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煤矸石中几种重金属元素含量及形态变化
引用本文:韩周,刘征涛,于淼,郭月,赫薇,祁智,魏忠义,王秋兵.煤矸石中几种重金属元素含量及形态变化[J].山西农业科学,2012,40(11):1200-1203.
作者姓名:韩周  刘征涛  于淼  郭月  赫薇  祁智  魏忠义  王秋兵
作者单位:1. 辽阳市太子河区种子管理站,辽宁辽阳,111000
2. 辽宁省葠窝水库管理局,辽宁辽阳,111000
3. 辽宁创兴规划设计有限公司,辽宁沈阳,110032
4. 朝阳市设施农业管理中心,辽宁朝阳,122000
5. 沈阳农业大学土地与环境学院,辽宁沈阳,110866
基金项目:辽宁省教育厅创新团队项目(2006T120);辽宁省自然科学基金项目(2040520)
摘    要:对抚顺西露天矿煤矸石山表层煤矸石进行多点取样,分析测定了矸石山表层煤矸石重金属Cd,Pb,Ni,Zn,Cr,Cu的含量及其形态特征。结果表明,煤矸石中Cd,Ni,Cu元素高出抚顺地区土壤环境背景值,其中Cd,Ni超出土壤环境质量2级标准。煤矸石重金属元素存在形态的分布规律总体与元素含量具有一致的变化规律,元素Cd,Pb,Ni,Zn,Cr,Cu的赋存形态普遍以残渣态、可还原态为主,可氧化态次之,弱酸可提取态比例最低。

关 键 词:煤矸石  重金属  含量  形态变化

Heavy Metals Content and Speciation in Coal Wastes
HAN Zhou , LIU Zheng-tao , YU Miao , GUO Yue , HE Wei , QI Zhi , WEI Zhong-yi , WANG Qiu-bing.Heavy Metals Content and Speciation in Coal Wastes[J].Journal of Shanxi Agricultural Sciences,2012,40(11):1200-1203.
Authors:HAN Zhou  LIU Zheng-tao  YU Miao  GUO Yue  HE Wei  QI Zhi  WEI Zhong-yi  WANG Qiu-bing
Institution:1.Seed Station of Taizihe District,Liaoyang,Liaoyang 111000,China;2.Shenwo Reservoir Management Office of Liaoning Province,Liaoyang 111000,China;3.Chong Xing Planning and Design Co.Ltd of Liaoning Province,Shenyang 110032, China;4.Facility Agriculture Management Center of Chaoyang,Chaoyang 122000,China;5.College of Land and Environment,Shenyang Agricultural University,Shenyang 110866,China)
Abstract:The weathered coal wastes were sampled at the surface layer in Fushun West Opencast coal mine dump,the content of Cd,Zn,Pb,Ni,Cr,Cu and their forms of the waste dump in surface rock were analyzied by ICP-AES.The results show that the contents of Cd,Ni,Co,Mn,Cu were beyond the limits in the region above the background value of soil environment in which Cd,Ni exceed soil environment quality criteria of 2th level.The changes of heavy metal elements and the presence of morphological features in the gangue rock showed some synchronization.Different class of heavy metals present in form of residual mainly of oxidizable fraction as well as reduced state content in the second,and weak acid extractable was the lowest.
Keywords:coal waste  heavy metals  contents  chemical speciation
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