外源硫在草甸草原黑钙土中的转化 |
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引用本文: | 袁新,刘贺永,李天鹏,李岩岩,王斌,冯雪,金兰淑,姜勇.外源硫在草甸草原黑钙土中的转化[J].土壤通报,2022,53(5):1140-1147. |
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作者姓名: | 袁新 刘贺永 李天鹏 李岩岩 王斌 冯雪 金兰淑 姜勇 |
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作者单位: | 1.沈阳农业大学 土地与环境学院,辽宁 沈阳 110866 |
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基金项目: | 国家自然科学基金面上项目(31870441, 32071563, 31800398)资助 |
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摘 要: | 目的 探讨元素硫添加后在草甸草原黑钙土中的氧化速率,明确土壤无机S组分的变化特征。 方法 依托内蒙古额尔古纳草甸草原硫磺添加试验平台,测定了元素S添加量(0、1、2、4、6、8、10 t hm?2)1年后的表观氧化速率及表层土壤(0 ~ 10 cm)各无机硫组分的变化。 结果 研究表明,对照中的土壤全硫含量为627.5 mg kg?1,其中无机硫和有机硫分别占2.4%和97.6%。硫添加处理的表土全硫含量分别比对照增加646.5 ~ 5182.5 mg kg?1,总无机硫分别比对照增加169.4 ~ 887.9 mg kg?1;硫添加处理中,表土中未氧化的元素硫分别为473.9 ~ 4264.0 mg kg?1,元素硫的表观氧化速率分别为173.5 ~ 271.3 g kg?1 a?1。在增加的表土总无机硫中,85.0% ~ 91.9%为(CaCl2浸提),7.8% ~ 17.1%为吸附性硫( Ca(H2PO4)2浸提),0.8% ~ 1.6%为难溶性硫(HCl浸提)。土壤无机硫组分与土壤pH呈显著负相关,与土壤电导率呈显著正相关。 结论 外源添加的元素硫主要氧化为植物可利用态的易溶性硫 和吸附性硫,而氧化为难溶性硫的比例很低。
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关 键 词: | 草甸草原 硫添加 无机硫组分 氧化速率 黑钙土 |
收稿时间: | 2021-08-15 |
Transformation of Added Sulfur in Chernozem of a Meadow Grassland |
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Institution: | 1.College of Land and Environment, Shenyang Agricultural University, Shenyang 110866, China2.Erguna Forest-Steppe Ecotone Ecosystem Research Station, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China |
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Abstract: | Objective To explore the oxidation rate of elemental sulfur (S) in chernozem of a meadow grassland, and to examine the changes in soil inorganic S fractions. Method Based on a field experiment of S addition (with S addition rates of 0, 1, 2, 4, 6, 8 and 10 t hm?2, respectively) conducted in a meadow grassland in Erguna, Inner Mongolia, we determined the apparent oxidation rate and inorganic S fractions in 0-10 cm soil layer after 1 year of elemental S additions. Result Total S content was 627.5 mg kg?1, with 2.4% inorganic S and 97.6% organic S in the treatment without elemental S addition. Soil total S content increased by 646.5-5182.5 mg kg?1, and the total inorganic S increased by 169.4-887.9 g kg?1 in the S added treatments as compared with the control. The unoxidized elemental S in the surface soil were 473.9-4264.0 g kg?1 in the S addition treatments, with an apparent oxidation rate from 173.5-271.3 g kg?1 a?1, respectively. In the total increased inorganic S, the CaCl2 extractable S (soluble S), Ca(H2PO4)2 extractable S (adsorbed S), and HCl extractable S (insoluble S) accounted for 85.0%-91.9%, 7.8%-17.1%, 0.8%-1.6%, respectively in the surface soil of the S added treatments. Soil inorganic S fractions correlated negatively with soil pH but positively with soil electric conductivity (EC). Conclusion The added elemental S were mainly oxidized into plant available S, while the insoluble S only accounted for a small proportion. |
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