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Changes in wettability of heat-treated wood due to artificial weathering
Authors:Xianai Huang  Duygu Kocaefe  Yasar Kocaefe  Yaman Boluk  Andre Pichette
Institution:1. Université du Québec à Chicoutimi, 555, boul. de l’Université, Chicoutimi, QC, G7H 2B1, Canada
2. University of Alberta, 3-142 Markin/CNRL Natural Resources Engineering Facility, Edmonton, AB, T6G 2W2, Canada
Abstract:Effect of artificial weathering on the wettability of three heat-treated North American wood species (jack pine, aspen, and birch) is studied from the point of view of the structural and chemical changes taking place on the wood surface. Weathering increases wettability of all three heat-treated woods by water. Changes in wettability during artificial weathering differ according to heat treatment procedure and wood species and are likely due to combination of structural and chemical changes of the surfaces. Scanning electron microscopic analysis indicates that cracks form due to degradation taking place during weathering. As a result, water has easier entry into the cell wall, which consequently increases wettability. IR spectra suggest that the OH/CH2 ratio for heat-treated specimens is inversely proportional to the contact angle regardless of the type of wood species. The presence of cellulose-rich layer on wood surface and increasing amount of amorphous cellulose transformed from crystallized cellulose due to weathering result in increase in hydroxyl; consequently, it increases heat-treated wood wettability.
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