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N,N-二亚乙基双丙烯酰胺与魔芋葡甘聚糖接枝共聚反应的研究
引用本文:吴绍艳,陈洁,祝媛媛,李琴,张丛兰.N,N-二亚乙基双丙烯酰胺与魔芋葡甘聚糖接枝共聚反应的研究[J].安徽农业科学,2012(30):14639-14640.
作者姓名:吴绍艳  陈洁  祝媛媛  李琴  张丛兰
作者单位:湖北大学知行学院
摘    要:目的]为了进一步开发利用魔芋资源,改善其黏度及水溶性。方法]硝酸铈铵引发魔芋葡甘聚糖与N,N-二亚乙基双丙烯酰接枝共聚,并对接枝共聚物的部分性质进行研究。结果]接枝共聚反应最佳条件为:N,N-二亚乙基双丙烯酸胺浓度1.5 mol/L,硝酸铈铵浓度8.0 mmol/L,反应温度60℃,反应时间2.5 h。结论]接枝共聚物的水溶性及溶液黏度增强,可用作工业增稠剂和上浆剂。

关 键 词:魔芋葡甘聚糖  硝酸铈铵  N  N-二亚乙基双丙烯酰胺  接枝共聚

Study on Graft Copolymerization Reaction of N,N-diethylenediacrylamide onto Konjac Glucomannan
Institution:WU Shao-yan et al(Zhixing College of Hubei University,Wuhan,Hubei 430011)
Abstract:Objective] In order to further develop and use konjac resources,its viscosity and water-solubility was improved.Method]Cerium ammonium nitrate(NH4)2Ce(NO3)6 initiated graft copolymerization of N,N-diethylenediacrylamide onto Konjac glucomannan.The reaction rule and the partial nature of graft copolymer were studied.Result]The best conditions of grafting copolymerization reaction were as follows: N,N-diethylenediacrylamide concentration of 1.5 mol/L,cerium ammonium nitrate concentrations of 8.0 mmol/L,reaction temperature of 60 ℃,reaction time of 2.5 h.Conclusion]Water-solubility and solution viscosity properties of graft copolymer was improved,and the graft copolymer could be used for industrial thickener and starching agent.
Keywords:Konjac glucomannan  Cerium ammonium nitrate  N  N-diethylenediacrylamide  Graft copolymerization
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