Preparation and characterization of imidacloprid lignin-polyethylene glycol matrices coated with ethylcellulose |
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| Authors: | Flores-Céspedes Francisco Figueredo-Flores Cristina Isabel Daza-Fernández Isabel Vidal-Peña Fernando Villafranca-Sánchez Matilde Fernández-Pérez Manuel |
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| Institution: | Department of Inorganic Chemistry, University of Almería, Campus de Excelencia Internacional Agroalimentario (ceiA3), La Ca?ada de San Urbano s/n, Almería. |
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| Abstract: | Imidacloprid, a systemic insecticide that has a water solubility of 610 mg L(-1), has been formulated in lignin-polyethylene glycol matrices by a melting process. This formulation was coated in a Wurster type fluidized-bed equipment using ethylcellulose and dibutyl sebacate. Imidacloprid has been entrapped, with an entrapment efficiency higher than 87% in all cases. Thermogravimetric analysis, differential scanning calorimetry, and Fourier transformed infrared spectroscopy studies indicate the stability and compatibility of polymers and imidacloprid. Scanning electron microscopy images show a homogeneous film of ethylcellulose in coated formulations. From T(50) values (the time taken for 50% of the active ingredient to be released into water), the release rate of imidacloprid is controlled by changing the thickness of the coating film and modifying its surface properties by adding a plasticizer. T(50) values, ranging from 3.02 to 168.6 h, allow supplying the appropriate amount of imidacloprid in each specific agronomic practice to increase the efficiency of this bioactive material and minimize the risk of environmental pollution. |
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