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Effect of Clay Minerals and Organic Matter on the Cation Exchange Capacity of Silt Fractions
Authors:Norman Peinemann  Nilda Mabel Amiotti  Pablo Zalba  Maria Bonita Villamil
Abstract:The cation exchange capacity (CEC) and specific surface properties were investigated in four particle‐size fractions < 50 μm from three loess (one Kastanozem and two Phaeozems), a holocene (Fluvisol) and a basalt soil (Nitisol) before and after destruction of organic matter. Particle‐size fractions were separated by sedimentation after chemical and physical dispersion of the soil samples. Illite, amorphous minerals, mixed layers, smectite and kaolinite were the predominant clay minerals. They were detected in all size fractions. The CEC increased with increasing organic matter contents and this effect was more pronounced in coarser fractions. The organic matter content per unit surface area was two or three times larger in coarse silt than in clay, irrespective of the soil type.
Keywords:cation exchange capacity  specific surface areas  particle‐size fractions  organic matter
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