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The formyl cation, HCO+, has long been believed to be an important intermediate in the chemistry of carbon monoxide (CO) in acidic environments, but its spectroscopic observation in solution has been elusive. This species was generated by the reaction of CO with the liquid superacid hydrofluoric acid-antimony pentafluoride (HF-SbF5) under pressure and was observed by nuclear magnetic resonance and infrared spectroscopy. Equilibria between CO in the gas phase, CO dissolved in HF-SbF5, the SbF5 adduct of formyl fluoride, and HCO+ associated with several equilibrating anions of the type [SbxF5x+1]- are proposed to describe the system. 相似文献
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Arkin IT Xu H Jensen MØ Arbely E Bennett ER Bowers KJ Chow E Dror RO Eastwood MP Flitman-Tene R Gregersen BA Klepeis JL Kolossváry I Shan Y Shaw DE 《Science (New York, N.Y.)》2007,317(5839):799-803
Na+/H+ antiporters are central to cellular salt and pH homeostasis. The structure of Escherichia coli NhaA was recently determined, but its mechanisms of transport and pH regulation remain elusive. We performed molecular dynamics simulations of NhaA that, with existing experimental data, enabled us to propose an atomically detailed model of antiporter function. Three conserved aspartates are key to our proposed mechanism: Asp164 (D164) is the Na+-binding site, D163 controls the alternating accessibility of this binding site to the cytoplasm or periplasm, and D133 is crucial for pH regulation. Consistent with experimental stoichiometry, two protons are required to transport a single Na+ ion: D163 protonates to reveal the Na+-binding site to the periplasm, and subsequent protonation of D164 releases Na+. Additional mutagenesis experiments further validated the model. 相似文献
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通过小尺度生态监测与遥感数据分析获取塔里木河下游荒漠河岸林现状信息,集中对阿拉干断面设立的100hm2长期监测样方内的胡杨树进行了详细的调查,对该断面胡杨林空间分布特征及其影响因素进行了分析。研究结果表明：塔里木河下游的胡杨具有伴河生长的特性;随着离河距离的增加,胡杨株数呈递减趋势;大部分胡杨主要分布在离河道200m范... 相似文献
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Origins of the 1988 north american drought 总被引：2，自引：0，他引：2
The 1988 summer drought in the United States was the most extensive in many years. Because the drought developed in different places at different times, not all regional effects can be traced to the same cause. Along the West Coast and in the northwestern United States drought conditions developed during 1987 in association with the 1986 to 1987 El Ni?o in the tropical Pacific Ocean. Record low rainfalls from April to June 1988 led to rapid development of drought in the North Central United States. Strong anticyclonic conditions and a northward displaced jet stream in the upper atmosphere over North America throughout this period were only part of pronounced and distinctive wavetrain of anomalies in the atmospheric circulation that appeared to emanate from the tropical Pacific. Below average sea surface temperatures along the equator in the Pacific in the northern spring of 1988, combined with warmer than normal water from 10 degrees to 20 degrees N, led to a northward displaced but still active intertropical convergence zone (ITCZ) southeast of Hawaii. Results from a steady-state planetarywave atmospheric model indicate that the atmospheric heating anomalies associated with the displaced ITCZ can force an anomalous wavetrain across North America similar to that observed. Land surface processes probably contributed to the severity and persistence of the drought; however, the large-scale atmospheric circulation perturbations associated with natural variations in the coupled atmosphere-ocean system in the tropical Pacific were most likely the primary cause. 相似文献
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G C Lantz S F Badylak M C Hiles T E Arkin 《American journal of veterinary research》1992,53(9):1594-1598
In dogs, gastric dilatation-volvulus (GDV) is characterized by cardiogenic shock, with resulting hypoperfusion. Treatment goals include reperfusion of transiently ischemic tissues, which indicates that reperfusion injury may be a factor in the physiopathogenesis of GDV. Recently, we obtained data that indicate that reperfusion injury may be involved in experimentally induced GDV. Using this GDV model, we evaluated mortality in 24 dogs of 4 equal groups, treated with deferoxamine (an iron chelator), dimethylsulfoxide (a free radical scavenger), a combination of the 2 drugs, or isotonic saline solution. All 6 dogs that were given deferoxamine survived; however, 3 dogs of the dimethylsulfoxide-treated group, 2 dogs of the combination-treated group, and 4 dogs of the saline-treated group died. Results of the study indicate that mortality associated with experimentally induced GDV is reduced by appropriate and timely pharmacologic intervention to prevent or attenuate reperfusion injury, and that deferoxamine may be more effective than dimethylsulfoxide. 相似文献
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Chivian D Brodie EL Alm EJ Culley DE Dehal PS DeSantis TZ Gihring TM Lapidus A Lin LH Lowry SR Moser DP Richardson PM Southam G Wanger G Pratt LM Andersen GL Hazen TC Brockman FJ Arkin AP Onstott TC 《Science (New York, N.Y.)》2008,322(5899):275-278
DNA from low-biodiversity fracture water collected at 2.8-kilometer depth in a South African gold mine was sequenced and assembled into a single, complete genome. This bacterium, Candidatus Desulforudis audaxviator, composes >99.9% of the microorganisms inhabiting the fluid phase of this particular fracture. Its genome indicates a motile, sporulating, sulfate-reducing, chemoautotrophic thermophile that can fix its own nitrogen and carbon by using machinery shared with archaea. Candidatus Desulforudis audaxviator is capable of an independent life-style well suited to long-term isolation from the photosphere deep within Earth's crust and offers an example of a natural ecosystem that appears to have its biological component entirely encoded within a single genome. 相似文献
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