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苦参碱和苦豆子总碱光分解及光分解抑制的研究
引用本文:吴传万,杜小凤,王伟中,田兴军.苦参碱和苦豆子总碱光分解及光分解抑制的研究[J].农药学学报,2005,7(4):343-348.
作者姓名:吴传万  杜小凤  王伟中  田兴军
作者单位:南京大学,生命科学学院,江苏,南京,210095;江苏省徐淮地区淮阴农业科学研究所,江苏,淮安,223001;江苏省徐淮地区淮阴农业科学研究所,江苏,淮安,223001;南京大学,生命科学学院,江苏,南京,210095
基金项目:江苏省农科院科研基金(6210316);江苏省“333人才培养工程”;国家自然科学基金(30470299)资助项目.
摘    要:研究了苦参碱(从苦豆子中提取分离获得)和苦豆子总碱在太阳光及紫外光照射下的光分解现象,发现两者均属于光易分解物质,其光分解半衰期均不超过1 h。运用11种不同的光稳定剂处理均能有效地抑制苦参碱和苦豆子总碱光分解,其中以TBHQ(Tertiary-butylhydroquinone,特丁基对苯二酚)的抑制效果最为明显。在此基础上探索了不同浓度TBHQ对苦参碱和苦豆子总碱光分解的抑制效应,结果显示其抑制效果与稳定剂的浓度相关,处理浓度越大,其抑制苦豆子总碱光分解的作用越强。

关 键 词:苦参碱  苦豆子总碱  光分解  光分解抑制
文章编号:1008-7303(2005)04-0343-06
收稿时间:2005-07-13
修稿时间:2005-09-26

Study on the Photolysis and the Photolysis Inhibition of Matrine and Total Alkaloids in Sophora alopecuroides
WU Chuan-wan,DU Xiao-feng,WANG Wei-zhong and TIAN Xing-jun.Study on the Photolysis and the Photolysis Inhibition of Matrine and Total Alkaloids in Sophora alopecuroides[J].Chinese Journal of Pesticide Science,2005,7(4):343-348.
Authors:WU Chuan-wan  DU Xiao-feng  WANG Wei-zhong and TIAN Xing-jun
Institution:1.School of Life Science, Nanjing University,Nanjing 210095, China2.Institute of Agricultural Science of Huaiyin in Xuhuai District of Jiangsu Province, Huaian 223001, China
Abstract:The photolysis of matrine and total alkaloids in Sophora alopecuroides in the sunlight and the UV-light were studied.In the sunlight or UV-light,the matrine and total alkaloids in S.(alopecuroides) were photolysised rapidly,both of them with half-lifes of less than one hour.In order to(inhibit) the photolysis of matrine and total alkaloids in S.alopecuroides and enhance their photostability,eleven photostabilizers were selected as photolysis inhibitors of matrine and total alkaloids in S.(alopecuroi)des.The result shows that all the eleven photostabilizers exhibited the effects of photolysis(inhibition),especially TBHQ(Tertiary-butylhydroquinone)with the best effects of inhibition.
Keywords:matrine  total alkaloids in Sophora alopecuroides  photolysis  photolysis inhibition
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