Retention and degradation of metribuzin in sandy loam and clay soils of Lebanon |
| |
| Authors: | R Khoury A Geahchan† C M Coste‡ J-F Cooper§ & A Bobe§ |
| |
| Institution: | Agricultural Department, Agricultural Research Institute, Fanar, Lebanon,; Department of Chemistry, Faculty of Science II, Lebanese University, Lebanon,; Centre de Phytopharmacie, Universitéde Perpignan, Perpignan, France,;and Laboratoire de Chimie Analytique, Facultéde Pharmacie, Universitéde Montpellier I, Montpellier, France |
| |
| Abstract: | The retention and degradation of metribuzin herbicide were studied under two environmental conditions. Field studies were carried out on two soils, a sandy loam soil (soil A) and a clay soil (soil B). Metribuzin was applied with a jet sprayer at 1060 g a.i. ha?1 and 1960 g a.i. ha?1 on soils A and B respectively. Reconstituted soil columns were used to study the herbicide movement and metabolism in the two soils. Analyses of metribuzin and its metabolites were carried out using standardized methods. The results indicated a very weak capacity of adsorption of metribuzin in the two soils, and the weak adsorbed fraction is easily desorbed. Degradation and mobility of metribuzin in the field and laboratory soil columns were very intense and rapid. Soil A favoured reductive deamination whereas soil B favoured oxidative desulphuration and the respective metabolites deaminometribuzin and diketometribuzin yield the same product deaminodiketometribuzin. Both leaching by rainfall and degradation were important in the disappearance of metribuzin from the soils. |
| |
| Keywords: | herbicide metribuzin mobility adsorption–desorption metabolism soils degradation |
|
|
