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椰子壳苯酚液化的研究
引用本文:郑志锋,邹局春,陈华平,张宏健.椰子壳苯酚液化的研究[J].福建林学院学报,2007,27(2):138-142.
作者姓名:郑志锋  邹局春  陈华平  张宏健
作者单位:西南林学院木质科学与装饰工程学院,云南,昆明,650224
基金项目:东北林业大学生物质材料科学与技术教育部重点实验室开放基金,云南省教育厅资助项目
摘    要:研究了催化剂种类、浓硫酸催化剂用量、液化反应温度、苯酚与椰子壳质量比、液化反应时间对液化产物残渣率及结合酚的影响。结果表明,浓硫酸是椰子壳液化反应较佳的催化剂;当浓硫酸用量为6%,反应温度为150℃,质量比为4∶1时,液化反应30 min可较好地将椰子壳液化;随着液化反应时间的延长,液化产物结合酚含量上升。

关 键 词:椰子壳  苯酚  液化  酸性催化剂  结合酚
文章编号:1001-389X(2007)02-0138-05
收稿时间:2006-11-28
修稿时间:2007-01-30

Study on liquefaction of coconut shell in phenol
ZHENG Zhi-feng,ZOU Ju-chun,CHEN Hua-ping,ZHANG Hong-jian.Study on liquefaction of coconut shell in phenol[J].Journal of Fujian College of Forestry,2007,27(2):138-142.
Authors:ZHENG Zhi-feng  ZOU Ju-chun  CHEN Hua-ping  ZHANG Hong-jian
Institution:College of Wood Science and Decoration Engineering, Southwest Forestry University, Kunming, Yuannan 650224, China
Abstract:The liquefaction of coconut shell in phenol was studied.The effects of catalysts,different content of sulphuric acid,reaction temperature,phenol: powder ratio,reaction time on the content of residue and combined phenol of the products of liquefaction were discussed in detail.The result showed that sulphuric acid was an excellent catalyst.With 6% sulphuric acid(the concentration of 98%) as the catalyst,reaction temperature at 150 ℃,the weight ratio of phenol to coconut powder being 4,and reaction time 30 mins,favourable liquefaction reaction parameters were found.The amount of combined phenol rose with the reaction time extending.
Keywords:coconut shell  phenol  liquefaction  acid catalyst  combined phenol
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