| 一种新型二茂铁丁酸混配合物的合成及晶体结构 |
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| 引用本文： | 冯世龙,邬全喜.一种新型二茂铁丁酸混配合物的合成及晶体结构[J].信阳农业高等专科学校学报,2008,18(4):123-124. |
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| 作者姓名： | 冯世龙 邬全喜 |
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| 作者单位： | 1. 郑州大学,化学系,河南,郑州,450052;信阳农业高等专科学校,生物技术系,河南,信阳,464000
2. 信阳农业高等专科学校,生物技术系,河南,信阳,464000 |
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| 摘 要： | 以二茂铁基丁酸(Fb)、4,4′-联吡啶(bpy)以及Zn(AC)2.2H2O为原料合成了一个新的混配合物Zn(Fb)2(bpy)2。X-射线单晶衍射分析表明,该化合物是一个四配体六配位单核配合物,并以氢键另连接两个二茂铁分子。
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| 关 键 词： | 二茂铁基丁酸 混配合物 晶体结构 |
Synthesis and crystal structure of a novel mixed-ligand complex from ferrocene |
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| FENG Shi-long,WU Quan-xi.Synthesis and crystal structure of a novel mixed-ligand complex from ferrocene[J].Journal of Xinyang Agricultural College,2008,18(4):123-124. |
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| Authors: | FENG Shi-long WU Quan-xi |
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| Institution: | FENG Shi-long1,2,WU Quan-xi2(1.Dept.of Chemistry,Zhengzhou University,Zhengzhou 450052,China,2.Dept.of Biotechnology,Xinyang Agricultural College,Xinyang 464000,China) |
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| Abstract: | A novel mixed - ligand complex Zn （Fb） 2 （bpy） 2 ] ＂ 2 HFb （ Fb = 4 - ferroceny] butyrate aniont, bpy = 4, 4＇ - Bipyrine ） was obtained by the reaction of Zn（ Ac）2 · 2H20 with sodium 4 - ferrocenyl butyrate and 4,4＇ - Bipyrine in methanol solution. X - ray structural analysis reveals that it is a anisomerous uninuclear complex and in the compound both of 4 - ferrocenyl butyric acid connects the complex by hydrogen bond N -H. |
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| Keywords: | 4-ferrocenyl butyric acid mixed-ligand complex crystal structure |
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