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Effect of temperature and flooding duration on phosphate sorption in an acid sulphate soil from Vietnam
Authors:VO  DINH QUANG JE DUFEY
Institution:UniversitéCatholique de Louvain, Unitédes Sciences du Sol, Place Croix du Sud 2/10, 1348 Louvain-la-Neuve, Belgium
Abstract:Phosphate sorption in soil is controlled largely by Fe-oxihydroxides, and so important changes in P dynamics are expected when the redox potential is modified. Such changes in P sorption when acid soil is flooded, as for rice cultivation, have been evaluated. Samples from an acid sulphate soil in the Mekong Delta of Vietnam were flooded for up to 56 d at 20°C and 30°C. Some of the samples incubated at 30°C were dried in open air for 30 d after flooding. Small redox potential (Eh<0) and pH>6 were rapidly reached in soil flooded at 30°C; less drastic reducing conditions (Eh ?0.2 V) and pH 4–5 occurred at 20°C. Phosphate sorption increased during flooding. The increase was twofold at 20°C, and 10-fold at 30°C. Phosphate sorption index decreased in the soil that was air dried after flooding at 30°C, but still remained two to three times greater than before flooding. These results were compared to the changes in oxalate-extractable Fe, i.e. poorly crystalline or amorphous Fe-oxihydroxides. The increase of P sorption per unit increase of oxalate-Fe was seven to eight fold larger at 30°C than at 20°C.
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