＋0.1g/LCPB（处理Ⅱ）瓶插液中微生物浓度,并且测定了各组月季鲜切花水分、衰老等生理指标和观赏价值。[结果]与不含CPB的处理Ⅰ相比,保鲜液中添加0.1g/LCPB（处理Ⅱ）瓶插液中微生物密度降低66.5%,花冠直径增大0.86cm,观赏寿命延长3.70d,切花后期的水分平衡和鲜重能较好地维持,花瓣衰老减缓。[结论]CPB作为可降解的杀菌剂对夏季月季切花具有较好的保鲜效果。 相似文献
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吡啶衍生物研究(Ⅷ):2-[(2-氯吡啶)-4-基]-5-烷氨基-1,3,4-噻二唑的合成及其除草活性 总被引：5，自引：0，他引：5
为寻找新的农药先导化合物 ,依据活性亚结构拼接原理 ,以异烟酸为起始原料 ,共合成了 12个标题化合物 ,其结构通过元素分析、1H和13 CNMR予以确认。所有化合物均具有一定的除草活性 ,且茎叶处理高于土壤处理 ,其中Ⅰ 0 4和Ⅰ 0 6在 1 5kg·hm-2 剂量下 ,茎叶处理对反枝苋、稗草、油菜和苜蓿的抑制率分别达 71 9%～89 2 %和 4 5 3%～ 87 0 % ;因此 ,该类化合物具有作为除草先导化合物进一步研究的价值 相似文献
10.
Poly ion complexes of anionic lignosulfonic acid (LSA) with cationic poly(2-vinyl pyridine) or poly(4-vinyl pyridine) were
prepared by mixing the polymer solutions in dimethyl sulfoxide or dilute hydrochloric acid. The complexes were formed as soon
as the polymer solutions were mixed. Fourier transform infrared (FTIR) measurements for the complexes revealed the presence
of strong ionic interactions between sulfonate anions of LSA and pyridinium cations of the vinyl pyridine (VPy) polymers.
The strong interaction was supported by detection of a glass transition temperature (T
g) much higher than pristine T
g values of VPy polymers in differential scanning calorimetry. By using the ionic complexation, a coating of LSA onto VPy polymer
films was undertaken to modify their original surface property. Formation of a thin complex film was confirmed by observation
of absorption bands that are characteristic of the pyridinium cation in reflection FTIR spectra measurements, and by visualization
of the attached LSA component in atomic force microscopy. This treatment resulted in the surface of the VPy polymer films
becoming hydrophobic. An adhesion test was also conducted by pasting two veneered woods with the polymer complex, followed
by shear-tearing them off. The adhesive strength of the complex was estimated to be 1.1 MPa.
Part of this report was presented at the 55th (Kyoto, March 2005) and 56th (Akita, August 2006) Annual Meetings of the Japan
Wood Research Society 相似文献