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1.
A straightforward approach was proposed to modify cotton fabric for oil/water separation based on musselinspired reaction. The poly(DMA-Octadecyl acrylate) was designed to contain key chemical constituents present in mussel adhesive proteins by free radical polymerization of dopamine hydrochloride and octadecyl acrylate, which strongly adsorbed to fabric substrates, providing a special surface for fabric. The chemical structure, surface topography, and surface wettability of the fabric were characterized. The results showed that as-prepared cotton fabric displayed a high CA of >150° when dripped water droplets were on the modified fabric surface, and the oil contact angle (OCA) was close to 0°, it had excellent potential to be used in practical applications and has created a new method of fabric modification for oil/water separation.  相似文献   

2.
The cotton fabric was modified with dopamine methacrylamide (DMA) based on mussel-inspired reaction and polymerized with zwitterionic sulfobetaine methacrylate (SBMA) through free radical polymerization reaction. The poly(DMA-SBMA) contained not only key chemical constituents of dopamine hydrochloride, which strongly adsorbed to fabric substrates, but also hydrophilic groups, providing a hydrophilic surface for fabric due to its strong interaction with water via electrostatic interactions. The chemical structure, surface topography, and surface wettability of the fabric were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and contact angle experiments, respectively. The results showed that the water contact angle (WCA) of the treated fabric was ~0 °, whereas the underwater oil contact angle (OCA) was ~161 °, as compared to ~25 ° for the control one. It is expected that as-prepared fabrics could be applied in oil/water separation due to such special superhydrophilicity and superoleophobicity.  相似文献   

3.
Herein we report a simple and reproducible method for fabricating highly durable and robust superhydrophobic and superoleophilic cotton fabrics via simultaneous radiation-induced graft polymerization of glycidyl methacrylate and subsequent chemical modifications with aminopropyltriethoxysilane and hexamethyldisilazane. The chemical structure and the surface topography of the pristine and the modified cotton fabrics were investigated in detail by ATR-FTIR, XPS, and 29Si NMR, and a grafting layer was successfully immobilized onto the surface of the cotton fabric by forming covalent bonds. Multi-dimensional surface roughness was created by combining micro-sized fibers of the cotton fabric, nanoscaled protuberances of the grafting chain, and molecular level spherical projection points of silicon methyl. The superhydrophobic cotton fabric exhibited long-term stability, ultra-high durability and robustness, and maintained its properties even after 25 wash cycles. The fabric also showed excellent water repellency with a water contact angle of 153 ° and a high efficiency of oil/water separation (98 %). The superhydrophobic/superoleophilic cotton fabric developed in the present work exhibits important potential applications in superhydrophobic textiles and oil/water separation.  相似文献   

4.
The stearyl methacrylate modified polysiloxane/nanocomposite was synthesized by graft copolymerization between stearyl methacrylate modified polysiloxane with pendent epoxy groups and amino-functionalized nano silica. Then it was utilized to fabricate the superhydrophobic cotton fabric by one-step method. The structures, chemical compositions, thermal properties, surface morphology and wettability were characterized by Fourier Transform Infrared Spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS), Thermo-gravimetric analyzer (TGA), Scanning electron microscopy (SEM) and Static contact angle analyzer. Results showed that a hydrophobic polysiloxane film and many nano-scaled tubercles were coated on the surface of the treated cotton fabrics plus their inherent microscaled roughness, which were the reasons why cotton fabric changed from hydrophilicity to hydrophobicity. In addition, with increase of the amount of nanocomposite, hydrophobicity of the treated cotton fabric would be enhanced; water contact angle of this fabric could attain 157°, which was higher than 141.5° reached by the fabric treated with stearyl methacrylate modified polysiloxane. The superhydrophobic cotton fabric also possessed favorable washing durability. On the other hand, its air permeability, color and softness would not be influenced instead.  相似文献   

5.
Selective separation is an effective method for the removal of heavy metal ions and waste oil from wastewater. Polyvinylidene fluoride (PVDF) was functionalized with polyvinyl acetate (PVAc) by in-situ polymerization, and novel PVAc-g-PVDF coating on surface modified cotton fabric were prepared. The contact angle (CA), pure water flux (PWF) and self-cleaning ability of coated cotton fabric were investigated in detail. In addition, the separation performance of coated cotton fabric was reflected by the removal of heavy metal ions in simulated wastewater. The results revealed that the PVAc-g-PVDF-coated cotton fabric was free of waste oil adhesion and was self-cleaning from waste oil in aqueous environment. Meanwhile, this coated cotton fabric can effectively separate oil/water mixtures with a high flux and high oil rejection, and was easily recycled for long-term use. More importantly, the heavy metal ions rejection ratio and adsorption capacity of cotton fabric were also improved with the addition of PVAc-g-PVDF coating. PVAc-g-PVDF-coated cotton fabric exhibited excellent rejection stability and reuse performances after several times fouling and washing tests. It can be expected that the present work will provide insight into a scaled-up fabrication process of PVAc-g-PVDF coating for purifying wastewater.  相似文献   

6.
Oxygen plasma pre-treatment was applied to cotton fabric with the aim of improving the water repellency performance of an inorganic-organic hybrid sol-gel perfluoroalkyl-functionalized polysilsesquioxane coating. Cotton fabric was pre-treated with low-pressure oxygen plasma for different treatment times and operating powers. Afterward, 1H,1H,2H,2H-perfluorooctyltriethoxysilane (SiF) was applied to the cotton fabric samples using the pad-dry-cure method. The surfaces of the untreated and modified cotton fibers were characterised using Fourier transform infrared spectroscopy, Xray photoelectron spectroscopy, scanning electron microscopy, and atomic force microscopy. The water repellency of the SiF-coated fabric samples was evaluated using static and sliding contact angle measurements with water. The results show that the plasma treatment with the shortest treatment time (10 s) and the lowest operating current (0.3 A) increased the atomic oxygen/carbon ratio of the cotton fiber surface from 0.6 to 0.8 and induced the formation of a nano-sized grainy surface. Increasing the plasma treatment time and/or operating current did not intensify the surface changes of the cotton fibers. Such saturation effects were explained by the large influence of reactive oxygen atoms during the plasma treatment. The measured static water contact angles on the surface of the untreated and plasma pre-treated and SiF-coated cotton fabrics showed that the oxygen plasma pre-treatment enabled the increase of the water contact angle from 135° to ≈150°, regardless of the applied plasma treatment time and discharge power. This improvement in the hydrophobicity of the SiF coating was followed by a decrease in the sliding angle of water droplets by more than 10° compared to the plasma untreated and SiF-coated sample characterized by a water sliding angle of 45°. Additionally, measurements of the water sliding angle revealed that the increase of the static contact angle from 149° to 150° corresponded to a drop of the water sliding angle from 33 to 24°, which suggests that the plasma pre-treatment of 20 s at an operating current of 0.3 A produced the best water-repellent performance of the SiF-coated cotton fabric.  相似文献   

7.
A facile and inexpensive way to prepare self-crosslinkable poly(dimethylsiloxane) (PDMS) for superhydrophobic treatment of cotton fabrics is reported in the study. Through thiol-ene click reaction between mercaptopropyltrimethoxysilane (MPTMOS) and vinyl-containing poly(dimethylsiloxane) (VPDMS), PDMS-g-TMOS can be simply and quickly synthesized. The trimethoxysilane group of PDMS-g-TMOS can react with hydroxyl group on cotton fabric and other -Si(OCH3)3 groups. The synthesized polysiloxane (PDMS-g-TMOS) was identified by FT-IR and 1H-NMR. The morphology of the treated cotton fabric was observed by SEM and XPS was used to analyze the elemental composition on the surface of cotton fabric. The analysis results indicated that the surface was fully covered with PDMS. Due to the low surface energy of PDMS and the rough surfaces of cotton fabric, the optimized water contact angle (WCA) and sliding angle were respectively 154°±0.4° and 14°±0.5°, indicating superhydrophobicity. Moreover, water spray test (AATCC Test Method 22-2010) was also applied to evaluate the water repellency of treated cotton fabric and a score of 90 was assigned according to AATCC Test Method 22-2010. The durability of treated cotton fabric was tested by 50 laundering cycles. The resultant WCA barely decreased and the score of water spray test dropped from 90 to 80, showing the reasonable wash durability.  相似文献   

8.
A novel dodecylphenylsiloxane oligomer resin/nanocomposite (PHDESR-SiO2) was prepared by graft copolymerization between dodecyl modified phenylsiloxane resin with pendent epoxy groups (PHDESR) and amino-functionalized silica nanoparticles (BTEPA-SiO2). PHDESR-SiO2 was then used to prepare a super hydrophobic surface on cotton fabric by a facile solution-immersion process method. Chemical structures, chemical compositions, wettability, surface morphology, and thermal properties were investigated by Fourier Transform Infrared Spectrum (FT-IR), 1H-NMR spectrum, X-ray photoelectron spectroscopy (XPS), static contact angle analyzer, scanning electron microscopy (SEM), Particle size distribution (PSD) and thermo-gravimetric analysis (TGA). The results showed that the target product PHDESR-SiO2 has an anticipative structure with many micro/nanostructure tubercles, a cross-linked network hydrophobic organosilicon resin film and many clusters of cylindrical dodecyl molecular brushes. This created super hydrophobic structure on the surface of the treated cotton fabrics. XPS analysis indicated that the long carbon chain groups had a slight tendency to enrich the film-air interface. In addition, PHDESR-SiO2 can provide good hydrophobicity for the treated fabric. As the dose of PHDESR-SiO2 increased, the hydrophobicity of the treated fabric enhanced and consequently the water static contact angle reached 152.5 °. This had little influence on the softness, color, and gas permeability of the fabrics. This makes it slightly stiff at high doses, and the super-hydrophobic cotton fabric also had good launderability.  相似文献   

9.
Cotton fabrics exhibiting superhydrophobic and antibacterial properties were prepared through a non-solvent induced phase separation method using hydrophobic poly(vinylidene fluoride) (PVDF) and its hybrids with photocatalytic zinc oxide nanoparticles (nano-ZnO) as surface modifying agents for cotton fabric. The effects of coagulating medium and temperature on microstructural morphology and surface hydrophobictity of the cotton fabrics were investigated by FE-SEM observation and contact angle measurement. Superhydrophobic cotton fabrics exhibiting water contact angle higher than 150 ° could be obtained by coating the fabrics with solutions of PVDF and nano-ZnO followed by coagulation in ethanol as non-solvent. This phenomenon is considered to be originated from both chemically hydrophobic PVDF layer and physical micro- and nano-bumps formed on the surface of cotton fabric, which are essential requirements for Lotus effect. Moreover, antibacterial properties could be synergistically obtained by utilizing photocatalytic effect of nano-ZnO.  相似文献   

10.
α,ω-di[(4-butoxy-piperazin-1-yl)-phosphinic acid methyl ether]-terminated linear polysiloxane (PNPDMS) was synthesized and utilized as the flame retardant and hydrophobing agent. The flame retardance and thermal decomposition behaviors of cotton fabrics were systematically estimated by limiting oxygen index (LOI), thermogravimetric analysis and vertical burning test, respectively. It was found that the LOI of cotton fabric treated with PNPDMS enhanced to 29.82 % compared with cotton fabric without treatment, whose LOI was only 18.00 %. The treated cotton fabric showed a shorter char length, a shorter After-flame time, and no After-glow time as revealed in vertical burning test. The mechanical property in treated cotton fabric was slightly decrease. Furthermore, the grade of water repellency of treated cotton fabric reached to 90 and water contact angle (WCA) increased to 141.90° compared with cotton fabric without treatment whose WCA was 62.80°. The result showed that the cotton fabric treated with PNPDMS exhibited excellent flame retardance and hydrophobic properties.  相似文献   

11.
N-halamine precursor 2,2,6,6-tetramethyl piperidinol (TMP), a hindered amine light stabilizer, was bonded onto cotton fabric by using 1,2,3,4-butanetetracarboxylic acid (BTCA) as a crosslinking agent. A variety of treating conditions including TMP concentration, curing temperature and time, and catalyst were studied. The treated fabrics were characterized using FTIR spectra and scanning electron microscope (SEM). The cotton fabric treated with TMP precursor could be rendered biocidal upon exposure to dilute household bleach. The chlorinated cotton swatches showed great efficacy and inactivated 100 % of Staphylococcus aureus with 7.1 log reduction with 5 min of contact and 83.25 % of E. coli O157:H7 at 10 min of contact. In addition, the wrinkle recovery angle of the treated cotton fabrics increased from 229 ° of untreated cotton fabrics to 253 °. This study provided a practical finishing process to produce cotton fabrics with easy care and antibacterial functionalities at the same time.  相似文献   

12.
A simple and facile method for fabricating the cotton fabric with superhydrophobicity, self-cleaning and flame retardancy was described in the present work. Three types of antimony pentoxide sol (Sb2O5), aluminum hydroxide sol (Al(OH)3) and 1H,1H,2H,2H-perfluorodecyltriethoxysilane (fluoroalkyl silanes) were used as coating for the cotton fabric. It was found that Sb2O5 and Al(OH)3 exhibited significant synergistic effects on the flame retardancy. When the weight ratio of Sb2O5/Al(OH)3(content 30 wt%) was 1:3, the results showed that the limiting oxygen index (LOI) value was 45.1 %, smoke density (SDR) value was 35 %, and it still passed UL94 V-0 rating. The cotton fabrics coated with fluoroalkyl silanes/Sb2O5/ Al(OH)3 showed a superhydrophobicity, anti-contamination and self-cleaning properties. In addition, the results exhibited the outstanding superhydrophobicity, oil/water separation, excellent waterproofing durability and flame retardancy of cotton fabric after 1000 cycles of washing by water, the LOI value was 40.1 %, SDR value was 39 % and WCA was 152° after 1000 cycles of washing. We believe that this simple, environmentally friendly and versatile fabrication of the cotton fabric had excellent real-life applications.  相似文献   

13.
Fluorinated polyacrylate latexes are preferably potential materials for use in the textile finishing due to their special surface property and especially economical, low-toxic characteristics compared to fluorinated polyacrylate solutions. A novel cationic fluorine-containing polyacrylate soap-free latex (CFMBD) with core-shell structure was accordingly developed by co-polymerizing dodecafluoroheptyl methacrylate (DFMA), methyl methacrylate (MMA), butyl acrylate (BA), and dimethylaminoethyl methacrylate (DM) using a cationic reactive emulsifier, maleic acid double ester-octadecyl poly(ethyleneoxy)20 ether-ethylene trimethyl ammonium chloride (R303). Then CFMBD was utilized to treat the cotton fabric. Results showed that the as-prepared latex had due structure and its particles had uniform spherical core-shell structure with an average diameter of 125 nm. The core-shell CFMBD latex film thus had two T g and its thermal property was improved due to the introduction of DFMA. CFMBD could form a smooth resin film on the treated fabric/fiber surface under FESEM observation. XPS analysis indicated the fluoroalkyl groups had the tendency to enrich at the film-air interface. Hydrophobicity of the CFMBD treated fabric was slightly superior to that of the fabric treated by general emulsion but their oleophobicity was identical. Contact angles of water and diiodomethane on the CFMBD treated fabric surface could attain 133.5 ° and 105.5 °, respectively. However, washing durability of the treated fabric by CFMBD showed improvement compared to the general emulsion. In addition, CFMBD didn’t influence whiteness of the treated fabric but would make it slightly stiff at high doses.  相似文献   

14.
UV curing of perfluoro-alkyl-polyacrylate resins able to impart water as well as oil-repellency to cotton fabrics was studied in comparison with conventional thermal polymerization. The process was assessed through weight gain and gel content measurements while the properties conferred to cotton fabrics were determined in terms of water and oil contact angles, moisture adsorption, and water vapor permeability. The polymerization yields were of the same order (>80 %) of those obtained with thermal curing as well as the high contact angles with water (>127°) and oil (>118°) even at low resin add-on (3 %). UV cured resins yielded oil contact angles mostly higher than 120° denoting super oil-repellent surfaces. Moreover the water and oil-repellency was adequately maintained after washing. The moisture adsorption of finished fabrics was lower than that of untreated cotton, but slightly higher for UV cured than thermally treated fabrics. Water vapor transmission rate showed that the finish treatment, thermal as well as by UV curing, does not reduce the breathability of the original cotton. DSC analysis demonstrated that the fiber pyrolysis is affected by the polymer add-on, while FTIR-ATR spectra of all finished fabrics showed typical peaks of ester and C-F groups. XPS analysis showed small differences between thermal and UV curing coatings with each resin, while coatings with the lowest percentage of fluorine groups did not affect the water and oil-repellency.  相似文献   

15.
An epoxy group-terminated polyvinylmethylsiloxane (EPVMS) was firstly prepared via the cohydrolysis/condensation reaction of octamethylcyclotetrasiloxane (D4), 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane (D4V), and epoxy group-terminated polydimethylsiloxane (ETP) under a base catalyst. Then, the EPVMS was reacted with polymethylhydrosiloxane oligomer (PHMS) by hydrosilylation to develop novel crosslinked polysiloxane with end-capped epoxy groups (CLPS). The chemical structure and the thermal property of the as-prepared products were characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectra (1H/13C NMR) and thermogravimetric analysis (TGA). Finally, the CLPS was applied as the finishing agent to treat the cotton fabrics. The film morphology and the surface properties were examined with scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), contact angle measurements, and other instruments. FT-IR and NMR results confirmed the structure of the resultants. The crosslinked polysiloxane CLPS showed better thermal stability than the uncrosslinked polysiloxane EPVMS. The CLPS film on cotton fabric surface seemed to be smooth compared to the control by SEM. However, owing to the crosslinked structure, the CLPS film on silicon-wafer was inhomogeneous and had a few weak or strong peaks. At 5 nm data scale and in 2×2 μm2 scanning field, the root mean square roughness of CLPS film reached to 0.414 nm. XPS analysis further demonstrates that there was a CLPS film covered on the cotton surface. Hydrophobicity of the CLPS treated fabric was superior to that of the EPVMS treated one. Whiteness of the treated fabrics by CLPS and EPVMS did not change at all compared to the control. The softness of the two treated fabrics was both better than that of control and particularly the softness of the EPVMS treated fabrics was preferable. The CLPS treated fabric possessed good washing durability.  相似文献   

16.
Herein, an intelligent cotton fabric was fabricated using a non-ionic surfactant based macro structured carbonaceous coating through the ‘knife-over-roll’ technique. The developed novel fabric was tested as flexible, mechanically robust with prolonged chemical/moisture resistance. Various characterization techniques were thoroughly used to analyze the fabric. The as-prepared fabric shows an outstanding electromagnetic interference (EMI) shielding efficiency (SE) of about 21.5 dB even at the lowest possible coating thickness (0.20 mm) where the highest EMI SE of 30.8 dB is obtained at only 0.30 mm coating thickness over the X-band frequency range (8.2-12.4 GHz), possibly due to the three-dimensionally interconnected network structure of conducting carbon particles. The micro-computed tomography disclosed the porous architecture and “void-filler” arrangement within the fabrics. For the betterment of serviceability and practicability of the coated fabric, the water tolerance and contact angle studies were conducted. The relatively high contact angle than pure cotton fabric, and excellent water resistance after coating ensure improved endurance for external or industrial uses. Therefore, this proof-of-construct manifests commercialization of the developed fabric for multipurpose applications in a facile, less-hazardous and economical way.  相似文献   

17.
We report herein a superhyrodrophobic poly(ethylene terephthalate) (PET) fabric prepared through a biomimetic method of the Lotus effect. To attain the Lotus effect on the PET fabrics, physical roughness and chemical hydrophobicity were controlled by adopting silica nanoparticles and a commercial water-repellent agent, respectively. For this, narrow-size distributed silica nano-particles were prepared by a sol-gel process. The water contact angle on PET fabric treated with both silica nanoparticles and water-repellent agent reached 158°, which was much higher than 137° reached by the fabric treated with the water-repellent agent only.  相似文献   

18.
This study evaluated the potential application of an atmospheric plasma (AP) treatment as a pre-treatment for digital textile printing (DTP) of polyester (PET) fabrics and cotton, in order to determine its viability as an alternative to the usual chemical treatment. The surface properties of the AP-treated fabrics were examined through scanning electron microscopy (SEM) and contact angle, and the physical properties, such as electrostatic voltage and water absorbance, were tested. The properties of cotton and PET with the AP treatment were found to be dependent on number of repetitions and electric voltage. Although no remarkable surface differences were observed by SEM in the fabrics before and after treatment, the static contact angle of the PET after AP treatment was decreased from 85 ° to 24 ° at wave. In addition, the charge decay time decreased as the voltage and number of treatments increased. The absorption height of PET changed after exposure to 7 mm with increasing measurement time. The K/S with and without the AP pre-treated and DTP finished cotton was better than that with the usual chemical modification. In PET, the 0.5 kW and 1 time AP-treated specimen showed the highest K/S values.  相似文献   

19.
In this study, chitosan and pentasodium tripolyphosphate (TPP)-based bilayers were fabricated on the cationized woven cotton fabrics via layer-by-layer (LBL) self-assembly technique. The initial cationic charges on cotton fabric were produced through the aminization procedure involving the covalent attachment of reactive dye to cotton fabric and subsequent reductive cleavage of the dye to free amine. Different numbers of bilayers (1, 5, and 10) consisting of chitosan/TPP have been deposited on the fabrics. The surface morphology, cationic group content, chemical surface modification, whiteness index, surface tension and antibacterial properties of the modified cotton samples were investigated using scanning electron microscopy (SEM), methylene blue test, FTIR, reflectance spectroscopy, water contact angle measurements and antibacterial test, respectively. The bacterial inhibition experiments demonstrated that the modified cotton fabric with the addition of chitosan/TPP bilayers can increase the degree of inhibition on E. coli and S. aureus bacteria. The utilized LBL method was an easy and cost-effective procedure for developing of novel antibacterial textiles with the highly attractive feature in the medical and hygienic products.  相似文献   

20.
The main idea of this work is to study the different phenomena of spreading, evaporation, and diffusion that bound to the ink-jet printing. The coating film is studied as well as its drying morphologies and its wetting behavior. Then the drop water spreading on coated fabric is investigated. At that time spreading kinetic is characterized by the digidrop 3S which permits to measure precisely the various parameters such as contact angle, diameter, height, volume and drop profile in contact with the support during wetting phenomenon. This survey shows, on the one hand, that the coating film structure is deeply affected by drying morphologies. On the other hand, drying conditions influence different parameters of kinetic drop spreading on virgin glass and cotton material. Then the increasing of coating film thickness encourages the drop spreading.  相似文献   

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