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基于MSC-IDA的土壤重金属镉污染移除净化技术研究
引用本文:刘倩,李爱霞,张艳青.基于MSC-IDA的土壤重金属镉污染移除净化技术研究[J].农学学报,2023,13(3):65-70.
作者姓名:刘倩  李爱霞  张艳青
作者单位:1. 济源市环境科学研究所
摘    要:受到各种条件的限制,土壤重金属镉污染采用统一净化方案并不能取得最佳治理效果。针对上述问题,提出基于MSC-IDA(磁性固体螯合剂)的土壤重金属镉污染移除净化技术。设计了4种不同的净化方案,设定不同的土壤样本(重金属镉元素含量:0.925、0.642、0.61 mg)、MSC-IDA浓度(0.01、0.05、0.1、0.20 mol/L)、净化时间(时间:0~120 min)、土壤粒径不同(50、100、200目),研究这些方案下的MSCIDA对土壤重金属镉污染的移除净化效果。结果表明:方案1条件下,在添加MSC-IDA后,3种土壤样本中镉含量均明显减少,其中样本1的去除率最高,为5.22%;方案2发现,在MSC-IDA添加量小于0.1 mol/L时,土壤中镉的去除率随MSC-IDA浓度的增加而增加,但当MSC-IDA含量超过0.1 mol/L之后,上升幅度逐渐趋于平缓,样本1 (Cd:0.925 mg/kg)去除率>样本2 (Cd:0.642 mg/kg)>样本3 (Cd:0.61 mg/kg)。方案3发现,震荡时间与镉的去除率成正比,但是90 min后,镉去除率增长趋于平...

关 键 词:MSC-IDA  土壤污染    移除效率  净化
收稿时间:2021-12-01

Study on Removal and Purification Technology of Soil Cadmium Based on MSC-IDA
LIU Qian,LI Aixia,ZHANG Yanqing.Study on Removal and Purification Technology of Soil Cadmium Based on MSC-IDA[J].Journal of Agriculture,2023,13(3):65-70.
Authors:LIU Qian  LI Aixia  ZHANG Yanqing
Abstract:Constrained by various conditions, the unified purification program for removing soil cadmium (Cd) can not achieve the best effect. A novel soil Cd pollution removal and purification technology based on magnetic solid chelator (MSC-IDA) was proposed. We collected three Cd-polluted soil samples (0.925, 0.642 and 0.61 mg/kg), set MSC-IDA concentrations (0.01, 0.05, 0.1 and 0.20 mol/L), purification time (0-120 min) and different soil particle size conditions (50, 100 and 200 mesh), and designed 4 programs to study the removal and purification efficiency of MSC-IDA on soil Cd. The results showed that under program 1, by adding MSC-IDA, the Cd content in the three Cd polluted soil samples decreased significantly, and the Cd removal rate of the first soil sample was the highest of 5.22%. The results of program 2 showed that when the addition amount of MSC-IDA was less than 0.1 mol/L, the removal rate of Cd in soil increased with the increase of MSC-IDA concentration, but when the concentration exceeded 0.1 mol/L, the increase gradually tended to be flat. The Cd removal rate of the first soil sample (Cd: 0.925 mg/kg) was higher than that of the second soil sample (Cd: 0.642 mg/kg) and the third soil sample (Cd: 0.61 mg/kg). The results of program 3 indicated that the shaking time was positively proportional to the removal rate of Cd, but after 90min, the enhancement of Cd removal rate tended to be flat and declining. Program 4 found that the larger the soil particle size, the better the purification effect of MSC-IDA was. To the three Cd-polluted soil samples, MSC-IDA had the best purification effect on the second one (Cd: 0.642mg/kg).
Keywords:MSC-IDA  soil pollution  cadmium  removal efficiency  purification  
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