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苘麻/聚乙烯复合材料性能的研究
引用本文:唐伟,张晨夕,王伟宏,郭丽敏.苘麻/聚乙烯复合材料性能的研究[J].安徽农业科学,2014(27):9509-9512,9618.
作者姓名:唐伟  张晨夕  王伟宏  郭丽敏
作者单位:东北林业大学生物质材料科学与技术教育部重点实验室,黑龙江哈尔滨,150040
基金项目:国家林业公益性行业科研专项经费项目
摘    要:我国的麻类资源非常丰富,将麻纤维用于复合材料的制备能扩大麻纤维的应用范围,有效提高麻纤维的使用价值.将苘麻纤维(AF)作为增强材料,通过热压工艺制备了苘麻/聚乙烯(PE)复合材,并探讨了该复合材的各项性能.通过热重分析确定了苘麻纤维的加工温度为180℃,对比分析AF/PE复合材的力学性能,确定制备复合材时AF含量控制在60%范围内能得到性能优异的复合材,AF与PE的最佳质量比为55∶45.苘麻纤维经硅烷偶联剂处理后,AF/PE复合材的弯曲性能和拉伸性能都有明显提高,吸水厚度膨胀率明显降低.由红外光谱分析发现,硅烷偶联剂与苘麻纤维表面的羟基发生化学反应生成了硅-氧-碳共价键,硅烷偶联剂使麻纤维表层与PE基质层之间产生分子结合,因此提高了PE基质与苘麻纤维的结合强度.

关 键 词:苘麻纤维  聚乙烯  复合材料  性能  硅烷偶联剂

Study on the Properties of Abutilon theophrasti Fiber/Polyethylene Composites
Institution:TANG Wei,ZHANG Chen-xi,WANG Wei-hong(Key Lab of Biomass Material Science and Technology, Northeast Forestry University, Harbin, Heilongjiang 150040)
Abstract:There are very abundant resources of bast fiber in China.Introducing AF to composite area can enlarge its application and increase its economic value.In this paper,AF was used to reinforce polyethylene (PE) to produce AF/PE composites by hot-pressing process,and explored various properties of this composites.Hot pressing temperature for producing the composite was finally determined at 180 ℃ by Thermogravimetric analysis.By analysing AF/PE composites mechanical properties and microstructure,these conclusions were obtained:the composite presented good properties when AF content was limited within 60% in the composites ; the best performance was obtained when the content of AF was 55%.When AF was treated with silane coupling agent,the bending property and tensile property of the AF/PE composites were improved obviously,thickness swelling caused by water absorption were decreased obviously.Based on FTIR spectra we know that silane coupling agent could react with the hydroxyl groups on the surface of AF and improve the compatibility between the AF and PE.
Keywords:Abutilon theophrasti fiber  Polyethylene  Composite  Property  Silane coupling agent
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