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OBPA防霉聚乙烯保鲜膜的研究
引用本文:杜林雪,李喜宏,陆书,来王彪,罗金山,刘海娇.OBPA防霉聚乙烯保鲜膜的研究[J].中国果菜,2014(4):17-21.
作者姓名:杜林雪  李喜宏  陆书  来王彪  罗金山  刘海娇
作者单位:天津科技大学,天津300457
基金项目:国家“十二五”农村领域国家科技计划项目(2012BAD38B02);国家“863”项目(2012AA101703)
摘    要:本文以线性低密度聚乙烯/低密度聚乙烯(LLDPE/LDPE=3:1)为基材,添加具有防霉功能的OBPA(10,10’-氧代双吩恶砒,10,10’oxybis-phenoxarsine),制备了厚度为0.016~0.017mm,浓度为0.00%、0.05%、0.10%、0.15%、0.20%和0.25%的OBPA防霉聚乙烯(PE)保鲜膜。结果表明:添加OBPA的保鲜膜抑制灰霉菌效果均达到QB/T2591-2003标准的1级水平;随着OBPA添加量的增多,断裂伸长率、拉伸强度和透明度不断降低,0.25%OBPA保鲜膜的断裂伸长率和拉伸强度分别比空白膜降低了14.84%和21.28%;添加OBPA能够增加保鲜膜的热合强度,0.25%OBPA保鲜膜比空白膜增加了27.92%;在8℃条件下对油菜保鲜12d,发现随着OBPA添加量的增多,0.25%OBPA保鲜膜包装的油菜的黄化率(9.43±0.07%)和失重率(1.00±0.04%)均较空白对照(分别为13.21±0.37%和1.32±0.07%)低。

关 键 词:聚乙烯  OBPA  防霉  保鲜膜  油菜

Study on Anti-mildew Polyethylene Plastic Added with OBPA
DU Lin-xue,LI Xi-hong,LU Shu-lai,WANG Biao,LUO Jin-shan,LIU Hai-jiao.Study on Anti-mildew Polyethylene Plastic Added with OBPA[J].China Fruit and Vegetable,2014(4):17-21.
Authors:DU Lin-xue  LI Xi-hong  LU Shu-lai  WANG Biao  LUO Jin-shan  LIU Hai-jiao
Institution:(Tianjin University of Science and Technology, Tianjin 300457, China)
Abstract:The LLDPE/LDPE (3:1) material was used as a substrate and OBPA(10,10'oxybis-phenoxarsine) as an organic anti-mildew filler to improve the mildew proof of PE film. The thickness of 0.016-0.017mm anti-mildew polyethylene(PE)film added with various amount of OBPA including 0.00%, 0.05%, 0.10%, 0.15%, 0.20%and 0.25% were prepared. Results indicated that the samples with OBPA all meet the level 1 standard visibly based on the QB/T2591-2003. With increasing the amount of OBPA, the elongation at break rate, the tensile strength and transparency reduced gradually. And elongation at break rate and the tensile strength of 0.25%OBPA were lower than the blank film 14.84% and 21.28%, respectively. However, adding 0.25% OBPA can increase the heat sealing strength with 27.92% compared with control film. With increasing the amount of OBPA, the etiolation rate and the weightlessness rate were retained after preservation of rape for 12 days at 8℃. The etiolation rate(9.43±0.07%) and the weightlessness rate(1.00±0.04%) of 0.25%OBPA were lower than control (13.21±0.37%and 1.32±0.07% respectively).
Keywords:Polyethylene  OBPA  anti-mildew  films  rape
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