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Factors influencing fluoride concentrations in Norwegian lakes
Authors:Brit Lisa Skjelkvåle
Institution:1. Norwegian Institute for Water Research, Box 69, 0808, Oslo, Norway
Abstract:The sources and mechanisms regulating fluoride (F) in Norwegian lake waters are studied using data from regional surveys of precipitation chemistry, lake water chemistry and bedrock geology. Fluoride concentrations in Norwegian lakes range from < 5 to 560 μg L?1. Fluoride content in the bedrock is the most important factor controlling F levels in lake waters, as shown by significant differences in median value of F concentrations between lakes situated in different geological provinces. There are also weak but significant correlations between F in the lakes and components typical for weathering such as non-marine Ca, Mg, Na and K. The regional picture of F concentration in lake water shows elevated F concentrations in the acidified areas in southern and southeastern Norway compared to other regions of the country with comparable geology. There is a weak but significant correlation between F and SO4, a typical indicator of acidification in surface water. Mass balance calculations in three catchments show that F is retained in soils in pristine areas, while F output exceeds precipitation input in acidified areas. This both demonstrates the strong retention capacity for F in soils and indicates that anthropogenic F added through polluted rain is a minor source of F in surface waters. Fluoride is mobilized in acidifies areas, probably due to complexation with Al.
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