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High-resolution NMR spectroscopy with a portable single-sided sensor
Authors:Perlo Juan  Demas Vasiliki  Casanova Federico  Meriles Carlos A  Reimer Jeffrey  Pines Alexander  Blümich Bernhard
Institution:Institut für Technische Chemie und Makromolekulare Chemie, RWTH-Aachen, D-52056, Germany.
Abstract:We report construction of a portable nuclear magnetic resonance sensor with a single-sided open probe design. The resulting magnetic field inhomogeneity is compensated by a pulse sequence that takes advantage of parallel inhomogeneity in the applied radio frequency field. We can thereby acquire fluorine-19 spectra of liquid fluorocarbons with 8 parts per million resolution, surmounting the long-standing obstacle of obtaining chemical shift information with open probe instruments.
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