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典型土壤中有效态镉CaCl2提取条件优化研究
引用本文:颜世红,吴春发,胡友彪,李振炫,卢青松,陈树,杨泉军.典型土壤中有效态镉CaCl2提取条件优化研究[J].中国农学通报,2013,29(9):99-104.
作者姓名:颜世红  吴春发  胡友彪  李振炫  卢青松  陈树  杨泉军
作者单位:1. 安徽理工大学地球与环境学院,安徽淮南232001;中国科学院南京土壤研究所,南京210008
2. 中国科学院南京土壤研究所,南京210008;南京信息工程大学,南京210008
3. 安徽理工大学地球与环境学院,安徽淮南,232001
4. 南京信息工程大学,南京,210008
5. 农业局植保站,山东沾化,256800
基金项目:国家自然科学基金项目"酸化土壤中镉在包气带和含水层中的迁移特征与预测模型研究"
摘    要:为了研究CaCl2提取不同类型土壤中有效态镉的优化条件,以中国南方酸性水稻土和西北中偏碱性灰钙土为研究对象,探讨不同浓度CaCl2提取剂和不同提取时间对2种土壤中镉提取量的影响.结果表明,CaCl2提取的镉主要为土壤中的水溶态镉与部分交换态镉;0.01 mol/L CaCl2浸提下,酸性水稻土在3h达到平衡,提取量占土壤中水溶态与交换态镉含量之和的4.68%~54.90%,灰钙土仅需1h就达到平衡,但提取量占土壤中水溶态与交换态镉含量之和的3.60%~3.89%;0.1 mol/L CaCl2浸提下,水稻土需12h才达到平衡,提取量占土壤中水溶态与交换态镉含量之和的83.28%~90.32%,灰钙土3h达到平衡,提取量占土壤中水溶态与交换态镉含量之和的44.21%~45.26%;提取剂CaCl2浓度越高,镉提取量就越大,达到平衡所需要的时间也越长;0.1 mol/L CaCl2比0.01 mol/L CaCl2更适宜酸性水稻土和中偏碱性灰钙土有效态镉的提取,水稻土和灰钙土所需的提取时间分别为12h和3h.

关 键 词:典型土壤  有效态镉  提取剂CaCl2  优化条件
收稿时间:2012/9/20 0:00:00
修稿时间:2012/10/8 0:00:00

Optimization of CaCl2 Extraction of Available Cadmium in Typical Soils
Yan Shihong , Wu Chunfa , Hu Youbiao , Li Zhenxuan , Lu Qingsong , Chen Shu , Yang Quanjun.Optimization of CaCl2 Extraction of Available Cadmium in Typical Soils[J].Chinese Agricultural Science Bulletin,2013,29(9):99-104.
Authors:Yan Shihong  Wu Chunfa  Hu Youbiao  Li Zhenxuan  Lu Qingsong  Chen Shu  Yang Quanjun
Abstract:In order to study the optimal conditions for extracting available cadmium from different types of soil with CaCl2, different concentrations of CaCl2 were used to extract available cadmium from sierozem and paddy soil with different extraction times. The results showed that: the extracted cadmium by CaCl2 was water-soluble and exchangeable cadmium, and the extracted contents increased with the time prolonged. The extracted cadmium by 0.01 mol/L CaCl2 from paddy soil reached equilibrium after 3 h and accounted for 4.68%-54.90% of the sum of water-soluble cadmium and exchangeable cadmium; the extracted cadmium by 0.01 mol/L CaCl2 from sierozem reached equilibrium after 3 h and accounted for 3.60%-3.89% of the sum of water-soluble cadmium and exchangeable cadmium; the extracted cadmium by 0.1 mol/L CaCl2 from paddy soil reached equilibrium after three hours and accounted for 83.28%-90.32% of the sum of water-soluble cadmium and exchangeable cadmium; the extracted cadmium by 0.01 mol/L CaCl2 from paddy soil reached equilibrium after 3 h and accounted for 44.21%-45.26% of the sum of water-soluble cadmium and exchangeable cadmium. It indicated that 0.1 mol/L CaCl2 was more suitable than 0.01 mol/L CaCl2 in available cadmium extracting for paddy soil and sierozem , and their equilibrium time was 12 h and 3 h, respectively.
Keywords:conditions optimization
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