High-resolution NMR spectroscopy with a portable single-sided sensor |
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Authors: | Perlo Juan Demas Vasiliki Casanova Federico Meriles Carlos A Reimer Jeffrey Pines Alexander Blümich Bernhard |
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Institution: | Institut für Technische Chemie und Makromolekulare Chemie, RWTH-Aachen, D-52056, Germany. |
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Abstract: | We report construction of a portable nuclear magnetic resonance sensor with a single-sided open probe design. The resulting magnetic field inhomogeneity is compensated by a pulse sequence that takes advantage of parallel inhomogeneity in the applied radio frequency field. We can thereby acquire fluorine-19 spectra of liquid fluorocarbons with 8 parts per million resolution, surmounting the long-standing obstacle of obtaining chemical shift information with open probe instruments. |
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