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Distribution of Trace Metals in Channel Sediment: a Case Study in South Atlantic Coast of Spain
Authors:Md Khurshid Alam Bhuiyan  Sabrina Qureshi  Md Masum Billah  Suresh Varma Kammella  Md Rushna Alam  Sunuram Ray  Md Mostafa Monwar  Abu Hena M K
Institution:1.Department of Physical Chemistry, Faculty of Marine and Environmental Sciences,University of Cádiz, Puerto Real Campus,Puerto Real,Spain;2.Department of Pharmacy, Faculty of Basic Medical and Pharmaceutical Sciences,University of Science and Technology Chittagong,Chittagong,Bangladesh;3.The United Graduate School of Agriculture Sciences,Kagoshima University,Kagoshima,Japan;4.Institute of Marine Sciences and Fisheries,University of Chittagong,Chittagong,Bangladesh;5.Department of Design and Planning in Complex Environments,Università Iuav di Venezia,Venice,Italy;6.Faculty of Agriculture and Food Sciences, Department of Animal Science and Fishery,Universiti Putra Malaysia Campus Bintulu,Bintulu,Malaysia
Abstract:Recently, Sancti Petri channel on the southwestern (SW) part of Iberian Peninsula has been experiencing urban, industrial, and vehicular expansion. Until recently, there have been only few published reports documenting the pattern of metal accumulation in this estuarine sediment. In the present study, trace metals such as Cu, Zn, Ni, Mn, Pb, Co, Cd, As, and Hg concentrations were analyzed from 69 sediment samples collected from 23 sampling sites of the Santi Petri channel. The magnitude of trace metal accumulation found as the following trend: Mn > Zn > Cu > Pb > Ni > Co > As > Cd > Hg. Spatial distribution pattern demonstrated overall decreasing trend of trace metal from Cadiz Bay mouth to the open ocean mouth, clearly correlative to the presence of anthropogenic inputs. Results of the principle component analysis (PCA) revealed that sediment metal chemistry of Sancti Petri channel is mainly regulated by the concentrations of Pb, Cu, Zn, and Ni; possible sources of those were from vehicular-related emissions. Pollution load index (PLI) and geo-accumulation index (I geo ) indicated overall low values. The study will stimulate improvement of our understanding regarding the pattern of accumulation of metals in the coastal sediments, and the recorded values of metals in the present study can be used as suitable reference for future studies.
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