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Formation and properties of hydroxy iron(iii) oligomer-citrate complex
Authors:Shin-Ichiro Wada  Takashi Ryu
Institution:Division of Bioresources and Environmental Sciences , Graduate School of Kyushu University , Fukuoka , 812-8581 , Japan
Abstract:Instantaneous neutralization of Fe (III) chloride dissolved in N a citrate by powdery NaHC03 gave stable clear brown sols. The sol particles separated by dialysis and freeze-drying showed a single diffraction peak at 2 nm and a citrate/Fe molar ratio of about 0.2 irrespective of the composition of the starting solutions. This indicates that the product may be a novel phase of Fe (III) citrate.
Keywords:Fe (III) citrate  Fe(III) hydroxide  hydrolysis  sol
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