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杨梅树叶、皮、根部精油成分及其抗氧化活性物质
引用本文:钟瑞敏,张振明,王羽梅,曾庆孝,彭华贵.杨梅树叶、皮、根部精油成分及其抗氧化活性物质[J].林产化学与工业,2006,26(1):1-5.
作者姓名:钟瑞敏  张振明  王羽梅  曾庆孝  彭华贵
作者单位:1. 华南理工大学轻工与食品学院,广东,广州,510640;韶关学院英东生物工程学院,广东,韶关,512005
2. 韶关学院英东生物工程学院,广东,韶关,512005
3. 华南理工大学轻工与食品学院,广东,广州,510640
4. 广东南岭自然保护区大顶山管理站,广东,韶关,512726
基金项目:国家自然科学基金资助项目(30370151)
摘    要:采用GC-MS技术结合Kovats保留指数(KI)对比法分析鉴定了采自南岭自然保护区的乌杨梅(Myrica rubravar.astropureaTsen.)叶、皮和根部芳香精油的成分,同时运用薄层层析(TLC)筛分法对其抗氧化活性物质进行了对比分析。杨梅树根和树皮精油的主要成分为5-羟基菖蒲烯(相对含量分别为74.66%和60.32%)和油酸(7.74%和11.39%),而树叶精油的主体成分为5-羟基菖蒲烯(30.44%)、石竹烯(11.61%)、异石竹烯(10.17%)、(E)-橙花叔醇(9.57%)和油酸(4.40%)。树根、树皮到树叶部位的次生代谢物明显出现越来越复杂的分化特性。5-羟基菖蒲烯是3个部位精油的主要抗氧化活性物质,但叶部精油中的倍半萜烯类物质也表现出一定的二苯代苦味酰(DPPH)自由基清除活性。

关 键 词:乌杨梅  芳香精油  Kovats保留指数  抗氧化活性
文章编号:0253-2417(2006)01-0001-05
收稿时间:10 8 2005 12:00AM
修稿时间:2005年10月8日

Chemical Composition and Antioxidant Components of Essential Oils from Leaves, Bark and Root of Myrica rubra
ZHONG Rui-min,ZHANG Zhen-ming,WANG Yu-mei,ZENG Qing-xiao,PENG Hua-gui.Chemical Composition and Antioxidant Components of Essential Oils from Leaves, Bark and Root of Myrica rubra[J].Chemistry & Industry of Forest Products,2006,26(1):1-5.
Authors:ZHONG Rui-min  ZHANG Zhen-ming  WANG Yu-mei  ZENG Qing-xiao  PENG Hua-gui
Institution:1. College of Light Industry and Food Science, South China University of Technology, Guangzhou 510640, China; 2. Yingdong College of Biotechnology, Shaoguan College, Shaoguan 512005, China; 3. Dadingshan Mountain Administration of Nanling National Nature Reserve, Shaoguan 512726, China
Abstract:Essential oils from leaves,bark and root of Chinese waxmyrtle(Myrica rubra var.astropurea Tsen),growing wild in Nanling National Nature Reserve,have been analyzed for their chemical composition and investigated for their antioxidant components.The GC-MS analysis as well as comparison of the Kovats retention indices(KI) of elution peaks with literature data were used for compound identification of the essential oils;TLC-screening method was used for analysis of antioxidant components in the oils.The essential oils of M.rubra bark and root are both dominated with 5-hydroxycalamenene(74.66% and(60.32%)) and oleic acid(7.74% and 11.39%),respectively,whereas,the leaves oil is constituted mainly by 5-hydroxycalamenene((30.44%)),caryophyllene(11.61%),isocaryophyllene(10.17%),(E)-nerolidol(9.57%) and oleic acid((4.40%)),(respectively.) The composition matrixes of the essential oils of M.rubra leaves,bark and root express the differential complexity of secondary metabolites in this species.5-Hydroxycalamenene is identified as the principal antioxidant in all three essential oils.However,the sesquiterpenes in leaves oil also show positive 2,2-diphenyl-1-picrylhydrazyl(DPPH) radical scavenging activity in certain extent.
Keywords:Myrica rubra var  astropurea Tsen  essential oil  Kovats retention index  antioxidant activity
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