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外源硫在草甸草原黑钙土中的转化
引用本文:袁新,刘贺永,李天鹏,李岩岩,王斌,冯雪,金兰淑,姜勇.外源硫在草甸草原黑钙土中的转化[J].土壤通报,2022,53(5):1140-1147.
作者姓名:袁新  刘贺永  李天鹏  李岩岩  王斌  冯雪  金兰淑  姜勇
作者单位:1.沈阳农业大学 土地与环境学院,辽宁 沈阳 110866
基金项目:国家自然科学基金面上项目(31870441, 32071563, 31800398)资助
摘    要:  目的  探讨元素硫添加后在草甸草原黑钙土中的氧化速率,明确土壤无机S组分的变化特征。  方法  依托内蒙古额尔古纳草甸草原硫磺添加试验平台,测定了元素S添加量(0、1、2、4、6、8、10 t hm?2)1年后的表观氧化速率及表层土壤(0 ~ 10 cm)各无机硫组分的变化。  结果  研究表明,对照中的土壤全硫含量为627.5 mg kg?1,其中无机硫和有机硫分别占2.4%和97.6%。硫添加处理的表土全硫含量分别比对照增加646.5 ~ 5182.5 mg kg?1,总无机硫分别比对照增加169.4 ~ 887.9 mg kg?1;硫添加处理中,表土中未氧化的元素硫分别为473.9 ~ 4264.0 mg kg?1,元素硫的表观氧化速率分别为173.5 ~ 271.3 g kg?1 a?1。在增加的表土总无机硫中,85.0% ~ 91.9%为(CaCl2浸提),7.8% ~ 17.1%为吸附性硫( Ca(H2PO4)2浸提),0.8% ~ 1.6%为难溶性硫(HCl浸提)。土壤无机硫组分与土壤pH呈显著负相关,与土壤电导率呈显著正相关。  结论  外源添加的元素硫主要氧化为植物可利用态的易溶性硫 和吸附性硫,而氧化为难溶性硫的比例很低。

关 键 词:草甸草原    硫添加    无机硫组分    氧化速率    黑钙土
收稿时间:2021-08-15

Transformation of Added Sulfur in Chernozem of a Meadow Grassland
Institution:1.College of Land and Environment, Shenyang Agricultural University, Shenyang 110866, China2.Erguna Forest-Steppe Ecotone Ecosystem Research Station, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China
Abstract:  Objective  To explore the oxidation rate of elemental sulfur (S) in chernozem of a meadow grassland, and to examine the changes in soil inorganic S fractions.  Method  Based on a field experiment of S addition (with S addition rates of 0, 1, 2, 4, 6, 8 and 10 t hm?2, respectively) conducted in a meadow grassland in Erguna, Inner Mongolia, we determined the apparent oxidation rate and inorganic S fractions in 0-10 cm soil layer after 1 year of elemental S additions.  Result  Total S content was 627.5 mg kg?1, with 2.4% inorganic S and 97.6% organic S in the treatment without elemental S addition. Soil total S content increased by 646.5-5182.5 mg kg?1, and the total inorganic S increased by 169.4-887.9 g kg?1 in the S added treatments as compared with the control. The unoxidized elemental S in the surface soil were 473.9-4264.0 g kg?1 in the S addition treatments, with an apparent oxidation rate from 173.5-271.3 g kg?1 a?1, respectively. In the total increased inorganic S, the CaCl2 extractable S (soluble S), Ca(H2PO4)2 extractable S (adsorbed S), and HCl extractable S (insoluble S) accounted for 85.0%-91.9%, 7.8%-17.1%, 0.8%-1.6%, respectively in the surface soil of the S added treatments. Soil inorganic S fractions correlated negatively with soil pH but positively with soil electric conductivity (EC).  Conclusion  The added elemental S were mainly oxidized into plant available S, while the insoluble S only accounted for a small proportion.
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