| 腐殖酸和溶液的pH对Na和Ca土壤粘土分散的影响 |
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| 作者姓名： | LAN Ye-Qing HU Qiong-Ying XUE Jia-Hua |
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| 作者单位： | [1]AppliedChemistryDepartmentofNanjingAgriculturalUniversity,Nanjing210095,China [2]AppliedChemistryDepartm,Nanjing210095,China |
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| 摘 要： | Dispersed soil clays have a negative impact on soil structure and contribute to soil erosion and contaminant movement.In this study,two typical soils from the south of China were chosen for investigating roles of pH and humic acid(HA) on dispersion of soil clays.Critical flocculation concentration (CFC) of the soil clay suspension was determined by using light transmission at a wavelength of 600 nm.The results indicated that effects of pH and HA on dispersion of the soil clays were closely related to the type of the major minerals makin up the soil and to the valence of the exchangeable cations as well.At four rates of pH(4,6,8and 10),the CFC for the Na-yellow-brown soil treated with H2O2 was increased from 0.32 to 0.56,6.0 to 14.0,10.0 to 24.6 and 26.0 to 52.0mmol L^-1 NaCl,respectively when Na-HA was added at the rate of from 0 to 40mgL^-1,With the same Na-HA addition and three pH(6,8and 10)treatments,the CFC for the Na-red soil was incresed from 0.5 to 20.0,1.0 to 40.0 and 6.0 to 141.0mmol L^-1 NaCl,respectively.Obviously,pH and HA has greater effects on clay dispersion of the red soil(dominated by 1:1 minerals and oxides) than on that of the yellow-brown soil(dominated by 2:1minerals).However,at three rates of pH(6,8and 10) and with the addition of Ca-HA from 0 to 40mg L^-1,the CFC of the Ca-yellow-brown soil and Ca-red soil treated with H2O2 was increased from 0.55 to 0.81,0.75 to 1.28,0.55 to 1.45and 0.038 to 0.266.0.25 to 0.62,0.7to 1.6mmol CaCl2 L^-1,respectively.So,Na-soil claye are more sensitive to pH and HA than Ca-soil clays.
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| 关 键 词： | 腐植酸 溶液 pH值 土壤粘粒悬液 钠离子 钙离子 离子饱和度 |
Effects of humic acid and solution pH on dispersion of Na- and Ca-soil clays |
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| LAN Ye-Qing,HU Qiong-Ying,XUE Jia-Hua.Effects of humic acid and solution pH on dispersion of Na- and Ca-soil clays[J].Pedosphere,1996,6(4):349-354. |
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| Authors: | LAN Ye-Qing HU Qiong-Ying and XUE Jia-Hua |
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| Institution: | [1]AppliedChemistryDepartmentofNanjingAgriculturalUniversity,Nanjing210095,China [2]AppliedChemistryDepartm,Nanjing210095,China |
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| Abstract: | Dispersed soil clays have a negative impact on soil structure and contribute to soil erosion and contaminant movement.In this study,two typical soils from the south of China were chosen for investigating roles of pH and humic acid(HA) on dispersion of soil clays.Critical flocculation concentration (CFC) of the soil clay suspension was determined by using light transmission at a wavelength of 600 nm.The results indicated that effects of pH and HA on dispersion of the soil clays were closely related to the type of the major minerals makin up the soil and to the valence of the exchangeable cations as well.At four rates of pH(4,6,8and 10),the CFC for the Na-yellow-brown soil treated with H2O2 was increased from 0.32 to 0.56,6.0 to 14.0,10.0 to 24.6 and 26.0 to 52.0mmol L^-1 NaCl,respectively when Na-HA was added at the rate of from 0 to 40mgL^-1,With the same Na-HA addition and three pH(6,8and 10)treatments,the CFC for the Na-red soil was incresed from 0.5 to 20.0,1.0 to 40.0 and 6.0 to 141.0mmol L^-1 NaCl,respectively.Obviously,pH and HA has greater effects on clay dispersion of the red soil(dominated by 1:1 minerals and oxides) than on that of the yellow-brown soil(dominated by 2:1minerals).However,at three rates of pH(6,8and 10) and with the addition of Ca-HA from 0 to 40mg L^-1,the CFC of the Ca-yellow-brown soil and Ca-red soil treated with H2O2 was increased from 0.55 to 0.81,0.75 to 1.28,0.55 to 1.45and 0.038 to 0.266.0.25 to 0.62,0.7to 1.6mmol CaCl2 L^-1,respectively.So,Na-soil claye are more sensitive to pH and HA than Ca-soil clays. |
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| Keywords: | clay dispersion humic acid pH soil |
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