| 微波诱导下高级润滑油的快速合成研究 |
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| 引用本文： | 傅世平,张凤秀,叶霞.微波诱导下高级润滑油的快速合成研究[J].西南农业大学学报,2004,26(4):514-517. |
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| 作者姓名： | 傅世平 张凤秀 叶霞 |
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| 作者单位： | [1]重庆师范大学化学系，重庆400047 [2]西南农业大学基础科技学院，重庆400716 |
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| 基金项目： | 重庆市科学基金攻关资助项目(6683) |
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| 摘 要： | 研究了三甲醇丙烷和季戊四醇与C5～C9的一元羧酸在微波诱导下快速合成高级润滑油，并与传统合成进行了比较。结果表明：在微波作用下，合成速率提高到原来10～15倍，三辛酸三甲醇丙烷酯、三壬酸三甲醇丙烷酯、四辛酸季戊四醇酯、四壬酸季戊四醇酯合成产率提高了10％～22％。微波诱导法速度快、方法简便、产率高，具有很好的应用潜力。
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| 关 键 词： | 微波 润滑油 三甲醇丙烷 季戊四醇 |
| 文章编号： | 1000-2642(2004)04-0514-04 |
MICROWAVE-INDUCED RAPID SYNTHESIS OF HIGH=GRADE LUBRICATING OILS |
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| FU Shi-ping,ZHANG Feng-xiu,YE Xia.MICROWAVE-INDUCED RAPID SYNTHESIS OF HIGH=GRADE LUBRICATING OILS[J].Journal of Southwest Agricultural University,2004,26(4):514-517. |
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| Authors: | FU Shi-ping ZHANG Feng-xiu YE Xia |
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| Institution: | FU Shi-ping~1,ZHANG Feng-xiu~2,YE Xia~2 |
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| Abstract: | With microwave irradiation, the esters of high-grade lubricating oils were synthesized. As compared with the conventional synthesis method, the new method greatly shortened the reaction time, with a 10 to 15 times greater reaction velocity. The yield rate of CH_3(CH_2)_6 COOOH_2]_3CCH_2CH_3,CH_3(CH_2)_7COOH_2]_3CCH_2CH_3,CH_3(CH_2)_6COOCH_2]_4C and CH_3(CH_2)_7COOOCH_2]_4C increased by 10 to 22%. |
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| Keywords: | microwave high-grade lubricating oil 1 1 1-tris(hydroxymethyl)propane pentaerythritol |
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