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Short-lived oxygen diffusion during hot, deep-seated meteoric alteration of anorthosite
Authors:Mora  Riciputi  Cole
Institution:Department of Geological Sciences, University of Tennessee, Knoxville, TN 37996-1410, USA. Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6365, USA.
Abstract:Heterogeneous oxygen isotope compositions of plagioclase from the Boehls Butte anorthosite include some of the most oxygen-18-depleted values (to -16 per mil) reported for plagioclase in meta-igneous rocks and indicate high-temperature (T > 500 degrees C) isotopic exchange between plagioclase and nearly pristine meteoric fluid. Retrograde reaction-enhanced permeability assisted influx of meteoric-hydrothermal fluids into the deep-seated anorthosite. Isotopic gradients of about 14 per mil over 600 micrometers in single crystals require short-lived (about 10(4) years) diffusional exchange of oxygen and locally large effective water:rock ratios, followed by rapid loss of water and cessation of oxygen diffusion in the anorthosite.
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