| 钳形配体2 溴 1, 3 双[ 4 ( 2 甲基) 噁唑基] 苯的合成研究 |
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| 引用本文： | 谭建平,李志福,南文汇,李 宇,罗群力.钳形配体2 溴 1, 3 双[ 4 ( 2 甲基) 噁唑基] 苯的合成研究[J].西南农业大学学报,2012,34(1):062-066. |
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| 作者姓名： | 谭建平 李志福 南文汇 李 宇 罗群力 |
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| 作者单位： | 西南大学化学化工学院 |
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| 基金项目： | 国家自然科学基金资助项目(20971105);教育部留学回国人员启动基金资助项目([2007]1108);重庆市自然科学基金资助项目(CSCT2006BB4026);中央高校基本科研业务费专项资金资助项目(XDJK2009C093);西南大学博士基金资助项目(SWUB20060001) |
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| 摘 要： | 以2,6-双(2-溴乙酰基)溴苯和乙酰胺为原料,分别用传统加热法和微波加热法制得了钳形配体2-溴-1,3-双4-(2-甲基)噁唑基]苯.结果表明,用微波加热法合成目标产物有显著优越性,可使产率从40%提高到85%,同时反应时间从3d缩短到15min.
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| 关 键 词： | 微波加热 合成 钳形配体 2-溴-1 3-双[4-(2-甲基)噁唑基]苯 |
Synthesis of Pincer Ligand of 2-Bromo-1,3-bis(2-methyl-oxazol-4-yl) benzene |
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| TAN Jian-ping,LI Zhi-fu,NAN Wen-hui, LI Yu,LUO Qun-li.Synthesis of Pincer Ligand of 2-Bromo-1,3-bis(2-methyl-oxazol-4-yl) benzene[J].Journal of Southwest Agricultural University,2012,34(1):062-066. |
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| Authors: | TAN Jian-ping LI Zhi-fu NAN Wen-hui LI Yu LUO Qun-li |
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| Institution: | School of Chemistry and Chemical Engineering,Southwest University,Chongqing 400715,China |
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| Abstract: | 2,6-Bis(2-bromoacetyl) bromobenzene was heated with acetamide to yield a pincer ligand,2-bromo-1,3-bis(2-methyl-oxazol-4-yl) benzene,with either conventional heating or microwave heating.The result showed that microwave heating is strikingly superior to conventional heating for the synthesis of the target compound.It increased the yield from 40% to 85% and shortened the reaction time from 3 days to 15 min in comparison with conventional heating. |
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| Keywords: | microwave heating synthesis pincer ligand 2-bromo-1 3-bis(2-methyl-oxazol-4-yl) benzene |
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